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Development of nontoxic and highly stable multi-color pigments based on the complexation of natural dye with inorganic hosts

Research Project

Project/Area Number 15K00724
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Home economics/Human life
Research InstitutionShizuoka University

Principal Investigator

Kohno Yoshiumi  静岡大学, 工学部, 准教授 (50334959)

Co-Investigator(Kenkyū-buntansha) 福原 長寿  静岡大学, 工学部, 教授 (30199260)
Co-Investigator(Renkei-kenkyūsha) MAEDA Yasuhisa  静岡大学, 工学部, 教授 (00159138)
TOMITA Yasumasa  静岡大学, 工学部, 准教授 (50303532)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords天然色素 / 耐久性 / 有機無機複合材料 / 色材 / 無機層状化合物 / 複合体 / 疎水相互作用 / 発色制御 / メソポーラスシリカ / 複合化 / 安定化
Outline of Final Research Achievements

It was confirmed that natural dye was stabilized by the complexation with various inorganic host materials. Clays with a layered structure was employed as a host material of hydrophobic natural dye, beta-carotene (BC). The interlayer cation of the clay was exchanged by surfactant molecules. The BC molecules was readily introduced into the interlayer of the clay by a strong interaction between the organo-modified clay and the dye molecules, and a deeply colored material was obtained by a rather simple and easy preparing method. The mesoporous silica containing trivalent cations in its framework was also used as a host material of BC. The cations in the framework worked as an acidic site, and the interaction between the acidic site and the BC molecules brought about the significant color change of BC from yellow to blue. The blue-colored BC was as stable as the original yellowish one under visible light irradiation.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (31 results)

All 2018 2017 2016 2015

All Journal Article (14 results) (of which Peer Reviewed: 14 results,  Acknowledgement Compliant: 2 results) Presentation (17 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] An easy and effective method for the intercalation of hydrophobic natural dye into organo-montmorillonite for improved photostabilitycarbon capture2018

    • Author(s)
      Y.Kohno, T.Taguchi, M.Shibata, Y.Tomita, C.Fukuhara, Y.Maeda
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 116C Pages: 168-173

    • DOI

      10.1016/j.jpcs.2018.01.027

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photochromic Properties of 3-Deoxyanthocyanidin Pigments Extracted and Purified from Sorghum Grains2018

    • Author(s)
      Mihara Mai、Tasaki Kumiko、Kohno Yoshiumi、Shibata Masashi
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 91 Issue: 3 Pages: 94-97

    • DOI

      10.4011/shikizai.91.94

    • NAID

      130006581750

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoanodic response of hematite electrode to citric acid in aqueous solution2017

    • Author(s)
      Maeda Yasuhisa、Itoh Yuki、Kodama Daiyu、Kohno Yoshiumi
    • Journal Title

      Journal of Electroanalytical Chemistry

      Volume: 785 Pages: 166-171

    • DOI

      10.1016/j.jelechem.2016.12.031

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Growth of p-type ZnOS films by pulsed laser deposition2017

    • Author(s)
      K. Kobayashi, T. Ohtsuki, Y. Tomita, Y. Kohno, Y. Maeda, S. Matsushima
    • Journal Title

      J. Crystal. Growth

      Volume: 457 Pages: 289-293

    • DOI

      10.1016/j.jcrysgro.2016.06.029

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and electrochemical properties of 4LiF-NiMn2O4 composite as a cathode material for Li-ion batteries2017

    • Author(s)
      Yasumasa Tomita, Noritaka Kimura, Yusuke Izumi, Juichi Arai, Yoshiumi Kohno, Kenkichiro Kobayashi
    • Journal Title

      Journal of Power Sources

      Volume: 354 Pages: 35-40

    • DOI

      10.1016/j.jpowsour.2017.04.003

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of Li-doped NiO on the charge?discharge properties of LiF?NiO composites used as cathode materials for Li-ion batteries2017

    • Author(s)
      Tomita Yasumasa、Kimura Noritaka、Nasu Hiromasa、Izumi Yusuke、Arai Juichi、Yamane Yohei、Yamada Koji、Kohno Yoshiumi、Kobayashi Kenkichiro
    • Journal Title

