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The study of ammonia production catalyst for automatic fertilization using green chemistry technique

Research Project

Project/Area Number 15K00608
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental conscious materials and recycle
Research InstitutionSendai National College of Technology

Principal Investigator

Endo Tomoaki  仙台高等専門学校, 総合工学科, 教授・副校長(研究・産学連携担当) (60369915)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords包接錯体 / 3次元ボールミル / フラーレン / γ-シクロデキストリン / アンモニア / 触媒 / 三次元ボールミル / 蛍光スペクトル / アンモニア合成 / バイキャップ型包接錯体 / シクロデキストリン / ボールミル / 窒素 / 1,3-ジオン
Outline of Final Research Achievements

Ammonia is produced about 1.5 million tons worldwide in 2010, and 80 to 90% of ammonia is used as fertilizer. Domestically, there are problems of soaring raw material costs and aging facilities, some company is stopping production plants. For the sustainable development of the Earth, it is necessary to develop a newly method to consider how to supply ammonia for fertilization. Here, it is unnecessary to produce ammonia in large quantities in a short time, and a method capable of continuously and stably supplying ammonia is required. For this purpose, we studied the inclusion complex of gamma-cyclodextrin and C60 derivative as catalyst for production of ammonia synthesis. In this research period, we have established a new manufacturing process of catalyst using three-dimensional ball mill.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (10 results)

All 2018 2017 2016 2015

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 2 results) Presentation (7 results) (of which Int'l Joint Research: 5 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] [Dedicated to Prof. T. Okada and Prof. T. Nishioka: data science in chemistry]Classification of Alkaloid Compounds Based on Subring Skeleton (SRS) Profiling: On Finding Relationship of Compounds with Metabolic Pathways2017

    • Author(s)
      Eguchi, R., Ono, N., Horai, H., Amin, M. A. U., Hirai, A. M., Kawahara, J., ... & Kanaya, S.
    • Journal Title

      Journal of Computer Aided Chemistry

      Volume: 18 Issue: 0 Pages: 58-75

    • DOI

      10.2751/jcac.18.58

    • NAID

      130005877929

    • ISSN
      1345-8647
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 地域創生、産学連携にも必要なケモメトリクス2016

    • Author(s)
      遠藤智明、速水健一
    • Journal Title

      CICSJ Bulletin

      Volume: 34 Issue: 3 Pages: 85

    • DOI

      10.11546/cicsj.34.85

    • NAID

      130005169236

    • ISSN
      0913-3747, 1347-2283
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Large Scale Synthesis of water-soluble (γ-Cyclodextrin)2-C60 Complex using Three Dimensional Ball Mill2018

    • Author(s)
      Tomoaki Endo, Daisuke Nagao, Fumiyoshi NAGAO, Yasuak Yamaoka, Eunsang Kwon
    • Organizer
      第98回日本化学会春年会 4F4-19
    • Related Report
      2017 Annual Research Report
  • [Presentation] Large Scale Synthesis of water-soluble (γ-Cyclodextrin)2-C60 Complex using Three Dimensional Ball Mill2018

    • Author(s)
      Tomoaki Endo, Daisuke Nagao, Fumiyoshi NAGAO, Yasuak Yamaoka, Eunsang Kwon
    • Organizer
      第98回日本化学会春年会 1PC-049
    • Related Report
      2017 Annual Research Report
  • [Presentation] Large Scale Synthesis of γ-Cyclodextrin Bicapped C60 Complex using 3-Dimentional Ball Mill2017

    • Author(s)
      Tomoaki Endo, Yasuaki Yamaoka, Daisuke Nagao, Fumiyoshi Nagao, Eunsang Kwon
    • Organizer
      The 17th International Synposium for Nobel Aromatic Compouinds (ISNA-17)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and evaluation of new type of water-soluble fullerne materials2015

    • Author(s)
      Tomoaki Endo, Yasuaki Yamaoka, Eunsang Kwon
    • Organizer
      THE INTERNATIONAL CHEMICAL CONGRESS OF PACIFIC BASIN SOCIETIES 2015
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Evaluation of New Type of Water Soluble Inclusion Complex of γ-Cyclodextrin with 1,3-Dione Adduct [60] Fulleren2015

    • Author(s)
      Tomoaki Endo, Yasuaki Yamaoka, Eunsang Kwon
    • Organizer
      The 13th International Kyoto Conference on New Aspect of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2015-11-09
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Structure of a New Type of γ-Clodextrin Complexed Bulky [60] Fullerene Derivative2015

    • Author(s)
      Tomoaki Endo, Eunsang Kwon
    • Organizer
      The 16th International Synposium for Nobel Aromatic Compouinds (ISNA-16)
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2015-07-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Dynamics of Lithium-Cation in a C60 Fullerene Cage2015

    • Author(s)
      Eunsang Kwon, Kazuhiko Kawachi, Yasuhiko Kasama and Tomoaki Endo
    • Organizer
      The 16th International Synposium for Nobel Aromatic Compouinds (ISNA-16) (Madrid, Spain)
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2015-07-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] 水溶性フラーレンの製造方法2017

    • Inventor(s)
      遠藤 智明、永弘 進一郎、長尾 文喜、長尾 大輔、渡邊 康徳
    • Industrial Property Rights Holder
      独立行政法人国立高等専門学校機構
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-153696
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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