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Simple evaluation of adsorption property of miicro-substances using gelled test solutions

Research Project

Project/Area Number 15K00586
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental engineering and reduction of environmental burden
Research InstitutionToyo University

Principal Investigator

SEIDA Yoshimi  東洋大学, 経済学部, 教授 (60216504)

Co-Investigator(Kenkyū-buntansha) 鈴木 孝弘  東洋大学, 経済学部, 教授 (30192131)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords極微量物質 / 水晶振動子マイクロバランス / 吸着 / ゲル / QCM / ナノ粒子 / ゲル化溶媒 / 水晶振動子 / ゆらぎ / アドミッタンス解析 / 有機溶媒 / 結晶ー非結晶 / 温度依存性 / 乾燥
Outline of Final Research Achievements

Quartz crystal microbalances (QCMs) with adsorbents immobilized on the QCM surface were examined. The QCM devices were contacted with a trace amount of VOC gas or gelled test solution with a trace amount of adsorbate. The applicability of the method as a data acquisition method of trace chemicals was examined. Although the gelation of test solutions had an effect on the QCM response, the influence of solvent gelation was small when the gel with high water content was used. When the amount of gelling solvent is small, the effects of solvent drying and gel deformation are not negligible. The influence was clarified from a surface thermography and QCM-A response. It was also clarified that VOC measurement can be available using the QCMs with gel membrane or nanoparticle adsorbent fixed on the QCM with high resolution. In the case of nanoparticle adsorbent, fixation method on the QCM greatly affects viscosity factor of QCM signal due to a fluctuation of the immobilized nanoparticles.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (25 results)

All 2018 2017 2016 2015 Other

All Journal Article (10 results) (of which Int'l Joint Research: 2 results,  Open Access: 6 results,  Peer Reviewed: 7 results,  Acknowledgement Compliant: 4 results) Presentation (13 results) (of which Int'l Joint Research: 3 results) Book (1 results) Remarks (1 results)

  • [Journal Article] キャスト高分子膜の乾燥プロセスにおける粘弾性およびサーモグラフ2018

    • Author(s)
      清田 佳美
    • Journal Title

      東洋大学紀要 自然科学篇

      Volume: 61 Pages: 97-103

    • NAID

      120006029241

    • Related Report
      2017 Annual Research Report
    • Open Access
  • [Journal Article] Determination of intraparticle diffusivity and fluid-to-solid mass transfer coefficient from single concentration history curve in circulated-type fixed-bed reactor2018

    • Author(s)
      N. Sonetaka, Y. Seida, E. Furuya
    • Journal Title

      Adsorption Science and Technology

      Volume: 36 Issue: 1-2 Pages: 571-585

    • DOI

      10.1177/0263617417707866

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Demonstration of QCM Measurement of Water during Its Freezing-Thawing Process2017

    • Author(s)
      Yoshimi Seida
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 50 Issue: 3 Pages: 195-200

    • DOI

      10.1252/jcej.16we013

    • NAID

      130005464559

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Adsorption properties of Stearyl Acrylate gel for VOC observed by QCM-A2017

    • Author(s)
      Yoshimi Seida, Takahiro Suzuki
    • Journal Title

      Macromolecular Symposia

      Volume: 372 Issue: 1 Pages: 132-139

    • DOI

      10.1002/masy.201600161

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Applicability of the KFav Model in the Prediction of Fixed Bed Breakthrough Curve2017

    • Author(s)
      T. Kawakita, Y. Seida, A. Murota, J. Fujiki, E. Furuya
    • Journal Title

      Adsorption Science and Technology

      Volume: 35 Issue: 1-2 Pages: 178-193

    • DOI

      10.1177/0263617416674013

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] キャスト高分子膜の乾燥プロセスにおける粘弾性およびサーモグラフ2017

    • Author(s)
      清田佳美
    • Journal Title

      東洋大学紀要自然科学篇

      Volume: 61 Pages: 97-103

    • NAID

      120006029241

    • Related Report
      2016 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] Adsorption properties of stearyl acrylate-gel for VOC observed by QCM-A2017

    • Author(s)
      Yoshimi Seida, Takahiro Suzuki
    • Journal Title

      Macromolecular Symposia

      Volume: 印刷中

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Quartz Crystal Microbalance Monitoring of Poly(Vinyl Alcohol) Sol during the Freeze-Thaw Process2016

    • Author(s)
      Yoshimi Seida, Mitsuteru Ogawa
    • Journal Title

      Journal Materials Science Research

      Volume: 5 Issue: 3 Pages: 42-51

    • DOI

      10.5539/jmsr.v5n3p42

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] QCMを用いた高粘性試料のアドミッタンス解析2016

    • Author(s)
      清田佳美
    • Journal Title

      東洋大学紀要 自然科学篇

      Volume: 60 Pages: 85-92

    • NAID

      120005820158

    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] Demonstration of QCM Measurement of Viscoelastic Phase Behavior of PVA Sol in Its Freezing-Thawing Process2015

