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化学修飾型ナフチレン環状分子の設計・合成

Research Project

Project/Area Number 15J05964
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Organic chemistry
Research InstitutionTohoku University

Principal Investigator

XUE JING  東北大学, 理学研究科, 特別研究員(PD)

Project Period (FY) 2015-04-24 – 2017-03-31
Project Status Declined (Fiscal Year 2016)
Budget Amount *help
¥2,170,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,000,000 (Direct Cost: ¥1,000,000)
Keywordsarylene macrocycles
Outline of Annual Research Achievements

The first study describes the development of arylene macrocycles for the single-layer OLED, enabling one material to function in electron and hole transport layers (ETL and HTL), as well, an emission layer (EML) as a host material. The structure-performance relationship studies revealed the requirement for the arylene macrocycles to be utilized in the single-layer OLED as a base material. An unexpectedly high EQE value was recorded with a green Ir(ppy)3 emitter in such a single-layer OLED, indicating nearly quantitative electro-optical conversion has been achieved. The results indicated the infinite possibilities of arylene macrocycles for the future development in the organic electronics.

In the second study, a series of nitrogen-embedded [n]CMPs (n = 6, 8, 10, 12 and 14) was synthesized via one-pot, cross-coupling macrocyclization and their fundamental properties were clarified. All the macrocyclic structures in the crystalline solid state were revealed by X-ray crystallographic analysis, showing that the overall macrocyclic structures changes dramatically; depending on the numbers of arylene units. The solution-phase analyses showed the presence of flexible macrocyclic structures.

Research Progress Status

翌年度、交付申請を辞退するため、記入しない。

Strategy for Future Research Activity

翌年度、交付申請を辞退するため、記入しない。

Report

(1 results)
  • 2015 Annual Research Report
  • Research Products

    (7 results)

All 2016 2015

All Journal Article (3 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (4 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Aromatic hydrocarbon macrocycles for highly efficient organic light-emitting devices with single-layer architectures2016

    • Author(s)
      J. Y. Xue, T. Izumi, A. Yoshii, K. Ikemoto, T. Koretsune, R. Akashi, R. Arita, H. Taka, H. Kita, S. Sato, H. Isobe
    • Journal Title

      Chemical Science

      Volume: 7 Issue: 2 Pages: 896-896

    • DOI

      10.1039/c5sc03807c

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Modular Synthesis of Aromatic Hydrocarbon Macrocycles for Simplified, Single-Layer Organic Light-Emitting Devices2016

    • Author(s)
      K. Ikemoto, A. Yoshii, T. Izumi, H. Taka, H. Kita, J. Y. Xue, R. Kobayashi, S. Sato, H. Isobe
    • Journal Title

      J. Org. Chem.

      Volume: 81 Issue: 2 Pages: 662-666

    • DOI

      10.1021/acs.joc.5b02620

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Introduction of Nitrogen Atoms in [n]Cyclo-meta-phenylenes via Cross Coupling Macrocyclization2016

    • Author(s)
      J. Y. Xue, K. Ikemoto, S. Sato, and H. Isobe
    • Journal Title

      Chem. Lett.

      Volume: 45 Issue: 6 Pages: 676-678

    • DOI

      10.1246/cl.160218

    • NAID

      130005155023

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Hydrocarbon macrocycles for organic-light emitting devices2015

    • Author(s)
      Jing Xue, Tomoo Izumi, Asami Yoshii, Koki Ikemoto, Hideo Taka, Sota Sato, Hiroshi Kita, and Hiroyuki Isobe
    • Organizer
      第30回若手研究者の仙台セミナー
    • Place of Presentation
      東北大学 (仙台)
    • Year and Date
      2015-12-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of Cyclo-meta-phenylene Derivatives for the Organic Materials2015

    • Author(s)
      Jing Xue, Koki Ikemoto, Norihisa Takahashi, Tomoo Izumi, Hideo Taka, Hiroshi Kita, Sota Sato, and Hiroyuki Isobe
    • Organizer
      16th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Madrid (Spain)
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrocarbon macrocycles for organic-light emitting devices2015

    • Author(s)
      Jing Xue, Tomoo Izumi, Asami Yoshii, Koki Ikemoto, Hideo Taka, Sota Sato, Hiroshi Kita, and Hiroyuki Isobe
    • Organizer
      第27回万有札幌シンポジウム
    • Place of Presentation
      北海道大学 (札幌)
    • Year and Date
      2015-07-04
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Hydrocarbon macrocycles for organic-light emitting devices2015

    • Author(s)
      Jing Xue, Tomoo Izumi, Asami Yoshii, Koki Ikemoto, Hideo Taka, Sota Sato, Hiroshi Kita, and Hiroyuki Isobe
    • Organizer
      第26回万有仙台シンポジウム
    • Place of Presentation
      仙台国際センター (仙台)
    • Year and Date
      2015-06-06
    • Related Report
      2015 Annual Research Report

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Published: 2015-11-26   Modified: 2024-03-26  

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