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新規エネルギー物質ロケット推進薬の高速燃焼現象解明と制御技術の確立

Research Project

Project/Area Number 15J04632
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Aerospace engineering
Research InstitutionYokohama National University

Principal Investigator

伊里 友一朗  横浜国立大学, 環境情報研究院, 特別研究員(PD)

Project Period (FY) 2015-04-24 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥2,170,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,000,000 (Direct Cost: ¥1,000,000)
Keywordsエネルギー物質 / ロケット推進薬 / 燃焼 / 凝縮相反応解析 / 素反応 / 熱分析 / 反応速度論解析 / 凝縮相反応
Outline of Annual Research Achievements

本年度は研究目標とする「新規エネルギー物質ロケット推進剤の高速燃焼現象解明と制御技術の確立」に関して、エネルギー物質の燃焼・分解反応に関するモデリングとシミュレーション技術に関して大きく進展した。前年度までに特定していたエネルギー物質に関する分解反応経路から,今年度はさらに拡張を達成し,基礎的なエネルギー物質推進剤組成物(硝酸アンモニウム,アンモニウムジニトラミド,硝酸ヒドロキシルアミン,ヒドロキシルアミン,硝酸グアニジンなど)に関する気・液両相の分解・燃焼反応に関する反応経路を定式化した。解析技術が整備されつつある気相反応のみならず,液相反応を取り扱っている点に本研究の独創性がある。これら特定された反応経路に対して,統計熱力学および反応速度論の理論より,(速度係数,熱力学データ,輸送定数から成る)詳細反応モデル【YNU modelシリーズ】を構築した。本モデルを使用して,任意組成・任意温度/圧力条件における上記エネルギー物質の化学反応を詳細に解析する反応シミュレーションを達成した。本研究成果は、エネルギー物質を使用した推進システム設計、特に着火・消炎などの過渡現象制御に関する設計に資することが期待できる。今後は,CFDと本反応シミュレーションをカップリングすることで,ロケットモーターおよびエンジン内の燃焼を詳細に解析できることが期待される。
これら研究成果について、2016年度は英文筆頭論文:4報(他に共著論文1報),国際会議発表:3件,国内学会発表:15件にて公表した。

Research Progress Status

28年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

28年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (26 results)

All 2017 2016 2015

All Journal Article (11 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 10 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (15 results) (of which Int'l Joint Research: 7 results,  Invited: 1 results)

  • [Journal Article] Initial Decomposition Pathways of Aqueous Hydroxylamine Solutions2017

    • Author(s)
      Y. Izato, M. Koshi, A. Miyake
    • Journal Title

      Journal of physical chemistry B

      Volume: 印刷中 Issue: 17 Pages: 4502-4511

    • DOI

      10.1021/acs.jpcb.6b10546

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Direct Self-Sustained Fragmentation Cascade of Reactive Droplets2017

    • Author(s)
      C. Inoue, Y. Izato, A. Miyake, E. Villermaux
    • Journal Title

      Physical Review Letters

      Volume: 118 Issue: 7 Pages: 074502-074502

    • DOI

      10.1103/physrevlett.118.074502

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Identification of thermal decomposition products and reactions for liquid ammonium nitrate on the basis of ab initio calculation2016

    • Author(s)
      Y. Izato, M. Koshi, A. Miyake
    • Journal Title

      International Journal of Chemical Kinetics

      Volume: 49 Issue: 2 Pages: 83-99

    • DOI

      10.1002/kin.21058

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Kinetics analysis of thermal decomposition of ammonium dinitramide (ADN)2016

    • Author(s)
      Y. Izato, M. Koshi, H. Habu, A. Miyake
    • Journal Title

      Journal of Thermal Analysis and Calorimetry

      Volume: 127 Issue: 1 Pages: 255-264

    • DOI

      10.1007/s10973-016-5703-4

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics Analysis of the Initial Decomposition Reaction of Ammonium Dinitramide2016

    • Author(s)
      Y. Izato, M. Koshi, H. Habu, A. Miyake
    • Journal Title

      TRANSACTIONS OF THE JAPAN SOCIETY FOR AERONAUTICAL AND SPACE SCIENCES, AEROSPACE TECHNOLOGY JAPAN

      Volume: 14 Issue: ists30 Pages: Pa_27-Pa_30

    • DOI

      10.2322/tastj.14.Pa_27

    • NAID

      130005172128

    • ISSN
      1884-0485
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of potassium chloride on thermal decomposition behavior of ammonium nitrate and carbon mixtures2015

    • Author(s)
      Y. Izato, A. Miyake
    • Journal Title

      J.Chem. Eng. Soc. Jpn.

      Volume: 48 Pages: 698-703

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal decomposition mechanism of molten ammonium nitrate2015

    • Author(s)
      Y. izato, A. Miyake
    • Journal Title

      J Therm Anal Calorim

      Volume: 121 Issue: 2 Pages: 98-103

    • DOI

      10.1007/s10973-015-4762-2

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Thermal decomposition mechanism of ammonium nitrate and potassium chloride mixture2015

    • Author(s)
      Y. Izato, A. Miyake
    • Journal Title

      J Therm Anal Calorim

      Volume: 121 Issue: 1 Pages: 287-294

    • DOI

      10.1007/s10973-015-4739-1

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A condensed phase decomposition mechanism for ammonium nitrate2015

    • Author(s)
      Y. Izato, A. Miyake
    • Journal Title

      Sci. Tech. energetic materials

      Volume: 76 Pages: 99-103

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal decomposition mechanism of ammonium nitrate and copper (II) oxide mixtures2015

