Analysis of atomic arrangement structure of novel nanoparticles and thin films of a non-long periodic system

• Project/Area Number: 15K04616
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Nanomaterials chemistry
• Research Institution: National Institute for Materials Science
• Principal Investigator: Sakata Osami 国立研究開発法人物質・材料研究機構, 技術開発・共用部門, ステーション長 (40215629)
• Research Collaborator: Song Chulho ; Kumara Loku Singgappulige Rosantha ; Chen Yanna ; Yang Anli ; Okkyun Seo ; Hiroi Satoshi ; Kim Jaemyung ; Akhil Tayal ; Natalia Palina
• Project Period (FY): 2015-04-01 – 2019-03-31
• Project Status: Completed (Fiscal Year 2018)
• Budget Amount: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
• Keywords: 金属ナノ粒子 / 酸化物薄膜 / シンクロトロンX線 / 原子配列構造 / 電子構造 / X線全散乱 / X線分光 / 構造秩序 / 高エネルギーX線回折 / 2体分布関数解析 / X線吸収微細構造分光 / ナノ粒子-MOFハイブリッド材料 / ナノ粒子 / 薄膜 / シンクロトロンＸ線 / 電子状態 / 高エネルギーX線全散乱 / 硬X線光電子分光 / Ruナノ粒子 / 近ー中距離構造 / 平均構造 / 構造秩序パラメータ / Rh-Cu合金ナノ粒子 / 酸化数 / ルテニウムナノ粒子 / 2体分布関数 / 原子-原子-原子の角度分布 / 配位数 / 酸化物半導体薄膜 / デバイ温度

Outline of Final Research Achievements

We investigated the relationship of the atomic arrangement and the electronic structure of metal nanoparticles, nanostructures and oxide thin film materials with the functions and properties. After analyzing the average structure, local structure and electronic structure of nanometer-sized metal particles (Ru, Rh, Pd-Pt, Rh-Cu) with hydrogen storage characteristics and CO oxidation performance using synchrotron X-ray techniques, we discussed the correlation with the characteristic properties. Moreover, the electronic state was investigated also about the metal nanostructural materials. Furthermore, the structural order and the electronic state of the oxide thin films were examined, and the relationship with the optical characteristics was discussed. The utilized synchrotron X-ray techniques were high energy X-ray total scattering, Rietveld analysis, tpair distribution function, reverse Monte Carlo modeling, X-ray absorption fine structure, hard X-ray photoelectron spectroscopy.

Academic Significance and Societal Importance of the Research Achievements

調べたナノ粒子、ナノ構造体、酸化物薄膜は工学的、あるいは産業応用的に重要な材料である。本研究で得られた、原子配列構造や電子構造の知見を材料の作成にフィードバックすることで、それらの材料の機能を向上させることに役立つと期待している。

Research Products

• [Journal Article] Correlation between the electronic/local structure and CO-oxidation activity of PdxRu1-x alloy nanoparticles (2019)
  • Author(s): Song Chulho、Tayal Akhil、Seo Okkyun、Kim Jaemyung、Chen Yanna、Hiroi Satoshi、Kumara L. S. R.、Kusada Kohei、Kobayashi Hirokazu、Kitagawa Hiroshi、Sakata Osami
  • Journal Title: Nanoscale Advances Volume: 1 Issue: 2 Pages: 546-553
  • DOI: 10.1039/c8na00305j
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Effects of interfacial structure of Pd?Pt nanoparticles on hydrogen solubility (2019)
  • Author(s): Tayal Akhil、Seo Okkyun、Kim Jaemyung、Kumara L.S.R.、Song Chulho、Hiroi Satoshi、Chen Yanna、Kobayashi Hirokazu、Kitagawa Hiroshi、Sakata Osami
  • Journal Title: Journal of Alloys and Compounds Volume: 791 Pages: 1263-1269
  • DOI: 10.1016/j.jallcom.2019.03.342
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Tuning of structural, optical band gap, and electrical properties of room-temperature-grown epitaxial thin films through the Fe2O3:NiO ratio (2019)
