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In-situ structural analysis of organic semiconductor thin films by 2D X-ray diffraction

Research Project

Project/Area Number 15K04647
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied materials
Research InstitutionIwate University

Principal Investigator

YOSHIMOTO Noriyuki  岩手大学, 理工学部, 教授 (80250637)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords有機半導体 / 結晶成長 / X線回折 / 薄膜成長 / 構造解析 / 放射光 / 2D-GIXD / X線回折
Outline of Final Research Achievements

In this study, we have clarified the crystal structures of dialkylated quterthiophenes (Cn-4T, n= 0, 4, 6, 8, 10, 12).) using in situ 2-dimensional grazing-incidence X-ray diffraction (2D-GIXD) during thin-film growth, and the effects of alkyl-chain length on the crystal growth mode, structure and transport properties are elucidated.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (41 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (17 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 16 results) Presentation (20 results) (of which Int'l Joint Research: 9 results,  Invited: 4 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] CINaM/CNRS UMR 7325(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] CNRS(France)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] CINaM CNRS UMR 7325(France)

    • Related Report
      2015 Research-status Report
  • [Journal Article] In situ characterization of the film coverage and the charge transport in the alkylated-organic thin film transistor2018

    • Author(s)
      Takeshi Watanabe, Tomoyuki Koganezawa, Mamoru Kikuchi, Hiroki Muraoka, Satoshi Ogawa, Noriyuki Yoshimoto, and Ichiro Hirosawa
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 57 Issue: 3S2 Pages: 03EG14-03EG14

    • DOI

      10.7567/jjap.57.03eg14

    • NAID

      210000148768

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface morphology of vacuum-evaporated pentacene film on Si substrate studied by in situ grazing-incidence small-angle X-ray scattering: I. The initial stage of formation of pentacene film2018

    • Author(s)
      Ichiro Hirosawa, Takeshi Watanabe, Tomoyuki Koganezawa, Mamoru Kikuchi, and Noriyuki Yoshimoto
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 57 Issue: 3S2 Pages: 03EG12-03EG12

    • DOI

      10.7567/jjap.57.03eg12

    • NAID

      210000148766

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular alignments of σ phase in co-evaporated pentacene and perfluoropentacne film on SiO2 studied by grazing-incidence X-ray diffraction2017

    • Author(s)
      Ichiro Hirosawa, Takeshi Watanabe, Tomoyuki Koganesawa, Keisuke Tada and Noriyuki Yoshimoto
    • Journal Title

      Mol. Cryst. Liq. Cryst. Vol.

      Volume: 654 Issue: 1 Pages: 47-52

    • DOI

      10.1080/15421406.2017.1355212

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The influence of branched alkyl side chains in oligothiophenes on the photovoltaic performance and morphology of solution-processed bulk-heterojunction solar cells2017

    • Author(s)
      I. Ata, S. Ben Dkhil, M. Pfannmller, S. Bals, D. Duch, J.-J. Simon, T. Koganezawa, N. Yoshimoto, C. Videlot-Ackermann, O. Margeat, J. Ackermann and P. Buerle
    • Journal Title

      Org. Chem. Front.

      Volume: 4 Issue: 8 Pages: 1561-1573

    • DOI

      10.1039/c7qo00222j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Side-chain engineering in a thermal precursor approach for efficient photocurrent generation2017

    • Author(s)
      Takahashi Kohtaro、Kumagai Daichi、Yamada Naoya、Kuzuhara Daiki、Yamaguchi Yuji、Aratani Naoki、Koganezawa Tomoyuki、Koshika Sota、Yoshimoto Noriyuki、Masuo Sadahiro、Suzuki Mitsuharu、Nakayama Ken-ichi、Yamada Hiroko
    • Journal Title

      J. Mater. Chem. A

      Volume: 5 Issue: 27 Pages: 14003-14011

    • DOI

      10.1039/c7ta04162d

    • NAID

      120006369665

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved performance of organic photovoltaic cells with PTB7-Th:PC71 BM by optimized solvent evaporation time in electrospray deposition2017

    • Author(s)
      T. Fukuda, A. Toda, K. Takahira, D. Kuzuhara, N. Yoshimoto
    • Journal Title

      Org. Electron.

      Volume: 48 Pages: 96-105

    • DOI

      10.1016/j.orgel.2017.05.049

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The effect of air exposure on the crystal structure of oligo -thiophene thin films investigated using in situ X-ray diffraction2017

    • Author(s)
      T. Watanabe, T. Koganezawa, M. Kikuchi, C. V. Ackermann, J. Ackermann, H. Brisset, N. Yoshimoto and I. Hirosawa
    • Journal Title

      J. Cryst. Growth

      Volume: 468 Pages: 816-820

    • DOI

      10.1016/j.jcrysgro.2017.01.051

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] P-type semiconductor surfactant modified zinc oxide nanorods for hybrid bulk heterojunction solar cells2017

    • Author(s)
      S. Ben Dkhil, M. Gaceur, W. Dachraoui, D. Hannani, S. Fall, F. Brunel, M. Wang, G. Poize, J. Mawyin, I. Shupyk, C. Martini, E. Shilova, F. Fages, T. Ishwara, J. Nelson, T.Watanabe, N. Yoshimoto, O. Margeat, C. Videlot-Ackermann, and J. Ackermann
    • Journal Title

      Solar Energy Materials and Solar Cells

      Volume: 159 Pages: 608-616

    • DOI

      10.1016/j.solmat.2016.01.006

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A new instrumentation for in situ characterization of the charge transport and crystallographic properties in co-evaporated organic thin film transistor2016

    • Author(s)
      Takeshi Watanabe, Mamoru Kikuchi, Kousaku Nishida, Tomoyuki Koganezawa, Ichiro Hirosawa, Noriyuki Yoshimoto
    • Journal Title

      Mol. Cryst. Liq. Cryst.