    • Author(s)
      Y. Izato, K. Kajiyama, A. Miyake
    • Journal Title

      Sci. Tech. Energetic Materials

      Volume: 75 Pages: 119-127

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal ignition behavior of waste woods mixed with unsaturated fatty acids2015

    • Author(s)
      R. Mizuta, Y. Izato, A. Miyake
    • Journal Title

      J Therm Anal Calorim

      Volume: 121 Issue: 1 Pages: 361-369

    • DOI

      10.1007/s10973-015-4788-5

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Combustion and decomposition model of ammonium dinitramide based propellant Isomerization of dinitraminic acid (HDN)2016

    • Author(s)
      Y. Izato, M. Koshi, H. Habu, A. Miyake
    • Organizer
      Asian joint conference on Propulsion and Power
    • Place of Presentation
      高松
    • Year and Date
      2016-03-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetics analysis of condensed phase decomposition of ammonium dinitramide (ADN)2016

    • Author(s)
      Y. Izato, H. Habu, M. Koshi, A. Miyake
    • Organizer
      2016 International Conference for Thermal Analysis and Calorimetry Congress
    • Place of Presentation
      Orlando, Florida, USA
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetics Analysis of Thermal Decomposition of Ammonium-Dinitramide (ADN)-Based-Ionic-Liquid Propellant2016

    • Author(s)
      Y. Izato, M. Hayata, H. Habu, A. Miyake
    • Organizer
      2016 International Conference for Thermal Analysis and Calorimetry Congress
    • Place of Presentation
      Orlando, Florida, USA
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A screening method for searching high performance and low melting point compositions of ADN based Deep Eutectic Energetic Ionic Liquid Propellants2016

    • Author(s)
      Y. Izato, M. Hayata, M. Itakura, H. Habu, A. Miyake
    • Organizer
      Calorimetry Conference 2017
    • Place of Presentation
      Oahu, Hawai, USA
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アンモニウムジニトラミドの分解反応速度解析2015

    • Author(s)
      伊里友一朗, 越光男, 羽生宏人, 三宅淳巳
    • Organizer
      火薬学会2015年度秋季研究発表会
    • Place of Presentation
      大分
    • Year and Date
      2015-12-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ab-initio計算を用いた硝酸アンモニウムの熱分解反応解析2015

    • Author(s)
      伊里友一朗, 越光男, 三宅淳巳
    • Organizer
      火薬学会2015年度秋季研究発表会
    • Place of Presentation
      大分
    • Year and Date
      2015-12-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] 金属の硝酸洗浄工程における爆発性錯体化合物蓄積に関する危険性評価2015

    • Author(s)
      伊里友一朗, 塩田謙人, 三宅淳巳
    • Organizer
      第48回安全工学研究発表会
    • Place of Presentation
      新潟
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] ジメチルスルホキシドの熱爆発転移シナリオ2015

    • Author(s)
      伊里友一朗, 馬場崎勇太, 飯塚義明, 三宅淳巳
    • Organizer
      第48回安全工学研究発表会
    • Place of Presentation
      新潟
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] 海洋漂着ポリスチレンの低温燃焼時におけるダイオキシン類生成と燃焼挙動2015

    • Author(s)
      伊里友一朗, 三宅淳巳
    • Organizer
      第48回安全工学研究発表会
    • Place of Presentation
      新潟
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] Kinetics analysis of condensed phase decomposition of ammonium dinitramide (ADN)2015

    • Author(s)
      Y. Izato, H. Habu, M. Koshi, A. Miyake
    • Organizer
      3rd Central and Eastern European Conference on Thermal Analysis and Calorimetry
    • Place of Presentation
      スロヴェニア
    • Year and Date
      2015-08-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetics analysis thermal decomposition of dimethyl sulfoxide (DMSO), under acidic condition2015

    • Author(s)
      Y. Izato, Y. Babasaki, Y. Iizuka, A. Miyake
    • Organizer
      3rd Central and Eastern European Conference on Thermal Analysis and Calorimetry
    • Place of Presentation
      スロヴェニア
    • Year and Date
      2015-08-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Condensed phase decomposition mechanism of ammonium dinitramide2015

    • Author(s)
      Y. Izato, H. Habu, M. Koshi, A. Miyake
    • Organizer
      30th International Symposium on Space Technology and Scienc
    • Place of Presentation
      神戸
    • Year and Date
      2015-07-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 硝酸アンモニウム, 特に酸化銅混合物との熱分解機構に関する研究2015

    • Author(s)
      伊里友一朗
    • Organizer
      火薬学会2015年度春季研究発表会
    • Place of Presentation
      神奈川
    • Year and Date
      2015-05-29
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] アンモニウムジニトラミドの燃焼反応モデル2015

    • Author(s)
      伊里友一朗, 羽生宏人, 越光男, 三宅淳巳
    • Organizer
      火薬学会2015年度春季研究発表会
    • Place of Presentation
      神奈川
    • Year and Date
      2015-05-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] 融解アンモニウムジニトラミドの初期熱分解2015

    • Author(s)
      伊里友一朗, 羽生宏人, 越光男, 三宅淳巳
    • Organizer
      火薬学会2015年度春季研究発表会
    • Place of Presentation
      神奈川
    • Year and Date
      2015-05-29
    • Related Report
      2015 Annual Research Report

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Published: 2015-11-26   Modified: 2024-03-26  

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