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Formation and reaction control of silicon nanostructures by vacuum thermal decomposition

Research Project

Project/Area Number 15K04618
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials engineering
Research InstitutionHirosaki University

Principal Investigator

ENTA YOSHIHARU  弘前大学, 理工学研究科, 准教授 (20232986)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsシリコン酸化膜 / 熱脱離 / ボイド / ナノ構造 / 電子線照射 / 還元反応 / 電子顕微鏡
Outline of Final Research Achievements

Silicon oxides, which are widely used as gate insulators of metal oxide semiconductor field-effect transistors in integrated circuits, have been investigated from the viewpoint of thermal stability, surface reaction, and new nano-structure formation by heating in vacuum. The obtained results are as follows. (1) During heating in vacuum, voids in the oxide layer are frequently formed at sites of adhesion of silicon particles. (2) By exposing organic compounds gas to the surface during cooling, nano-ring structures are obviously formed inside the voids. (3) The shape of the voids are controlled by surface orientation of the silicon substrate.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (33 results)

All 2018 2017 2016 2015

All Journal Article (11 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 8 results,  Open Access: 3 results) Presentation (22 results) (of which Int'l Joint Research: 5 results)

  • [Journal Article] Effects of source gases on the properties of silicon/nitrogen-incorporated diamond-like carbon films prepared by plasma-enhanced chemical vapor deposition2017

    • Author(s)
      Nakazawa Hideki、Magara Kohei、Takami Takahiro、Ogasawara Haruka、Enta Yoshiharu、Suzuki Yushi
    • Journal Title

      Thin Solid Films

      Volume: 636 Pages: 177-182

    • DOI

      10.1016/j.tsf.2017.05.046

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Activation Energy of Thermal Desorption of Silicon Oxide Layers on Silicon Substrates2017

    • Author(s)
      Yoshiharu Enta, Shodai Osanai, Takahito Ogasawara
    • Journal Title

      Surface Science

      Volume: 656 Pages: 96-100

    • DOI

      10.1016/j.susc.2016.10.007

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of Temperature and Pressure in Oxynitridation Kinetics on Si(100) with N2O Gas2017

    • Author(s)
      Yoshiharu Enta, Makoto Wada, Mariko Arita, Takahiro Takami
    • Journal Title

      Materials Science in Semiconductor Processing

      Volume: 印刷中 Pages: 63-67

    • DOI

      10.1016/j.mssp.2016.10.025

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of graphene/SiC/AlN multilayers synthesized by pulsed laser deposition on Si(110) substrates2016

    • Author(s)
      S. Narita, K. Meguro, T. Takami, Y. Enta, H. Nakazawa
    • Journal Title

      Journal of Crystal Growth

      Volume: 460 Pages: 27-36

    • DOI

      10.1016/j.jcrysgro.2016.12.068

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Tribological properties and thermal stability of hydrogenated, silicon/nitrogen-coincorporated diamond-like carbon films prepared by plasma-enhanced chemical vapor deposition2016

    • Author(s)
      Hideki Nakazawa, Saori Okuno, Kohei Magara, Kazuki Nakamura, Soushi Miura, Yoshiharu Enta
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 12 Pages: 1255011-9

    • DOI

      10.7567/jjap.55.125501

    • NAID

      210000147302

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural and electrical properties and current-voltage characteristics of nitrogen-doped diamond-like carbon films on Si substrates by plasma-enhanced chemical vapor deposition2016

    • Author(s)
      Masato Tsuchiya, Kazuki Murakami, Kohei Magara, Kazuki Nakamura, Haruka Ohashi, Kengo Tokuda, Takahiro Takami, Haruka Ogasawara, Yoshiharu Enta, Yushi Suzuki, Satoshi Ando, and Hideki Nakazawa
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 6 Pages: 065502-065502

    • DOI

      10.7567/jjap.55.065502

    • NAID

      210000146590

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ring structures formed inside voids in SiO2 layer on Si(100) during thermal decomposition2016

    • Author(s)
      Yoshiharu Enta, Shodai Osanai, Taichi Yoshida
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 2 Pages: 028004-028004

    • DOI

      10.7567/jjap.55.028004

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Angle-Resolved and Resonant Photoemission Study of the Valence Bands of α-La(0001) on W(110)2016

    • Author(s)
      Yoshiharu Enta, Osamu Morimoto, Hiroo Kato, Yasuo Sakisaka
    • Journal Title

