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Fabrication of high density storage using self-organized organic molecules

Research Project

Project/Area Number 15K04630
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials engineering
Research InstitutionFukuoka University

Principal Investigator

SUZUKI TAKAYUKI  福岡大学, 工学部, 教授 (10580178)

Co-Investigator(Kenkyū-buntansha) 柳生 数馬  福岡大学, 工学部, 助教 (90609471)
Research Collaborator Tochihara Hiroshi  
Project Period (FY) 2015-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2015: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords走査トンネル顕微鏡 / ナノ表面・界面 / 有機半導体
Outline of Final Research Achievements

We found that PTCDA and pentacene molecules were not self-ordered on the missing dimer row formed on the Ge/Si(001) surface. Therefore, in order to investigate its reason, we have curried out STM and DFT studies of initial growth of pentacene thin film on Si(001) substrate, and adsorption and self-ordering of PTCDA molecules on Ge(001). Furthermore, we also studied surface structure of the Si(111)-√7×√3-In that is known to be surface super conductor at low temperature by means of XPS, STM and DFT. Each research result was published in international journals.

Academic Significance and Societal Importance of the Research Achievements

1分子が1ビットに対応する記録媒体が出来れば、現在のフラッシュメモリに代表される記録媒体の記録密度を大幅に向上させることができる。一方、シリコン無機半導体と有機半導体から成るハイブリッド・分子エレクトロニクス素子の実現には、無機・有機半導体界面を原子レベルで観察して制御する技術が重要である。上記2つのデバイスの実現に関連する共通技術として、シリコンやゲルマニウムといった典型的な無機半導体上での、PTCDA分子やペンタセン分子といった典型的なn型有機半導体の化学吸着構造や成長過程を原子レベルで詳細に調べることで、無機・有機半導体界面の構造や性質を制御する方法を研究した。

Report

(5 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (34 results)

All 2019 2018 2017 2016 2015 Other

All Int'l Joint Research (9 results) Journal Article (8 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 7 results,  Acknowledgement Compliant: 3 results) Presentation (17 results) (of which Int'l Joint Research: 5 results)

  • [Int'l Joint Research] University of Warwick(英国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] University of Duisburg-Essen(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Charles University(チェコ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Universytet Wroclawski(ポーランド)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] University of Warwick(英国)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] University of Duisburg-Essen(ドイツ)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] University of Warwick(英国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] University of Duisburg-Essen(ドイツ)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] University of Warwick(英国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Initial Growth of Pentacene Thin Film on Si(001) Substrate2019

    • Author(s)
      Suzuki T.、Yagyu K.、Tochihara H.
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 5 Pages: 2996-3003

    • DOI

      10.1021/acs.jpcc.8b11238

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-ordering of chemisorbed PTCDA molecules on Ge(001) driven by repulsive forces2019

    • Author(s)
      Kocan Pavel、Pieczyrak Barbara、Jurczyszyn Leszek、Yoshimoto Yoshihide、Yagyu Kazuma、Tochihara Hiroshi、Suzuki Takayuki
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 印刷中 Issue: 18 Pages: 9504-9511

    • DOI

      10.1039/c9cp01335k

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Indium coverage of the Si(111)-7×3-In surface2017

    • Author(s)
      Suzuki T.、Lawrence J.、Walker M.、Morbec J. M.、Blowey P.、Yagyu K.、Kratzer P.、Costantini G.
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 3 Pages: 035412-035412

    • DOI

      10.1103/physrevb.96.035412

    • NAID

      130007509711

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Adsorption of PTCDA on Ge(001)2017

    • Author(s)
      P. KOCAN, Y. YOSHIMOTO, K. YAGYU, H. TOCHIHARA, T. SUZUKI,
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 6 Pages: 3320-3326

    • DOI

      10.1021/acs.jpcc.6b09793

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Neutralization of an epitaxial graphene grown on a SiC(0001) by means of palladium2017

    • Author(s)
      Kazuma Yagyu, Kazutoshi Takahashi, Hiroshi Tochihara, Hajime Tomokage, Takayuki Suzuki
    • Journal Title

      APPLIED PHYSICS LETTERS

      Volume: 110 Issue: 13

    • DOI

      10.1063/1.4979083

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Theoretical Study of Cu Intercalation Through a Defect in Zero-Layer Graphene on SiC Surface2017

    • Author(s)
      Yuuichi Orimoto, Kohei Otsuka, Kazuma Yagyu, Hiroshi Tochihara,Takayuki Suzuki, and Yuriko Aoki
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 13 Pages: 7294-7302

    • DOI

      10.1021/acs.jpcc.7b00314

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Chlorine adlayer-templated growth of a hybrid inorganic - organic layered structure on Au(111)2016

    • Author(s)
      I.I. Rzeznicka, H. Horino, K. Yagyu, T. Suzuki, S. Kajimoto, H. Fukumura
    • Journal Title

      Surface Science

      Volume: 印刷中 Pages: 46-50

    • DOI

      10.1016/j.susc.2016.03.007

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Angle resolved photoemission spectroscopy on Pd intercalated graphenes grown on a SiC(0001) surface2016

