Development of Loop-shape pi-Conjugated Polymers with Hydrogen-bond Network
| Project/Area Number |
15H06849
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional solid state chemistry
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| Research Institution | National Institute for Materials Science |
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Principal Investigator |
NAGURA Kazuhiko 国立研究開発法人物質・材料研究機構, 若手国際研究センター, ICYS研究員 (60758332)
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| Research Collaborator |
MOCHIZUKI Chihiro
TAKEUCHI Masayuki
NAKANISHI Takashi
MATSUSHITA Yoshitaka
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| Project Period (FY) |
2015-08-28 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | π共役高分子 / フォルダマー / チオフェン / イミダゾール / 水素結合 / パイ共役高分子 |
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| Outline of Final Research Achievements |
We have designed and synthesized π-conjugated polymers with loop-shape structures constructed by hydrogen-bond network. The polythiophenes with imidazolyl side chains or fused imidazole rings, which work as hydrogen bond platform, were synthesized by the catalyst-transfer polymerization or direct CH arylation polymerization, and subsequent deprotection. The loop-shape structures of obtained polymers were confirmed by the various spectroscopic, and microscope measurements. The obtained loop-shape polymers showed distinct optical and conducting characters from linear polymers in the single molecule and aggregation states.
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Report
(3 results)
Research Products
(3 results)