      World Journal of Condensed Matter Physics

      Volume: 6 Issue: 01 Pages: 17-26

    • DOI

      10.4236/wjcmp.2016.61003

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Interfacial Structure of Oxynitride Layer on Si(100) with Plasma-Excited N2O2016

    • Author(s)
      Y. Enta
    • Journal Title

      International Journal of Applied and Natural Sciences

      Volume: 5-1 Pages: 63-68

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Dry-Oxidation Rate of Si(100) Surface up to 2 nm-Oxide Thickness2015

    • Author(s)
      Y. Enta, M. Arita, M. Wada
    • Journal Title

      International Journal of Applied and Natural Sciences

      Volume: 4-6 Pages: 51-56

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] シリコン酸窒化膜の内殻準位異常シフトに対する表面吸着種の影響2015

    • Author(s)
      高見 貴弘、和田 誠、遠田 義晴
    • Journal Title

      電子情報通信学会技術研究報告書

      Volume: 115-179 Pages: 71-74

    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] 室温電子線照射によるSiO2膜/Si基板界面でのSi微細構造形成2018

    • Author(s)
      遠田 義晴,増田 悠右,千田 陽介
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電子線照射によるSiO2/Si界面反応2018

    • Author(s)
      遠田義晴
    • Organizer
      半導体薄膜高額の過去・現在・未来 -ICT社会の将来を見据えて-
    • Related Report
      2017 Annual Research Report
  • [Presentation] 真空蒸着と低温アニールによるBi媒介Geナノドット形成-12017

    • Author(s)
      滝田 健介, 対馬 和都, 遠田 義晴, 俵 毅彦, 舘野 功太, 章 国強, 後藤 秀樹, 池田 高之, 水野 誠一郎, 岡本 浩
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 真空蒸着と低温アニールによるBi媒介Geナノドット形成-22017

    • Author(s)
      対馬 和都, 滝田 健介, 中澤 日出樹, 遠田 義晴, 俵 毅彦, 舘野 功太, 章 国強, 後藤 秀樹, 岡本 浩
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 希釈ガスに水素ガスを用いたプラズマ化学気相成長法によるSi/N共添加 DLC 薄膜の作製と評価2017

    • Author(s)
      中村 和樹,大橋 遼, 横山 大, 田島 圭一郎, 遠藤 則史, 末光 眞希, 遠田 義晴, 小林 康之, 中澤 日出樹
    • Organizer
      応用物理学会第72回東北支部学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Electron Beam Irradiation Effects on SiO2 Layer on Silicon Substrate at Room Temperature2017

    • Author(s)
      Yusuke Masuda, Yoshiharu Enta
    • Organizer
      The 8th International Symposium on Surface Science(ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of Organic-Compounds Doses on Silicon Fine Structures Formed in Voids on Silicon Dioxide Layers by Annealing in Vacuum2017

    • Author(s)
      Yoshiharu Enta, Takayuki Nagai, Kano Ogawa, Taichi Yoshida, Shodai Osanai, Takahito Ogasawara, Yoshisumi Tsuchimoto, Chikashi Maita, Natsuki Ujiie, Hideki Nakazawa
    • Organizer
      The 8th International Symposium on Surface Science(ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of nitrogen doping on the chemical bonding states and properties of silicon-doped diamond-like carbon films2017

    • Author(s)
      Kazuki Nakamura, Haruka Ohashi, Tai Yokoyama, Kei-ichiro Tajima, Norifumi Endo, Maki Suemitsu, Yoshiharu Enta, Yasuyuki Kobayashi, Hideki Nakazawa
    • Organizer
      The 8th International Symposium on Surface Science(ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] シリコン基板上シリコン酸化膜の電子線照射による還元反応2017

    • Author(s)
      増田悠右、遠田義晴
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 水素原子を用いた3C-SiC/Si基板上へのグラフェンの低温形成2017

    • Author(s)
      荒畑宏樹、成田克、遠藤則史、末光眞希、遠田義晴、中澤日出樹
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 真空蒸着法によるBi 媒介Ge ナノドットの形成過程評価2017

    • Author(s)
      滝田健介,対馬和都, 遠田義晴, 俵毅彦,舘野功太,章国強,後藤秀樹, 岡本浩
    • Organizer
      平成29年度電気関係学会東北支部連合大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 希釈ガスとしてH2を用いたプラズマCVD法によるDLC膜特性へのSiおよびN添加効果2016