      Journal of Applied Electrochemistry

      Volume: 47 Issue: 9 Pages: 1057-1063

    • DOI

      10.1007/s10800-017-1104-z

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Substituted Compounds of Lithium Indium Bromide and Fabrication of All Solid-State Battery2017

    • Author(s)
      Tomita Yasumasa、Nishiyama Hiroo、Yamada Koji、Kohno Yoshiumi、Kobayashi Kenkichiro
    • Journal Title

      Recent Innovations in Chemical Engineering

      Volume: 10 Issue: 1 Pages: 12-17

    • DOI

      10.2174/2405520410666170614114423

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Oxidation on Charge-Discharge Property of Iron Fluoride for Li-ion Secondary Battery2016

    • Author(s)
      Yasumasa Tomita, Jinta Kato, Naoki Kamiya, Yoshiumi Kohno, Yasuhisa Maeda, and Kenkichiro Kobayashi
    • Journal Title

      Transactions of the Materials Research Society of Japan

      Volume: 41 Issue: 4 Pages: 375-378

    • DOI

      10.14723/tmrsj.41.375

    • NAID

      130005172508

    • ISSN
      1382-3469, 2188-1650
    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and charge-discharge properties of LiF-NiO composite as a cathode material for Li-ion batteries2016

    • Author(s)
      Yasumasa Tomita, Hiromasa Nasu, Yusuke Izumi, Juichi Arai, Satoshi Otsuka,Yohei Yamane, Koji Yamada, Yoshiumi Kohno, Kenkichiro Kobayashi
    • Journal Title

      Journal of Power Sources

      Volume: 329 Pages: 406-411

    • DOI

      10.1016/j.jpowsour.2016.08.095

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photochromic Properties of 3-Deoxyanthocyanidin Pigments in Nontoxic Solvents2016

    • Author(s)
      Yuki Yagishita, Mai Mihara, Yoshiumi Kohno, and Masashi Shibata
    • Journal Title

      J. Food Sci.

      Volume: 81 Issue: 12

    • DOI

      10.1111/1750-3841.13548

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Simple Method to Make Composites of Hydrophobic Plant-Derived Dye with Organo-Modified Hydrotalcite2016

    • Author(s)
      Yoshiumi Kohno, Nana Ooka, Masashi Shibata, Choji Fukuhara, Yasumasa Tomita, and Yasuhisa Maeda
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 89 Issue: 12 Pages: 414-419

    • DOI

      10.4011/shikizai.89.414

    • NAID

      130005464593

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fixation and stability enhancement of beta-carotene by organo-modified mesoporous silica2016

    • Author(s)
      Yoshiumi Kohno, Yasushi Kato, Masashi Shibata, Choji Fukuhara, Yasuhisa Maeda, Yasumasa Tomita, and Kenkichiro Kobayashi
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 220 Pages: 1-6

    • DOI

      10.1016/j.micromeso.2015.08.019

    • NAID

      120006457910

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photodegradation of Veratryl Alcohol on a Titanium Dioxide Photoelectrode in Aqueous Solution Containing Chloride Ions2015

    • Author(s)
      Daiyu Kodama, Eriko Uchiyama, Yoshiumi Kohno, Yasumasa Tomita, Kenkichiro Kobayashi, and Yasuhisa Maeda
    • Journal Title

      Journal of The Surface Finishing Society of Japan

      Volume: 66 Issue: 9 Pages: 420-424

    • DOI

      10.4139/sfj.66.420

    • NAID

      130005261641

    • ISSN
      0915-1869, 1884-3409
    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation of Composite Comprising Anthocyanidin Dye and HMS-Type Mesoporous Silica and its Color Properties2015

    • Author(s)
      Y.-H. Lin, H. Murakami, Y. Kohno, M. Shibata
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 88 Issue: 11 Pages: 371-377

    • DOI

      10.4011/shikizai.88.371

    • NAID

      130005126237

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 無機ホストと複合化したβカロテンの特異的な色変化2017

    • Author(s)
      河野芳海,浅羽龍真,廣澤展行,塩田淑仁,柴田雅史,前田康久
    • Organizer
      2017年光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機修飾粘土との複合化によるカロテノイド系色素の安定性改善2017