  • Author(s): Seo Okkyun、Tayal Akhil、Kim Jaemyung、Song Chulho、Chen Yanna、Hiroi Satoshi、Katsuya Yoshio、Ina Toshiaki、Sakata Osami、Ikeya Yuki、Takano Shiori、Matsuda Akifumi、Yoshimoto Mamoru
  • Journal Title: Scientific Reports Volume: 9 Issue: 1 Pages: 4304-4304
  • DOI: 10.1038/s41598-019-41049-9
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Size effects on rhodium nanoparticles related to hydrogen-storage capability (2018)
  • Author(s): Song Chulho、Yang Anli、Sakata Osami、Kumara L. S. R.、Hiroi Satoshi、Cui Yi-Tao、Kusada Kohei、Kobayashi Hirokazu、Kitagawa Hiroshi
  • Journal Title: Physical Chemistry Chemical Physics Volume: 20 Issue: 22 Pages: 15183-15191
  • DOI: 10.1039/c8cp01678j
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Local Geometry and Electronic Properties of Nickel Nanoparticles Prepared via Thermal Decomposition of Ni-MOF-74 (2018)
  • Author(s): Tayal Akhil、Chen Yanna、Song Chulho、Hiroi Satoshi、Kumara L. S. R.、Palina Natalia、Seo Okkyun、Mukoyoshi Megumi、Kobayashi Hirokazu、Kitagawa Hiroshi、Sakata Osami
  • Journal Title: Inorganic Chemistry Volume: 57 Issue: 16 Pages: 10072-10080
  • DOI: 10.1021/acs.inorgchem.8b01230
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Electronic origin of hydrogen storage in MOF-covered palladium nanocubes investigated by synchrotron X-rays (2018)
  • Author(s): Chen Yanna、Sakata Osami、Nanba Yusuke、Kumara Loku Singgappulige Rosantha、Yang Anli、Song Chulho、Koyama Michihisa、Li Guangqin、Kobayashi Hirokazu、Kitagawa Hiroshi
  • Journal Title: Communications Chemistry Volume: 1 Issue: 1
  • DOI: 10.1038/s42004-018-0058-3
  • NAID: 120006529731
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Lattice constant, bond-orientational order, and solid solubility of PdPt bimetallic nanoparticles (2018)
  • Author(s): Seo Okkyun、Kim Jaemyung、Hiroi Satoshi、Song Chulho、Kumara L. S. R.、Tayal Akhil、Chen Yanna、Kobayashi Hirokazu、Kitagawa Hiroshi、Sakata Osami
  • Journal Title: Applied Physics Letters Volume: 113 Issue: 7 Pages: 071907-071907
  • DOI: 10.1063/1.5040661
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Stacking fault density and bond orientational order of fcc ruthenium nanoparticles (2017)
  • Author(s): Okkyun Seo, Osami Sakata, Jae Myung Kim, Satoshi Hiroi, Chulho Song, L. S. R. Kumara, Koji Ohara, Shun Dekura, Kohei Kusada, Hirokazu Kobayashi, and Hiroshi Kitagawa
  • Journal Title: Applied Physics Letters Volume: 111 Issue: 25 Pages: 253101-253101
  • DOI: 10.1063/1.5006830
  • Peer Reviewed / Open Access
• [Journal Article] Lattice distortion and electronic structure of magnesium-doped nickel oxide epitaxial thin films (2017)
  • Author(s): Y. Chen, Osami Sakata, R. Yamauchi, A. Yang, L. S. R. Kumara, C. Song, N. Palina, M. Taguchi, T. Ina, Y. Katsuya, H. Daimon, A. Matsuda, and M. Yoshimoto
  • Journal Title: Physical Review B Volume: 95 Issue: 24
  • DOI: 10.1103/physrevb.95.245301
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Hydrogen storage and stability properties of Pd-Pt solid-solution nanoparticles revealed via atomic and electronic structure (2017)