    • Author(s)
      中村 和樹,大橋 遼, 横山 大, 田島 圭一郎, 遠藤 則史, 末光 眞希, 遠田 義晴, 中澤 日出樹
    • Organizer
      応用物理学会第71回東北支部学術講演会
    • Place of Presentation
      東北大学
    • Year and Date
      2016-12-01
    • Related Report
      2016 Research-status Report
  • [Presentation] 希釈ガスに水素ガスを用いたプラズマ化学気相成長法によるSi/N共添加ダイヤモンドライクカーボンの膜特性2016

    • Author(s)
      中村和樹、大橋遼、横山大、田島圭一郎、遠藤則史、末光眞希、遠田義晴、中澤日出樹
    • Organizer
      2016年真空・表面科学合同講演会 第36回表面科学学術講演会 第57回真空に関する連合講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2016-11-29
    • Related Report
      2016 Research-status Report
  • [Presentation] 希釈ガスに水素ガスを用いたプラズマCVD法によるN添加およびSi/N共添加DLC膜の特性比較2016

    • Author(s)
      中村和樹、大橋遼、横山大、田島圭一郎、遠藤則史、末光眞希、遠田義晴、中澤日出樹
    • Organizer
      第30回ダイヤモンドシンポジウム
    • Place of Presentation
      東京大学
    • Year and Date
      2016-11-16
    • Related Report
      2016 Research-status Report
  • [Presentation] Silicon Fine Structures Formed by Thermal Desorption of Silicon Dioxide Layer in Vacuum2016

    • Author(s)
      Yoshiharu Enta, Takayuki Nagai, Kano Ogawa, Taichi Yoshida, Shodai Osanai, Takahito Ogasawara, Yoshisumi Tsuchimoto, Chikashi Maita, Natsuki Ujiie, Hideki Nakazawa
    • Organizer
      Asian Conference on Nanoscience and Nanotechnology 2016
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2016-11-11
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 希釈ガスとしてH2を用いたプラズマCVD法によるDLC膜特性へのSiおよびN添加効果2016

    • Author(s)
      中村 和樹, 大橋 遼, 横山 大, 田島 圭一郎, 遠藤 則史, 末光 眞希, 遠田 義晴, 中澤 日出樹
    • Organizer
      第77回応用物理学会学術講演会
    • Place of Presentation
      朱鷺メッセ新潟コンベンションセンター
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Effects of Temperature and Pressure in Oxynitridation Kinetics on Si(100) with N2O Gas2016

    • Author(s)
      Yoshiharu Enta, Makoto Wada, Mariko Arita, and Takahiro Takami
    • Organizer
      7th International Symposium on Control of Semiconductor Interfaces ISCSI-VII: International SiGe Technology and Device Meeting ISTDM 2016
    • Place of Presentation
      名古屋大学
    • Year and Date
      2016-06-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] シリコン酸化膜熱脱離によるボイド内リング構造形成の雰囲気依存性2016

    • Author(s)
      遠田 義晴,長内 翔大,小笠原 崇仁
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] シリコン酸化膜のボイド状熱脱離とボイド内微細構造2015

    • Author(s)
      遠田義晴,永井孝幸,吉田太祐,長内翔大,小笠原崇仁
    • Organizer
      応用物理学会第70回東北支部学術講演会
    • Place of Presentation
      ホテルアップルランド
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
  • [Presentation] シリコン酸窒化膜内殻準位異常シフトの解析2015

    • Author(s)
      高見貴弘,和田誠,遠田義晴
    • Organizer
      応用物理学会第70回東北支部学術講演会
    • Place of Presentation
      ホテルアップルランド
    • Year and Date
      2015-12-03
    • Related Report
      2015 Research-status Report
  • [Presentation] 気相熱励起N2Oガスを用いたシリコン熱酸窒化反応2015

    • Author(s)
      高見 貴弘,遠田 義晴
    • Organizer
      第76回応用物理学会学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] シリコン酸窒化膜の内殻準位異常シフトに対する表面吸着種の影響2015

    • Author(s)
      高見 貴弘,和田 誠,遠田 義晴
    • Organizer
      電子情報通信学会 電子部品・材料研究会
    • Place of Presentation
      弘前大学
    • Year and Date
      2015-08-10
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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