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Development of advanced treatment technique of wastewater containing organochlorine compounds by hydrothermal oxidation based hybrid process

Research Project

Project/Area Number 15K00585
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental engineering and reduction of environmental burden
Research InstitutionOsaka City University

Principal Investigator

KOMETANI Noritsugu  大阪市立大学, 大学院工学研究科, 教授 (80295683)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords廃棄物処理 / 触媒・化学プロセス / 水熱酸化法 / キャビテーション / フェントン法 / 水熱酸化 / オゾン / 水質浄化 / キャビテーション法
Outline of Final Research Achievements

The hybrid processes of hydrothermal oxidation and Fenton, UV or cavitation process have been developed to allow for advanced treatment of wastewater containing persistent pollutants under mild reaction condition. Cu/Ni binary catalyst was found to enhance the decomposition of pollutants because of acceleration of Fenton-like reaction by inter-element interaction. A hybrid process of hydrothermal oxidation and UV showed no appreciable superiority with respect to hydrothermal oxidation alone. Hydrodynamic cavitation could be successfully generated under hydrothermal condition using a Venturi tube, which promoted the decomposition of pollutant by hydrothermal oxidation.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (23 results)

All 2017 2016 2015

All Journal Article (8 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 7 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (15 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Degradation of Hydrophilic Polymers in Aqueous Solution by Using Ozone Microbubble2017

    • Author(s)
      T. Nishiyama, K. Matsuura, E. Sato, N. Kometani, H. Horibe
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 30 Issue: 3 Pages: 285-289

    • DOI

      10.2494/photopolymer.30.285

    • NAID

      130005950264

    • ISSN
      0914-9244, 1349-6336
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Photocatalytic Reduction of CO2 by Pt-Loaded TiO2 in the Mixture of Sub- and Supercritical Water and CO22017

    • Author(s)
      N. Kometani, S. Hirata, M. Chikada
    • Journal Title

      Journal of Supercritical Fluids

      Volume: 120 Pages: 443-447

    • DOI

      10.1016/j.supflu.2016.05.031

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] WD-XRF Imaging With Polycapillary Optics Under Glancing Incidence Geometry2016

    • Author(s)
      Y. Takimoto, M. Yamanashi, S. Kato, T. Shoji, N. Kometani, K. Tsuji
    • Journal Title

      Advances in X-ray Analysis

      Volume: 59 Pages: 120-124

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Sample preparation for TXRF analysis of metal particles in used machine oils and preliminary research for application of principal component analysis2016

    • Author(s)
      T. Matsuno, Y. Tabuchi, R. Hosomi, T. Hasegawa, N. Kometani, K.i Tsuji
    • Journal Title

      Advances in X-ray Analysis

      Volume: 59 Pages: 112-119

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] 酸化銅触媒を用いたフェントン・水熱酸化法による汚染水高度処理技術2015

    • Author(s)
      米谷紀嗣
    • Journal Title

      ケミカルエンジニアリング

      Volume: 60 Pages: 20-24

    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] Advanced Treatment of Polluted Water Containing Chlorinated Organic Compounds by the Hydrothermal Oxidation Technique Using Copper Oxide Catalyst2015

    • Author(s)
      米谷紀嗣,高見玲奈,中尾恭平
    • Journal Title

      JAPANESE JOURNAL OF MULTIPHASE FLOW

      Volume: 29 Issue: 4 Pages: 302-308

    • DOI

      10.3811/jjmf.29.302

    • NAID

      130005118671

    • ISSN
      0914-2843, 1881-5790
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] In Situ Observations of Thermoreversible Gelation and Phase Separation of Agarose and Methylcellulose Solutions under High Pressure2015

    • Author(s)
      Noritsugu Kometani, Masahiro Tanabe, Lei Su, Kun Yang, and Katsuyoshi Nishinari
    • Journal Title

      J. Phys. Chem. B

      Volume: 119 Issue: 22 Pages: 6878-883

    • DOI

      10.1021/acs.jpcb.5b03632

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Preliminary experiment of X-ray diffraction imaging2015

