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Syngas production from carbon dioxide using reaction-separation combined process with hydrogen separation

Research Project

Project/Area Number 15K00582
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental engineering and reduction of environmental burden
Research InstitutionGifu University

Principal Investigator

UEMIYA Shigeyuki  岐阜大学, 工学部, 教授 (60221800)

Co-Investigator(Kenkyū-buntansha) 宮本 学  岐阜大学, 工学部, 准教授 (60538180)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsメンブレンリアクター / ドライリフォーミング / 膜分離 / 反応分離 / 水素 / 二酸化炭素 / メタン / 合成ガス / ドライリホーミング / パラジウム / パラジウム膜
Outline of Final Research Achievements

Noble reaction system that would convert carbon dioxide and methane to syngas with high efficiency by using a reaction-separation process incorporating with a hydrogen separation membrane was investigated. A syngas production catalyst developed was demonstrated to be highly active at a relatively low temperature and was applied to the reaction-separation combined process. As a result, in separation-reaction combined process using a Pd membrane, about 90% of the product hydrogen permeated through the membrane, so that produced hydrogen was separated immediately from the reaction field. The progress of the water gas shift reaction was suppressed, and then hydrogen / carbon monoxide ratio of the synthesis gas was increased, and as a result, the hydrogen yield was improved dramatically.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (5 results)

All 2018 2017 2016

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (4 results)

  • [Journal Article] Effect of basicity of metal doped ZrO 2 supports on hydrogen production reactions2018

    • Author(s)
      Miyamoto Manabu、Hamajima Akira、Oumi Yasunori、Uemiya Shigeyuki
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 43 Issue: 2 Pages: 730-738

    • DOI

      10.1016/j.ijhydene.2017.11.041

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] CO2メタネーションにおけるCeO2担体効果2017

    • Author(s)
      上宮成之、平野智之、中村匡宏、宮本 学、近江靖則
    • Organizer
      石油学会第60回年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ZrO2担体に塩基性酸化物を添加したRu系メタンドライリホーミング用の触媒の開発2017

    • Author(s)
      濱島 亮、宮本 学、近江靖則、上宮成之
    • Organizer
      石油学会第60回年会(第22回JPIJSポスターセッション)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 多孔質担体層をポストコーティングした水素分離用Pd複合膜の作製2017

    • Author(s)
      水谷太智、宮本 学、近江靖則、上宮成之、山田博史、田川智彦
    • Organizer
      石油学会第47回石油・石油化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] フォトリソグラフィーを用いたPd複合膜の作製における樹脂基板の表面改質がPd層に及ぼす効果2016

    • Author(s)
      村瀬達也,宮本学,近江靖則,上宮成之,山田博史,田川智彦
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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