  • Author(s): L. S. R. Kumara, Osami Sakata, H. Kobayashi, C. Song, S. Kohara, T. Ina, T. Yoshimoto, S. Yoshioka, S. Matsumura, & H. Kitagawa
  • Journal Title: Scientific Report Volume: 7 Issue: 1 Pages: 14606-14616
  • DOI: 10.1038/s41598-017-14494-7
  • NAID: 120007006233
  • Peer Reviewed / Open Access
• [Journal Article] Electronic Structure Evolution with Composition Alteration of RhxCuy Alloy Nanoparticles (2017)
  • Author(s): N. Palina, O. Sakata, L. S. R. Kumara, C. Song, K. Sato, K. Nagaoka, T. Komatsu, H. Kobayashi, K. Kusada, H. Kitagawa
  • Journal Title: Scientific Reports Volume: 7 Issue: 1 Pages: 41264-41264
  • DOI: 10.1038/srep41264
  • Peer Reviewed / Open Access
• [Journal Article] Size Dependence of Structural Parameters in fcc and hcp Ru Nanoparticles, Revealed by Rietveld Refinement Analysis of High-energy X-ray Diffraction Data (2016)
  • Author(s): C. Song, O. Sakata, L. S. R. Kumara, S. Kohara, A. Yang, K. Kusada, H. Kobayashi, H. Kitagawa
  • Journal Title: Scientific Reports Volume: 6 Issue: 1 Pages: 31400-31400
  • DOI: 10.1038/srep31400
  • NAID: 120005860052
  • Peer Reviewed / Open Access
• [Journal Article] Origin of the Catalytic Activity of Face-Centered-Cubic Ruthenium Nanoparticles Determined from an Atomic-Scale Structure (2016)
  • Author(s): L. S. R. Kumara, O. Sakata, S. Kohara, A. Yang, C. Song, K. Kusada, H. Kobayashi, H. Kitagawa
  • Journal Title: Physical Chemistry Chemical Physics Volume: 18 Issue: 44 Pages: 30622-30629
  • DOI: 10.1039/c6cp04088h
  • NAID: 120005856165
  • Peer Reviewed / Open Access
• [Journal Article] Atomic disorder of Li0.5Ni0.5O thin films caused by Li doping: estimation from x-ray Debye-Waller factors (2015)
  • Author(s): A. Yang, O. Sakata, R. Yamauchi, L. S. R. Kumara, C. Song, Y. Katsuya, A. Matsuda, M. Yoshimoto
  • Journal Title: Journal of Applied Crystallography Volume: 48 Issue: 6 Pages: 1896-1900
  • DOI: 10.1107/s1600576715020002
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Presentation] Synchrotron X-ray Characterization of Mg Doped NiO Epitaxial Thin Films (2018)
  • Author(s): Yanna Chen
  • Organizer: Progress In Electromagnetics Research Symposium (PIERS 2018)
  • Int'l Joint Research
• [Presentation] A 3D structural study of hydrogenated and non-hydrogenated amorphous In-Ga-Zn-O thin films (2017)
  • Author(s): L. S. R. Kumara, 坂田修身, 石川 恭兵, 小原真司, 平松 秀典, 細野 秀雄, 神谷 利夫
  • Organizer: 第64回応用物理学会春季学術講演会
  • Place of Presentation: パシフィコ横浜
  • Year and Date: 2017-03-17
• [Presentation] fcc、hcp構造を有する各のRuナノ粒子の原子配列構造 (2017)
  • Author(s): 坂田修身, L. S. R. Kumara, 宋哲昊, 小原真司, 草田康平, 小林浩和, 北川宏
  • Organizer: 第30回日本放射光学会年会・放射光科学合同シンポジウム
  • Place of Presentation: 神戸市・神戸芸術センター
  • Year and Date: 2017-01-08
• [Presentation] Information we obtained as to electronic states and atomic arrangements of functional nanoparticles using synchrotron-based x-ray techniques (2017)
  • Author(s): Osami Sakata
  • Organizer: OIST Mini Symposium "Nanoclusters in Action"
  • Int'l Joint Research / Invited
• [Presentation] Introduction of the NIMS beamline BL15XU at SPring-8 and our research activities (2017)
  • Author(s): Osami Sakata
  • Organizer: Open forum on “Photon and Advanced Materials Characterizations -Mehr Licht!”
