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Preparation of novel nanocomposite materials through surface modification of cellulose nanofibrils

Research Project

Project/Area Number 15H06848
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Wood science
Research InstitutionForestry and Forest Products Research Institute

Principal Investigator

Fujisawa Shuji  国立研究開発法人森林総合研究所, 森林資源化学研究領域, 研究員 (80756453)

Project Period (FY) 2015-08-28 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords複合材料 / ナノセルロース / 表面改質 / TEMPO酸化 / ナノファイバー
Outline of Final Research Achievements

A simple and efficient method for the preparation of cellulose nanofibrils (CNFs)/polymer nanocomposite materials was developed, using polystyrene and poly(methyl methacrylate) as polymer matrices. CNFs were prepared by TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl)-mediated oxidation of wood cellulose. In the polymer nanocomposite materials, the CNFs were individually and homogeneously dispersed, and therefore, the nanocomposites showed good optical transparency, which is as high as original polymers. The nanocomposites exhibited improved strength, Young’s modulus, and thermal dimensional stability with increasing CNF content. Therefore, this preparation technique provides a simple environmentally-friendly method for the preparation of novel CNF/polymer nanocomposite materials.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • Research Products

    (23 results)

All 2017 2016 2015

All Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Acknowledgement Compliant: 9 results) Presentation (11 results) (of which Int'l Joint Research: 1 results,  Invited: 5 results) Book (3 results)

  • [Journal Article] Facile route to transparent, strong, and thermally stable nanocellulose polymer nanocomposites from an aqueous Pickering emulsion2017

    • Author(s)
      Fujisawa, S., Togawa, E., Kuroda, K.
    • Journal Title

      Biomacromolecules

      Volume: VOL18 Issue: 1 Pages: 266-271

    • DOI

      10.1021/acs.biomac.6b01615

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Pickering emulsionを用いた水系でのナノセルロース/疎水性高分子複合化技術2017

    • Author(s)
      藤澤秀次
    • Journal Title

      機能紙研究会誌

      Volume: 55巻 Pages: 25-29

    • NAID

      130006132763

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] セルロースナノファイバーの表面処理,分散性向上技術の種類とその特性2017

    • Author(s)
      藤澤秀次
    • Journal Title

      Material Stage

      Volume: 16巻 Pages: 25-28

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] TEMPO酸化CNFを用いた樹脂コンポジットの力学物性2016

    • Author(s)
      藤澤秀次
    • Journal Title

      成形加工

      Volume: 28巻 Pages: 326-329

    • NAID

      130007930290

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Orientation control of cellulose nanofibrils in all-cellulose composites and mechanical properties of the films2016

    • Author(s)
      Fujisawa, S., Togawa, E., Hayashi, N.
    • Journal Title

      Journal of Wood Science

      Volume: 62 Issue: 2 Pages: 174-180

    • DOI

      10.1007/s10086-015-1533-4

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Low-birefringent and highly tough nanocellulose-reinforced cellulose triacetate2015

    • Author(s)
      Soeta, H., Fujisawa, S., Saito, T., Berglund, L. A., Isogai, A.
    • Journal Title

      ACS Applied Materials & Interface

      Volume: 7 Issue: 20 Pages: 11041-11046

    • DOI

      10.1021/acsami.5b02863

    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] SEC-MALLS analysis of wood holocelluloses dissolved in 8% LiCl/1,3-dimethyl-2-imidazolidinone: challenges and suitable analytical conditions2015

    • Author(s)
      Ono, Y., Hiraoki, R., Fujisawa, S., Saito, T., Isogai, A.
    • Journal Title

      Cellulose

      Volume: 22 Issue: 5 Pages: 3347-3357

    • DOI

      10.1007/s10570-015-0694-z

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ナノセルロース複合材料の構造と機能2015

    • Author(s)
      藤澤秀次
    • Journal Title

      Nanofiber

      Volume: 6 Pages: 32-36

    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] ナノセルロース/ポリマー複合材料の界面修飾と力学物性2015

    • Author(s)
      藤澤秀次
    • Journal Title

      Cellulose Communications

      Volume: 22 Pages: 57-61

    • NAID

      40020497749

    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Presentation] Pickeringエマルションをテンプレートにした、ナノセルロース/ポリマー複合マイクロ粒子の調製2017