    • Author(s)
      Yoshimi Seida
    • Journal Title

      Macromolecular Symposia

      Volume: 358 Issue: 1 Pages: 176-181

    • DOI

      10.1002/masy.201500061

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] オルガノゲルコーティング QCM の VOC 応答挙動2017

    • Author(s)
      鈴木寛之,清田佳美*,徳山英昭,古谷英二
    • Organizer
      分離技術回年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] Adsorption responses of thermos-responsive organogel coupled with quartz crystal microbalance in response to VOC gases2017

    • Author(s)
      H. Suzuki, Y. Seida, H. Tokuyama, E. Furuya
    • Organizer
      World Congress Chemical Engineering (WCCE) 2017, Barcelona, Spain
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of LCST Control on Gas Adsorption Property in PNIPA-DMAPAA Copolymer Gel2016

    • Author(s)
      Yoshimi SEIDA, Yuto Amano, Eiji Furuya
    • Organizer
      26th Japan Material Research Society
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2016-12-19
    • Related Report
      2016 Research-status Report
  • [Presentation] Influence of Phase Transition Temperature on CO2 Adsorption/Desorption Behavior of Thermo-Responsive Gel Slurry2016

    • Author(s)
      Yuto Amano, Yoshimi SEIDA, Eiji Furuya)
    • Organizer
      AIChE
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2016-11-15
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] オルカノゲルの結晶・非結晶相におけるVOC吸・脱着応答のQCM観測2016

    • Author(s)
      清田佳美, 徳山英昭,鈴木寛之,古谷英二
    • Organizer
      日本吸着学 会研究発表会
    • Place of Presentation
      長崎大学、長崎
    • Year and Date
      2016-11-10
    • Related Report
      2016 Research-status Report
  • [Presentation] クライオQCM-Aを用いるソフトマテリアルの相変化の観測2016

    • Author(s)
      清田佳美,小川光輝
    • Organizer
      化学工学会第48回 秋季大会
    • Place of Presentation
      徳島大学 徳島
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] ポリマー溶液キャスト乾燥過程の粘弾性及びサーモグラフ,化学工学会第48回秋季大 会2016

    • Author(s)
      清田佳美,鈴木孝弘,後藤健彦
    • Organizer
      化学工学会第48回秋季大 会
    • Place of Presentation
      徳島大学 徳島
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] Adsorption and desorption properties of acrylate-acrylic acid gel for VOC observed by QCM-A2016

    • Author(s)
      Yoshimi SEIDA, Takahiro Suzuki
    • Organizer
      Polymer Network Group 2016
    • Place of Presentation
      KTH, Stockholm, Sweden
    • Year and Date
      2016-06-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] アミン共重合した感温性ゲルの相挙動を利用するCO2吸着分離2016

    • Author(s)
      清田佳美, 天野裕斗, 古谷英二
    • Organizer
      分離技術会年会2016
    • Place of Presentation
      日大 生産工学部,津田沼
    • Year and Date
      2016-05-27
    • Related Report
      2016 Research-status Report
  • [Presentation] 反復凍結融解過程におけるPVAゾルの構造形成と水和挙動の相関2016

    • Author(s)
      清田 佳美, 小川 光輝
    • Organizer
      分離技術会年会2016
    • Place of Presentation
      日大 生産工学部,津田沼
    • Year and Date
      2016-05-27
    • Related Report
      2016 Research-status Report
  • [Presentation] 感温性ゲルスラリーの二酸化炭素吸・脱着特性に及ぼすゲル相転移温度の影響2016

    • Author(s)
      天野裕斗,清田佳美, 古谷英二
    • Organizer
      分離技術会年会2016
    • Place of Presentation
      日大 生産工学部,津田沼
    • Year and Date
      2016-05-27
    • Related Report
      2016 Research-status Report
  • [Presentation] ポリマー溶液乾燥過程のQCM-A観測およびサーモグラフ2016

    • Author(s)
      清田 佳美, 鈴木 孝弘, 後藤 健
    • Organizer
      分離技術会年会2016
    • Place of Presentation
      日大 生産工学部,津田沼
    • Year and Date
      2016-05-27
    • Related Report
      2016 Research-status Report
  • [Presentation] ポリマー溶液乾燥過程のQCM観察およびサーモグラフ2016

    • Author(s)
      清田佳美、後藤健彦、鈴木孝弘
    • Organizer
      分離技術会年会2016
    • Place of Presentation
      日本大学生産工学部
    • Year and Date
      2016-05-27
    • Related Report
      2015 Research-status Report
  • [Book] 《高分子、コーティング剤、粘・接着、ガラス、化粧品、食品における》動的粘弾性チャートの解釈事例集 -2016

    • Author(s)
      清田佳美
    • Total Pages
      399
    • Publisher
      技術情報協会
    • Related Report
      2015 Research-status Report
  • [Remarks] 公的資金等による研究の成果

    • URL

      http://www7b.biglobe.ne.jp/~natscireslab_hp/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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