    • Author(s)
      田口大雅,河野芳海,柴田雅史,前田康久
    • Organizer
      色材協会創立90周年記念会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] カロテノイド系天然色素と有機修飾粘土との最適な複合方法の調査2017

    • Author(s)
      田口大雅,河野芳海,柴田雅史,前田康久
    • Organizer
      第48回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 安定化剤の添加によるβ-カロテン/無機ホスト複合体の安定性の向上2017

    • Author(s)
      藤本悠椰,河野芳海,柴田雅史,前田康久
    • Organizer
      第48回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photochromic properties of 3-deoxyanthocyanidin pigments extracted and purified from Sorghum grains2017

    • Author(s)
      Mai Mihara, Kumiko Tasaki, Yoshiumi Kohno, Masashi Shibata
    • Organizer
      90th JSCM Anniversary Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機修飾粘土との複合化によるβ-カロテンの安定性改善2017

    • Author(s)
      田口大雅,河野芳海,柴田雅史,前田康久
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス(神奈川県横浜市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 金属イオン添加メソポーラスシリカへのアニオン性天然色素の吸着2017

    • Author(s)
      竹中祐梨菜,河野芳海,柴田雅史,前田康久
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス(神奈川県横浜市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 天然スピルリナ青色素と各種無機ホストとの複合化2017

    • Author(s)
      天野侑志,河野芳海,柴田雅史,前田康久
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス(神奈川県横浜市)
    • Related Report
      2016 Research-status Report
  • [Presentation] Theoretical study on absorption wavelength control and improvement of light fastness of β-carotene using solid acid2017

    • Author(s)
      Nobuyuki Hirosawa,Yoshihito Shiota,Yoshiumi Kohno,Ryuma Asaba,Kazunari Yoshizawa
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学日吉キャンパス(神奈川県横浜市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 有機修飾粘土との複合化による疎水性天然色素の安定性改善2016

    • Author(s)
      田口大雅,古賀美樹子,柴田雅史,河野芳海,前田康久
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] 無機ホストとの複合化によるβカロテンの発色制御2016

    • Author(s)
      浅羽龍真,河野芳海,柴田雅史,前田康久
    • Organizer
      2016年色材研究発表会
    • Place of Presentation
      大阪大学吹田キャンパス(大阪府吹田市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 有機修飾粘土を用いた疎水性天然色素の安定化2016

    • Author(s)
      田口大雅,河野芳海,柴田雅史,前田康久
    • Organizer
      2016年色材研究発表会
    • Place of Presentation
      大阪大学吹田キャンパス(大阪府吹田市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 無機ホストとの複合化によるβカロテンの発色制御と安定性向上2016

    • Author(s)
      浅羽龍真,河野芳海,柴田雅史,前田康久
    • Organizer
      第47回 中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋技術科学大学(愛知県豊橋市)
    • Related Report
      2016 Research-status Report
  • [Presentation] 有機修飾粘土との複合化による疎水性天然色素の安定性向上2016

    • Author(s)
      田口大雅,河野芳海,柴田雅史,前田康久
    • Organizer
      第47回 中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋技術科学大学(愛知県豊橋市)
    • Related Report
      2016 Research-status Report
  • [Presentation] Enhanced stability of natural dye incorporated in mesoporous silicate2015

    • Author(s)
      Yoshiumi Kohno, Yasuhisa Maeda
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hwaii Convention Center (Honolulu, Hawaii)
    • Year and Date
      2015-12-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金属含有メソポーラスシリカとの複合化によるβカロテンの特異的な色変化とその安定性評価2015

    • Author(s)
      浅羽龍真,樋口駿,河野芳海,柴田雅史,前田康久
    • Organizer
      2015 年色材研究発表会
    • Place of Presentation
      千葉工業大学(千葉県習志野市)
    • Year and Date
      2015-10-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 各種溶媒を用いたアントシアニン系ルテオリニジン色素溶液のフォトクロミック特性2015

    • Author(s)
      八木下優貴,三原麻衣,小笹葉月,河野芳海,柴田雅史
    • Organizer
      2015 年色材研究発表会
    • Place of Presentation
      千葉工業大学(千葉県習志野市)
    • Year and Date
      2015-10-21
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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