  • Invited
• [Presentation] Pd-Pt 固溶体ナノ粒子の局所構造と電子構造 (2017)
  • Author(s): 坂田修身, L.S.R. Kumara, 宋哲昊, 小原真司, 吉本敏規, 吉岡聰, 松村 晶, 小林浩和, 北川宏
  • Organizer: 平成29年度 日本結晶学会年会
• [Presentation] Size effects on Rhodium nanoparticles related to hydrogen-storage ability (2017)
  • Author(s): Chulho Song, O. Sakata, L. S. R. Kumara, S. Hiroi, K. Kusada, H. Kobayashi, and H. Kitagawa
  • Organizer: EMN Summit 2017
  • Int'l Joint Research
• [Presentation] Stacking fault density and bond orientational order of fcc ruthenium nanoparticles (2017)
  • Author(s): Okkyun Seo, Osami Sakata, Jae Myung Kim, Satoshi Hiroi, Chulho Song, Loku Singgappulige Rosantha Kumara, Koji Ohara, Shun Dekura, Kohei Kusada, Hirokazu Kobayashi, and Hiroshi Kitagawa
  • Organizer: EMN Summit 2017
  • Int'l Joint Research
• [Presentation] Synchrotron X-ray characterization of MgxNi1-xO epitaxial thin films (2017)
  • Author(s): Y. Chen, O. Sakata, R. Yamauchi, A. Yang, L.S.R. Kumara, C. Song, N. Palina, M. Taguchi, T. Ina, Y. Katsuya, H. Daimon, A. Matsuda, and M. Yoshimoto
  • Organizer: EMN Summit 2017
  • Int'l Joint Research
• [Presentation] Electronic states and atomic arrangements of functional nanoparticles obtained from synchrotron-based x-ray characterization (2017)
  • Author(s): O. Sakata, L. S. R. Kumara, C. Song, Y. Chen, O. Seo, K. Kusada, H. Kobayashi, and H. Kitagawa
  • Organizer: EMN Summit 2017
  • Int'l Joint Research / Invited
• [Presentation] Pdナノ結晶中の固溶水素の電子状態 (2017)
  • Author(s): 出倉駿・小林浩和 ・池田龍一・前里光彦・Loku Singgappulige Rosantha Kumara・ 坂田修身・北川宏
  • Organizer: 第68回コロイドおよび界面化学討論会
• [Presentation] Synchrotron-based X-ray Characterization of Metal Nanoparticles and Epitaxial Thin Films (2017)
  • Author(s): Osami Sakata, Loku Singgappulige Rosantha Kumara, Chulho Song1, Natalia Palina, Chen Yanna
  • Organizer: ACCEL日英シンポジウム2017
  • Int'l Joint Research / Invited
• [Presentation] Synchrotron X-ray studies of electronic states and atomic structures of functional nanoparticles (2016)
  • Author(s): O. Sakata, L. S. R. Kumara, C. Song, N. Mueller, S. Kohara, K. Kusada, H. Kobayashi, H. Kitagawa
  • Organizer: AsCA2016 The 14th Conference of Asian Crystallographic Association
  • Place of Presentation: ベトナム・ハノイ Hanoi University of Science and Technology (HUST)
  • Year and Date: 2016-12-05
  • Int'l Joint Research / Invited
• [Presentation] Pair distribution function and reverse Monte Carlo study of Pd nanoparticles based on high-energy x-ray diffraction (2016)
  • Author(s): L. S. R. Kumara, 坂田修身, 小原真司, 宋哲昊, 小林 浩和, 北川 宏
  • Organizer: 日本結晶学会平成28年度年会
  • Place of Presentation: 茨城県立県民文化センター
  • Year and Date: 2016-11-18
• [Presentation] X線回折によるエピタキシャルMgxNi1-xO薄膜の原子配列の秩序度の評価 (2016)
  • Author(s): 坂田修身, CHEN Yanna, L. S. R. Kumara, 宋哲昊, PALINA Natalia, 勝矢良雄, 山内涼輔, 松田晃史, 吉本護
