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Green and efficient synthesis of key raw materials for super engineering plastics by high temperature high pressuure water microflow process

Research Project

Project/Area Number 15H06892
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Reaction engineering/Process system
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Nagao Ikuhiko  国立研究開発法人産業技術総合研究所, 化学プロセス研究部門, 研究員 (80760313)

Project Period (FY) 2015-08-28 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords高温高圧水 / 超臨界水 / 亜臨界水 / フロープロセス / マイクロプロセス / 流通式反応装置 / 縮合反応 / クロスカップリング / 反応工学 / プロセスシステム
Outline of Final Research Achievements

Due to the increasing concerns on developments of sustainable chemical technologies, there have been huge demands for process, which combines high production efficiency, low environmental burden, high hygiene level, and economic viability, altogether. In the perspective, utilization of water as reaction media in a chemical process would be one of the most attractive solution. The end of this research is developing cross-coupling reaction utilizing high temperature high pressure water, directing toward creation of efficient and green chemical process for key raw materials of super engineering plastics. Thorough the research, successful results were achieved; the developed microflow process enabled cross coupling reactions with reduced amount of catalysts and base in extremely accelerated reaction time.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • Research Products

    (6 results)

All 2017 2016

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (2 results) Book (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Rapid Production of benzazole derivatives by a high-pressure and high-temperature water microflow chemical process2016

    • Author(s)
      Ikuhiko Nagao, Takayuki Ishizaka, Hajime Kawanami
    • Journal Title

      Green Chemistry

      Volume: 18 Issue: 12 Pages: 3494-3498

    • DOI

      10.1039/c6gc01195k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 高温高圧水マイクロ化学プロセスによる遷移金属触媒クロスカップリング反応2016

    • Author(s)
      長尾育弘、石坂孝之、川波肇
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学、徳島市
    • Related Report
      2016 Annual Research Report
  • [Presentation] 高温高圧水マイクロ化学プロセスによるヘテロ元素含有芳香族分子の迅速合成2016

    • Author(s)
      長尾育弘、石坂孝之、川波肇
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学、吹田市
    • Related Report
      2015 Annual Research Report
  • [Book] ケミカルエンジニヤリング 特集=フローマイクロリアクターの開発と応用、2016, Vol.61, No.9, 16-24「高温高圧水マイクロリアクターによる有機材料合成法の開発」2016

    • Author(s)
      長尾育弘、川波肇
    • Total Pages
      8
    • Publisher
      化学工業社
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 高温高圧水中合成反応のための反応、抽出、分離を含む流通式連続処理方法及び装置2017

    • Inventor(s)
      長尾育弘、石坂孝之、川波肇
    • Industrial Property Rights Holder
      長尾育弘、石坂孝之、川波肇
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017-02-21
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] ベンゾアゾール類の合成方法2016

    • Inventor(s)
      長尾育弘、川波肇、石坂孝之
    • Industrial Property Rights Holder
      長尾育弘、川波肇、石坂孝之
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-01-28
    • Related Report
      2015 Annual Research Report

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Published: 2015-08-26   Modified: 2018-03-22  

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