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High efficiency utilization of slaked lime for neutralization treatment of waste incineration exhaust gas

Research Project

Project/Area Number 15K00577
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental engineering and reduction of environmental burden
Research InstitutionHokkaido University

Principal Investigator

Hwang In-Hee  北海道大学, 工学(系)研究科(研究院), 助教 (70447077)

Co-Investigator(Kenkyū-buntansha) 松藤 敏彦  北海道大学, 工学研究院, 教授 (00165838)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords廃棄物焼却 / 排ガス処理 / 消石灰 / 塩化水素 / 塩化水酸化カルシウム / 中和反応 / 硫黄酸化物 / ごみ焼却排ガス処理
Outline of Final Research Achievements

Fly ashes discharged from incineration facilities which were performing dry scrubbing of acid gas using slaked lime and dust collection using a bag filter were analyzed. As a result, it was revealed that the reaction product of HCl and slaked lime was calcium chloride hydroxide (CaClOH), not generally known anhydrous or hydrous calcium chlorides (CaCl2). In the experiment under the condition of 170oC, and Ca/Cl molar ratio=0.1-5 using a lab scale of flow-through reactor, Ca(OH)2 and HCl reaction product was also CaClOH, which was consistent with the analysis result of fly ashes obtained from incineration facilities. Considering the efficient use of slaked lime, it was desirable to make the reaction proceed up to CaCl2 formation, but it was suggested that CaClOH might be formed as a main product the current dry scrubbing process of flue gas treatment.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (10 results)

All 2017 2016 2015

All Presentation (10 results) (of which Int'l Joint Research: 5 results)

  • [Presentation] ごみ焼却排ガスの中和処理用消石灰と塩化水素の反応機構に関する研究2017

    • Author(s)
      黄仁姫,向山和晃,松尾孝之,松藤敏彦,山田裕史
    • Organizer
      第38回全国都市清掃研究・事例発表会
    • Place of Presentation
      釧路市観光国際交流センター,釧路市
    • Year and Date
      2017-01-18
    • Related Report
      2016 Research-status Report
  • [Presentation] ごみ焼却排ガス乾式処理での塩化水素と消石灰の反応メカニズム2017

    • Author(s)
      黄 仁姫, 須藤 航, 松尾 孝之, 東條 安匡, 松藤 敏彦
    • Organizer
      第28回廃棄物資源循環学会研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Experimental study on reaction of slaked lime and hydrogen chloride in dry scrubbing of flue gas generated from waste incinerator2017

    • Author(s)
      In-Hee Hwang, Wataru Sudo, Takayuki Matsuo, Yasumasa Tojo, Toshihiko Matsuto
    • Organizer
      The 2017 Spring Conference of the Korea Society of Waste Management
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 消石灰を用いたごみ焼却排ガス中の塩化水素除去機構の解明2016

    • Author(s)
      須藤航、黄仁姫、松尾孝之、松藤敏彦
    • Organizer
      2016年度廃棄物資源循環学会北海道支部ポスター発表会
    • Place of Presentation
      北海道大学,札幌市
    • Year and Date
      2016-10-25
    • Related Report
      2016 Research-status Report
  • [Presentation] アンケート調査および飛灰分析によるごみ焼却排ガス中酸性ガス乾式処理の機構解明2016

    • Author(s)
      向山 和晃, 黄 仁姫, 松尾 孝之, 松藤 敏彦
    • Organizer
      平成28年度廃棄物資源循環学会研究発表会
    • Place of Presentation
      和歌山大学, 和歌山市
    • Year and Date
      2016-09-27
    • Related Report
      2016 Research-status Report
  • [Presentation] Reaction of Calcium Hydroxide and Hydrogen Chloride in Dry Scrubbing Process of Municipal Solid Waste Incineration Plant2016

    • Author(s)
      In-Hee Hwang, Kazuaki Mukaiyama, Takayuki Matsuo, Toshihiko Matsuto, Ryoji Sameshima
    • Organizer
      9th i-CIPEC
    • Place of Presentation
      Kyoto Research Park, Kyoto
    • Year and Date
      2016-09-20
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Investigation on reaction characteristics of calcium hydroxide and hydrogen chloride in flue gas of municipal solid waste incinerator by questionnaire survey and fly ash analysis2016

    • Author(s)
      In-Hee Hwang, Kazuaki Mukaiyama, Takayuki Matsuo, Toshihiko Matsuto, Ryoji Sameshima
    • Organizer
      The 7th China-Japan Joint Conference on Material Recycling and Waste Management
    • Place of Presentation
      Okinawa Prefecture Government Building (South Okinawa Government Office), Naha
    • Year and Date
      2016-07-18
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Calcium compounds in fly ashes discharged from municipal solid waste incinerators adopting a drying scrubbing and fabric filters2016

    • Author(s)
      In-Hee Hwang, Kazuaki Mukaiyama, Takayuki Matsuo, Toshihiko Matsuto
    • Organizer
      The 9th Intercontinental Landfill Research Symposium
    • Place of Presentation
      Noboribetsu Grand Hotel, Noboribetsu
    • Year and Date
      2016-06-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Study on mechanism of calcium hydroxide and acidic gases in flue gas of municipal solid waste incinerator2016

    • Author(s)
      In-Hee Hwang, Kazuaki Mukaiyama, Takayuki Matsuo, Toshihiko Matsuto, Ryoji Sameshima
    • Organizer
      20th Korea-Japan Joint International Session, The 2016 Spring Conference of the Korea Society of Waste Management
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2016-05-12
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ラボ試験によるごみ焼却排ガス中のHCl乾式除去の機構解明2015

    • Author(s)
      木下亮,黄仁姫,松藤敏彦,松尾孝之,鮫島良二
    • Organizer
      第26回廃棄物資源循環学会研究発表会
    • Place of Presentation
      九州大学(福岡市)
    • Year and Date
      2015-09-02
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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