    • Author(s)
      Kazuma Yagyu, Takayuki Suzuki
    • Journal Title

      Activity Report Synchrotron Light Application Center Saga University 2014-2015

      Volume: 印刷中

    • Related Report
      2015 Research-status Report
  • [Presentation] Si(001)-2×1 表面上のペンタセン薄膜成長のSTM 観察2018

    • Author(s)
      鈴木孝将, 柳生数馬, 栃原浩
    • Organizer
      日本物理学会 2018 年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] SiC(0001)表面に成長したグラフェン膜への ロジウム原子インターカレーション2018

    • Author(s)
      柳生数馬, 栃原浩, 鈴木孝将
    • Organizer
      日本物理学会 2018 年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Initial growth of pentacene thin film on Si(001) substrate2018

    • Author(s)
      T. Suzuki, K. Yagyu, H. Tochihara
    • Organizer
      Pacific Rim Symposium on Surface, Coating & Interfaces 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SiC(0001)表面に成長したグラフェン膜へのロジウム原子吸着2018

    • Author(s)
      柳生数馬, 栃原浩, 鈴木孝将
    • Organizer
      日本物理学会 第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] In吸着Si(111)表面上へのTCNQ吸着2017

    • Author(s)
      鈴木 孝将, J. LAWRENCE, P. BLOWEY, G. COSTANTINI,
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] グラフェンとSiC基板間にインターカレートした金属層の厚さ評価2017

    • Author(s)
      柳生数馬, 大島義文, 栃原浩, 鈴木孝将
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Indium coverage on Si(111)-√7×√3-In surface2017

    • Author(s)
      T. Suzuki, J. Lawrence, M. Walker, J. M. Morbec, P. Blowey, K. Yagyu, P. Kratzer, G. Costantini
    • Organizer
      33rd European Conference On Surface Science (ECOSS 33)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Si(111)-√7×√3-In再構成構造のIn吸着量2017

    • Author(s)
      鈴木 孝将, J. Lawrence, M. Walker, J. M. Morbec, P. Blowey, 柳生 数馬, P. Kratzer, G. Costantini
    • Organizer
      日本物理学会 2017秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Relation of kinds of intercalated metallic atoms and charge transfer2017

    • Author(s)
      Kazuma YAGYU, Hiroshi TOCHIHARA, and Takayuki SUZUKI
    • Organizer
      International Symposium on Epitaxial Graphene (ISEG-2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 微細CPWの高周波伝送特性評価2017

    • Author(s)
      小川剛司, 韓栄建, 崔雲, 末次正, 鈴木孝将
    • Organizer
      応用物理学会九州支部学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Si(111)-√7×√3-In表面上へのTCNQ吸着による表面構造相転移2016

    • Author(s)
      鈴木 孝将, J. LAWRENCE, P. BLOWEY, G. COSTANTINI,
    • Organizer
      物性研短期研究会
    • Place of Presentation
      東京大学・物性研究所
    • Year and Date
      2016-10-31
    • Related Report
      2016 Research-status Report
  • [Presentation] Pd のインターカレーションによる電気的に中性なグラフェンの生成2016

    • Author(s)
      柳生数馬,高橋和敏,栃原 浩,友景 肇,鈴木孝将
    • Organizer
      物性研短期研究会
    • Place of Presentation
      東京大学・物性研究所
    • Year and Date
      2016-10-31
    • Related Report
      2016 Research-status Report
  • [Presentation] Neutralization of an epitaxial graphene on the SiC(0001) by means of palladium intercalation2016

    • Author(s)
      K. YAGYU, K. TAKAHASHI, H. TOCHIHARA, H. TOMOKAGE, T. SUZUKI,
    • Organizer
      The 13th Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures 2016
    • Place of Presentation
      Laboratori Nazionali di Frascati, Rome, Italy
    • Year and Date
      2016-10-09
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Si(111)-√7×√3-In表面上へのTCNQ吸着による表面構造相転移2016

    • Author(s)
      鈴木 孝将, J. LAWRENCE, P. BLOWEY, G. COSTANTINI,
    • Organizer
      日本物理学会 2016年秋季大会
    • Place of Presentation
      金沢大学
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Neutralization of a graphene grown on the SiC(0001) by means of the Pd intercalation2016

    • Author(s)
      K. YAGYU, K. TAKAHASHI, H. TOCHIHARA, H. TOMOKAGE, T. SUZUKI,
    • Organizer
      International conference on Advanced Nano Materials 2016
    • Place of Presentation
      University of Aveiro, Aveiro, Portugal
    • Year and Date
      2016-07-25
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] SiC(0001)表面上に成長したグラフェン膜へのPdインターカレーション2016

    • Author(s)
      柳生数馬,高橋和敏,栃原浩,友景肇,鈴木孝将
    • Organizer
      日本物理学会 第71回年次大会
    • Place of Presentation
      東北学院大
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] SiC(0001)表面上に成長したゼロ層グラフェンへのパラジウムインターカレーション2015

    • Author(s)
      柳生数馬,栃原浩,友景肇,鈴木孝将
    • Organizer
      九州表面・真空研究会2016(兼 第20回九州薄膜表面研究会)
    • Place of Presentation
      九州工業大学戸畑キャンパス
    • Year and Date
      2015-06-13
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2022-02-21  

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