    • Author(s)
      藤澤秀次、戸川英二、黒田克史
    • Organizer
      第67回日本木材学会大会
    • Place of Presentation
      九州大学、アクロス福岡(福岡県福岡市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] セルロースナノファイバー/高分子複合材料の物性と展望~植物繊維でプラスチックをつよくする~2017

    • Author(s)
      藤澤秀次
    • Organizer
      愛媛県バイオマス利活用促進連絡協議会
    • Place of Presentation
      愛媛県美術館 (愛媛県松山市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Pickering emulsionを用いた水系でのナノセルロース/疎水性高分子複合化技術2016

    • Author(s)
      藤澤秀次
    • Organizer
      第55回機能紙研究会研究発表・講演会
    • Place of Presentation
      岐阜市文化産業交流センター(岐阜県岐阜市)
    • Year and Date
      2016-10-12
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Cellulose nanofibrils as a building block for polymer nanocomposite materials2016

    • Author(s)
      Fujisawa, S.
    • Organizer
      RIKEN CEMS Topical Meeting 2016 "Nanoparticles/Nanotubes/Nanosheets"
    • Place of Presentation
      理化学研究所(埼玉県和光市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Pickering emulsionを用いた、水系でのナノセルロース/ポリスチレン複合材料調製2016

    • Author(s)
      藤澤秀次、戸川英二、久保智史
    • Organizer
      第83回紙パルプ研究発表会
    • Place of Presentation
      東京大学弥生講堂(東京都文京区)
    • Year and Date
      2016-06-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] TEMPO酸化ナノセルロース/プラスチック透明複合材料の熱機械物性2016

    • Author(s)
      藤澤秀次、齋藤継之、磯貝明
    • Organizer
      プラスチック成形加工学会第27回年次大会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2016-06-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] TEMPO酸化セルロースナノファイバーを用いた透明高分子複合材料の熱機械物性2016

    • Author(s)
      藤澤秀次、久保智史、林徳子
    • Organizer
      平成28年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Uniaxial orientation of nanocelluloses in all-cellulose nanocomposite: The relationship between structure and mechanical properties2016

    • Author(s)
      Fujisawa, S., Togawa, E., Hayashi, N., Saito, T., Isogai, A.
    • Organizer
      251st American Chemica Society National Meeting & Exposition
    • Place of Presentation
      サンディエゴ(アメリカ合衆国)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] TEMPO酸化CNFと高分子のナノ複合化によって発現する材料特性2016

    • Author(s)
      藤澤秀次
    • Organizer
      セルロース学会第21回ミクロシンポジウム「躍進する若手研究者達による研究最前線」
    • Place of Presentation
      キャンパスプラザ京都(京都府京都市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] TEMPO触媒酸化法によるセルロースナノファイバーの製造と応用2016

    • Author(s)
      藤澤秀次
    • Organizer
      つくばサイエンス・アカデミー第9回研究情報交換会
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 循環型社会の実現を目指したナノセルロース材料利用技術2015

    • Author(s)
      藤澤秀次
    • Organizer
      第13回環境研究シンポジウム 2050年の地球と暮らし-環境技術と地球規模課題-
    • Place of Presentation
      一橋大学一橋講堂 (東京都千代田区)
    • Year and Date
      2015-11-10
    • Related Report
      2015 Annual Research Report
  • [Book] 機能紙最前線~次世代機能紙とその垂直連携に向けて~ Pickering エマルションを起点とした水中でのナノセルロース/疎水性ポリマー複合化2017

    • Author(s)
      藤澤秀次
    • Total Pages
      350
    • Publisher
      株式会社加工技術研究会
    • Related Report
      2016 Annual Research Report
  • [Book] ナノセルロースの製造技術と応用展開 第Ⅲ編第3章 セルロースナノクリスタルで架橋した高強度ポリウレタン材料2016

    • Author(s)
      藤澤秀次
    • Total Pages
      245
    • Publisher
      S&T出版
    • Related Report
      2016 Annual Research Report
  • [Book] 図解よくわかるナノセルロース2015

    • Author(s)
      藤澤秀次
    • Total Pages
      208
    • Publisher
      日刊工業新聞社
    • Related Report
      2015 Annual Research Report

URL: 

Published: 2015-08-26   Modified: 2018-03-22  

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