  • Organizer: 日本結晶学会平成28年度年会
  • Place of Presentation: 茨城県立県民文化センター
  • Year and Date: 2016-11-18
• [Presentation] シンクロトロンＸ線回折と硬Ｘ線光電子分光によるMgxNi1-xO エピタキシャル薄膜の原子スケール構造と電子構造の解析 (2016)
  • Author(s): 坂田修身, L. S. R. Kumara, 宋哲昊,小原真司,草田康平, 小林浩和,北川宏
  • Organizer: 第77回応用物理学会秋季学術講演会
  • Place of Presentation: 新潟県・朱鷺メッセ
  • Year and Date: 2016-09-13
• [Presentation] Atomic scale structure of face-centered cubic ruthenium nanoparticles by high-energy X-ray diffraction (2016)
  • Author(s): Osami Sakata, L. S. R. Kumara, Chulho Song, Shinji Kohara, Kohei Kusada, Hirokazu Kobayashi and Hiroshi Kitagawa
  • Organizer: 20th International Vacuum Congress IVC-20
  • Place of Presentation: 韓国・釜山 Busan Exhibition and Convention Center
  • Year and Date: 2016-08-25
  • Int'l Joint Research
• [Presentation] RhCu Nanoparticles: Electronic Structure Evolution (2016)
  • Author(s): Osami Sakata, L. S. R. Kumara, Chulho Song, Natalia Palina, Yanna Chen,Hirokazu Kobayashi, Kohei Kusada,and Hiroshi Kitagawa
  • Organizer: 2016 JapanGermany Joint Symposium on Advanced Characterization of Nanostructured Materials for Energy and Environment
  • Place of Presentation: ドイツ・デュッセルドルフ
  • Year and Date: 2016-06-28
  • Int'l Joint Research
• [Presentation] PdxPt1-x合金ナノ粒子の電子状態と原子スケール構造解析 (2016)
  • Author(s): 坂田 修身，L. S. R. Kumara，宋 哲昊，小原 真司，小林 浩和，北川 宏
  • Organizer: ナノ学会第14回大会
  • Place of Presentation: 北九州市 北九州国際会議場
  • Year and Date: 2016-06-14
• [Presentation] Synchrotron x-ray studies of newly synthesized nanoparticles using diffraction and spectroscopy (2016)
  • Author(s): O.Sakata
  • Organizer: Korean Physical Society Meeting 韓国物理学会 2016年春の学術論文発表会
  • Place of Presentation: Daejeon Convention Center (DCC), Daejeon, Korea
  • Year and Date: 2016-04-22
  • Int'l Joint Research / Invited
• [Presentation] Atomic-scale and electronic structure of fcc- and hcp-type Ru nanosized catalyst (2016)
  • Author(s): 坂田修身, L. S. R. Kumara, 宋哲昊, A. YANG, 小原真司, 草田康平, 小林浩和, 北川宏
  • Organizer: 第63回応用物理学会春季学術講演会
  • Place of Presentation: 東京工業大学大岡山キャンパス
  • Year and Date: 2016-03-19
• [Presentation] Size-effect of Pd and Ru nanoparticles revealed by rietveld analysis using high-energy X-ray diffraction (2016)
  • Author(s): 宋哲昊, 坂田修身, L. S. R. Kumara, 小原真司, 草田康平, 小林浩和, 北川宏
  • Organizer: 第63回応用物理学会春季学術講演会
  • Place of Presentation: 東京工業大学大岡山キャンパス
  • Year and Date: 2016-03-19
• [Presentation] Electronic structural study of Pd-Pt bimetallic alloy nanoparticles (2016)
  • Author(s): L. S. R. Kumara, 坂田修身, 宋哲昊, A. Yang, 草田 康平, 小林 浩和, 北川 宏
  • Organizer: 第63回応用物理学会春季学術講演会
  • Place of Presentation: 東京工業大学大岡山キャンパス
  • Year and Date: 2016-03-19
• [Presentation] Nanoparticle studies using synchrotron X-ray techniques of hard X-ray photoelectron spectroscopy and high-energy X-ray scattering (2015)