    • Author(s)
      Masaki Yamanashi, Noritsugu Kometani, Kouichi Tsuji
    • Journal Title

      Nuclear Instruments and Methods in Physics Research B

      Volume: 355 Pages: 272-275

    • DOI

      10.1016/j.nimb.2015.02.049

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 水熱酸化法とオゾン酸化法のハイブリッド化による難分解性有機物の高度処理2017

    • Author(s)
      小林健吾,米谷紀嗣
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] 超臨界水中における芳香族塩素化合物の吸収スペクトルのその場測定2017

    • Author(s)
      平田章太郎、米谷紀嗣
    • Organizer
      第58回高圧討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 難分解性有機汚染物質の水熱酸化を促進するCu-Ni触媒の開発2017

    • Author(s)
      成田正彰、米谷紀嗣
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 水熱酸化法とオゾン処理法の複合プロセスによる汚染水処理技術の開発2017

    • Author(s)
      小林健吾、米谷紀嗣
    • Organizer
      化学工学会第49回秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 緑色蛍光タンパク質の回転緩和を用いたカラギーナンのゾル-ゲル転移の研究2016

    • Author(s)
      山崎真代,米谷紀嗣
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2016-11-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 高温高圧水中での紫外可視光照射によるCO2 光触媒還元2016

    • Author(s)
      平田章太郎,米谷紀嗣
    • Organizer
      第57回高圧討論会
    • Place of Presentation
      筑波大学大学会館(茨城県つくば市)
    • Year and Date
      2016-10-26
    • Related Report
      2016 Research-status Report
  • [Presentation] 水熱酸化法とオゾン酸化法のハイブリッド化による難分解性有機物の高度処理2016

    • Author(s)
      小林健吾,米谷紀嗣
    • Organizer
      第57回高圧討論会
    • Place of Presentation
      筑波大学大学会館(茨城県つくば市)
    • Year and Date
      2016-10-26
    • Related Report
      2016 Research-status Report
  • [Presentation] 有機汚染物質の水熱酸化処理に用いられる Cu-Ni 二元系触媒の開発2016

    • Author(s)
      成田正彰,米谷紀嗣
    • Organizer
      第57回高圧討論会
    • Place of Presentation
      筑波大学大学会館(茨城県つくば市)
    • Year and Date
      2016-10-26
    • Related Report
      2016 Research-status Report
  • [Presentation] キャビテーションをベースとした複合プロセスによる難分解性有機物分解処理2016

    • Author(s)
      竹内柊平,米谷紀嗣
    • Organizer
      化学工学会 第48回秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島県徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] 緑色蛍光タンパク質の回転緩和によるカラギーナンのゾル-ゲル転移の研究2016

    • Author(s)
      山崎真代,米谷紀嗣
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] キャビテーションをベースとした複合プロセスによる 3,4-ジクロロフェノール分解処理2016

    • Author(s)
      竹内柊平,米谷紀嗣
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] 高温高圧下での水を還元剤とする白金担持酸化チタンによるCO2光触媒還元2016

    • Author(s)
      平田章太郎,米谷紀嗣
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Reaction Mechanism of the Oxidative Decomposition of Organochlorine Compounds By Fenton-like Reaction in Subcritical Water2015

    • Author(s)
      Noritsugu Kometani, Reina Takami
    • Organizer
      2015 Annual Meeting of AIChE
    • Place of Presentation
      ソルトレークシティー(アメリカ合衆国)
    • Year and Date
      2015-11-08
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic Reduction of CO2 by Pt-Loaded TiO2 in the Mixture of Sub- and Supercritical Water and CO22015

    • Author(s)
      Noritsugu Kometani, Shoutarou Hirata, Masashi Chikada
    • Organizer
      11th International Symposium on Supercritical Fluids (ISSF 2015)
    • Place of Presentation
      ソウル(大韓民国)
    • Year and Date
      2015-10-11
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 超臨界水・二酸化炭素混合流体中での二酸化炭素光触媒還元2015

    • Author(s)
      米谷紀嗣,近田昌志,平田章太郎
    • Organizer
      光化学討論会
    • Place of Presentation
      大阪市立大学杉本キャンパス(大阪府大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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