Synthesis of graphene on pentacene structure by hot mesh deposition and transfer mechanism of relativistic particles

• Project/Area Number: 15K04611
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Nanomaterials chemistry
• Research Institution: University of Hyogo
• Principal Investigator: Heya Akira 兵庫県立大学, 工学研究科, 准教授 (80418871)
• Co-Investigator(Kenkyū-buntansha): 松尾 直人 兵庫県立大学, 工学研究科, 教授 (10263790)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000); Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
• Keywords: グラフェン / ナノリボン / ペンタセン / 加熱触媒体 / 重合 / ペンタセン多量体 / ホットメッシュ堆積 / ペンタセン気相重合 / 触媒体 / Ni担持W / グラフェン/ペンタセン積層構造 / ペリペンタセン / 水素化 / 膜厚場計測

Outline of Final Research Achievements

We tried to form the graphene film on a quartz substrate using pentacene (C22H14) molecules including a hexagonal lattice. To enhance the pentacene decomposition and graphene formation, the two W catalysts were used. The pentacene dimer (peripentacene) was obtained from pentacene using two heated catalysts. The W supported Ni (WNi) mesh was used as a catalyst to supply the decomposition site (Ni region) and polymerization site (W region) of the pentacene molecules. The decomposition temperature of pentacene molecules for the WNi(100%) mesh was lower than that for the W mesh. The pentacene multimers (N=2-5) were obtained and polymerization reaction can be enhanced by using the WNi(3%).

Research Products

• [Journal Article] Guidelines for bottom-up approach of nanocarbon film formation from pentacene using heated tungsten on quartz substrate without metal catalyst (2018)
  • Author(s): Heya Akira、Matsuo Naoto
  • Journal Title: Japanese Journal of Applied Physics Volume: 57 Issue: 4S Pages: 04FL03-04FL03
  • DOI: 10.7567/jjap.57.04fl03
  • NAID: 210000148962
  • Peer Reviewed
• [Presentation] ペンタセンとNi担持Wメッシュを用いたナノカーボン膜の作製 (2018)
  • Author(s): 部家 彰、山崎 良、松尾 直人
  • Organizer: 第65回応用物理学会春季学術講演会
• [Presentation] Ni担持Wメッシュを用いたペンタセンの分解 (2017)
  • Author(s): 部家 彰、山崎 良、松尾 直人
  • Organizer: 第64回応用物理学会春季学術講演会
  • Place of Presentation: パシフィコ横浜（神奈川県横浜市）
  • Year and Date: 2017-03-15
• [Presentation] 2段Wメッシュを用いたHMD法によるグラフェン作製 (2017)
  • Author(s): 植林 暉仁、部家 彰、松尾 直人
  • Organizer: 材料物性工学談話会
  • Place of Presentation: 京都大学（京都府京都市）
  • Year and Date: 2017-01-13
• [Presentation] Formation of Graphene-Related Organic Film by Hot Mesh Deposition Using W Mesh Supported Ni (2017)
  • Author(s): Akira Heya, Ryo Yamasaki, and Naoto Matsuo
  • Organizer: THE 24th INTERNATIONAL WORKSHOP ON ACTIVE-MATRIX FLATPANEL DISPLAYS AND DEVICES
  • Int'l Joint Research
• [Presentation] 加熱金属メッシュで生成した原子状水素による酸化グラフェンの低温還元 (2017)
  • Author(s): 部家 彰、松尾 直人
  • Organizer: 第14回Cat-CVD研究会
• [Presentation] ペンタセン原料を用いたCu基板上へのグラフェンの低温形成 (2017)
  • Author(s): 部家 彰、松尾 直人
  • Organizer: 第78回応用物理学会秋期学術講演会
• [Presentation] Dimer Formation of Pentacene by Heated Tungsten (2017)
  • Author(s): Akira Heya, Naoto Matsuo
  • Organizer: 2018 International Conference on Solid State Devices and Materials
  • Int'l Joint Research
• [Presentation] 加熱金属線を用いたペンタセンの分解とグラフェン系有機膜の形成 (2016)
  • Author(s): 部家 彰、松尾 直人
  • Organizer: 電子情報通信学会 電子ディスプレイ/シリコン材料・デバイス 研究会
  • Place of Presentation: 奈良先端科学技術大学院大学（奈良県生駒市）
  • Year and Date: 2016-12-12
• [Presentation] Study on graphene formation by Hot mesh deposition (2016)
  • Author(s): Satoshi Fuji, Akira Heya. Naoto Matsuo
  • Organizer: The 23rd International Workshop on Active-Matrix Flatpanel Displays and Devices
  • Place of Presentation: 龍谷大学響都ホール（京都府京都市）
  • Year and Date: 2016-07-07
  • Int'l Joint Research
• [Presentation] Study on graphene formation by hot mesh deposition (2016)
  • Author(s): Satoshi Fuji, Akira Heya and Naoto Matsuo
  • Organizer: THE 23rd INTERNATIONAL WORKSHOP ON ACTIVE-MATRIX FLATPANEL DISPLAYS AND DEVICES
  • Place of Presentation: Ryukoku University Avanti Kyoto Hall (Kyoto, Kyoto)
  • Year and Date: 2016-07-07
  • Int'l Joint Research
• [Presentation] HMD法を用いたグラフェン作製に関する検討 (2016)
  • Author(s): 平野竣、部家彰、 松尾直人
  • Organizer: 材料物性工学談話会2016
  • Place of Presentation: 京都大学（京都府京都市）
  • Year and Date: 2016-01-27
• [Presentation] HMD法によるグラフェン形成に関する検討 (2015)
  • Author(s): 平野竣、部家彰、 松尾直人
  • Organizer: 薄膜材料デバイス研究会 第12回研究集会
  • Place of Presentation: 龍谷大学響都ホール（京都府京都市）
  • Year and Date: 2015-10-31
• [Remarks] 兵庫県立大学 教員詳細 部家彰
  • URL: http://www.gokakunin2.com/03/7010/eng/outline/faculty/heya/index.html