  • Author(s): O. Sakata, M. Koyama, H. Kitagawa
  • Organizer: The International Conference on Small Science 2015
  • Place of Presentation: タイ王国 プーケット
  • Year and Date: 2015-11-05
  • Int'l Joint Research / Invited
• [Presentation] Structures of bimetallic nanoparticles by total X-ray scattering method (2015)
  • Author(s): L. S. R. Kumara, 坂田修身, 小原真司, 宋哲昊, 草田 康平, 小林 浩和, 北川 宏
  • Organizer: 日本結晶学会年会 平成27年度年会
  • Place of Presentation: 大阪府立大学
  • Year and Date: 2015-10-18
• [Presentation] 高輝度放射光X線回折による原子配列の乱れの解析： 金属ナノ粒子と酸化物エピタキシャル薄膜 (2015)
  • Author(s): 坂田修身
  • Organizer: 日本セラミックス協会第28回秋季シンポジウム
  • Place of Presentation: 富山大学
  • Year and Date: 2015-09-16
  • Invited
• [Presentation] Size dependence in the electronic structure of fcc- and hcp-type Ru nanoparticles (2015)
  • Author(s): L. S. R. Kumara, 坂田修身, A. Yang, 草田 康平, 小林 浩和, 北川 宏
  • Organizer: 第76回応用物理学会秋季学術講演会
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2015-09-14
• [Presentation] Lattice distortion and temperature factor of Ru nanoparticles revealed by rietveld analysis using high-energy X-ray diffraction (2015)
  • Author(s): 宋哲昊, 坂田修身, L. S. R. Kumara, 小原真司, 草田康平, 小林浩和, 北川宏
  • Organizer: 第76回応用物理学会秋季学術講演会
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2015-09-14
• [Presentation] Thin film and nanoparticle studies using synchrotron X-ray diffraction and hard X-ray photoelectron spectroscopy (2015)
  • Author(s): O. Sakata
  • Organizer: 8th International Conference on Materials for Advanced Technology of the Materials Research Society of Singapore
  • Place of Presentation: シンガポール Suntec Singapore Convention & Exhibition Centre
  • Year and Date: 2015-06-30
  • Int'l Joint Research / Invited
• [Presentation] Nanoparticle studies using advanced synchrotron-based X-ray techniques (2015)
  • Author(s): O. Sakata, L. S. R. Kumara, A. YANG, C. Song, S. Kohara
  • Organizer: Japan-Spain Joint Symposium on Heterogeneous Catalysis
  • Place of Presentation: スペイン Institute of Chemical Research of Catalonia
  • Year and Date: 2015-06-23
  • Int'l Joint Research / Invited
• [Remarks] 坂田修身｜研究者総覧SAMURAI
  • URL: https://samurai.nims.go.jp/profiles/sakata_osami
• [Remarks]
  • URL: http://www.researcherid.com/ProfileView.action?returnCode=ROUTER.Success&Init=Yes&SrcApp=CR&queryString=KG0UuZjN5Wn3gwA6mL71llxe9sFsVTX65J5BwEQHdW0%253D&SID=E4w5CCjkassEHJFMRvt
• [Remarks] Ruナノ粒子の構造と触媒活性との関連を見いだす
  • URL: http://www.spring8.or.jp/ja/news_publications/press_release/2016/161028/
• [Remarks] 組成が違っても触媒活性が同等な新規Rh-Cuナノ粒子の電子状態の観測
  • URL: http://www.spring8.or.jp/ja/news_publications/press_release/2017/170125/
• [Remarks] NIMS Researchers Database SAMRAI
  • URL: http://samurai.nims.go.jp/SAKATA_Osami-e.html
• [Remarks] RESEARCHERID
  • URL: http://www.researcherid.com/rid/H-2621-2011