      Volume: 636 Issue: 1 Pages: 168-175

    • DOI

      10.1080/15421406.2016.1201411

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Square-Centimeter-Sized High-Efficiency Polymer Solar Cells: How the Processing Atmosphere and Film Quality Influence Performance at Large Scale2016

    • Author(s)
      Sadok Ben Dkhil, Martin Pfannm, Sara Bals, Tomoyuki Koganezawa, Noriyuki Yoshimoto, Driss Hannani, Meriem Gaceur, Christine Videlot-Ackermann, Olivier Margeat, Jorg Ackermann,
    • Journal Title

      Adovanced Energy Materials

      Volume: 6 Issue: 13 Pages: 1600290-1600290

    • DOI

      10.1002/aenm.201600290

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 放射光を用いた有機半導体薄膜形成素過程の解明 吉本則之、菊池護2016

    • Author(s)
      吉本則之、菊池護
    • Journal Title

      金属

      Volume: 86 Pages: 687-691

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Tuning the Work Function of Graphene with the Adsorbed Organic Molecules: First-Principles Calculations2016

    • Author(s)
      Kazume Nishidate, Noriyuki Yoshimoto, Peerasak Chantngarm, Hiroaki Saito, Masayuki Hasegawa
    • Journal Title

      Mol. Phys.

      Volume: 114 Issue: 20 Pages: 2993-2998

    • DOI

      10.1080/00268976.2016.1213437

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] ontrolled donor-accepter ratio for application of organic photovoltaic cells by alternative intermitternt electrospray co-deposition2016

    • Author(s)
      Takeshi Fukuda, Katsumi Suzuki, Noriyuki Yoshimoto, Yingjie Liao
    • Journal Title

      Organic Electronics

      Volume: 33 Pages: 32-39

    • DOI

      10.1016/j.orgel.2016.03.011

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Observation of electric potential in organic thin-film transistor by bias applied hard X-ray photoemission spectroscopy2016

    • Author(s)
      Takeshi Watanabe, Keisuke Tada, Satoshi Yasuno, Hiroshi Oji, Noriyuki Yoshimoto and Ichiro Hirosawa
    • Journal Title

      Jpn J. Appl. Phys.

      Volume: 55 Issue: 3S2 Pages: 03DD12-03DD12

    • DOI

      10.7567/jjap.55.03dd12

    • NAID

      210000146200

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Depth profile of electric potential of metal-coated pentacene films on SiO2 studied by Hard X-ray Photoelectron Spectroscopy under applied bias voltage2016

    • Author(s)
      Ichiro Hirosawa, Takeshi Watanabe, Hiroshi Oji, Satoshi Yasuno, Keisuke Tada, and Noriyuki Yoshimoto
    • Journal Title

      Jpn J. Appl. Phys.

      Volume: 55

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] P-type semiconductor surfactant modified zinc oxide nanorods for hybrid bulk heterojunction solar cells2016

    • Author(s)
      S. Ben Dkhil, M. Gaceur, W. Dachraoui, D. Hannani, S. Fall, F. Brunel, M. Wang, G. Poize, J. Mawyin, I. Shupyk, C. Martini, E. Shilova, F. Fages, T. Ishwara, J. Nelson, T.Watanabe, N. Yoshimoto, O. Margeat, C. Videlot-Ackermann, and J. Ackermann
    • Journal Title

      Solar Energy Materials and Solar Cells

      Volume: 印刷中

    • Related Report
      2015 Research-status Report
  • [Journal Article] ollapsed armchair single-walled carbon nanotubes as an analog of closed-edged bilayer graphene nanoribbons2015

    • Author(s)
      Masayuki Hasegawa, Kazume Nishidate, and Noriyuki Yoshimoto
    • Journal Title

      Phys. Rev. B

      Volume: 92 Issue: 24 Pages: 245429-245429

    • DOI

      10.1103/physrevb.92.245429

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 液晶性有機半導体薄膜の構造と温度依存性2018

    • Author(s)
      三浦 慎平、大場 涼矢、山口 裕二、葛原 大軌、菊池 護、小金澤 智之、廣沢 一郎、吉本 則之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] GISAXS によるペンタセン製膜中の表面形態評価 (II)2018

    • Author(s)
      広沢 一郎, 渡辺 剛, 小金澤 智之, 吉本 則之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] アルキル鎖をもつ有機半導体の薄膜成長初期過程の温度依存性2017

    • Author(s)
      葛原 大軌, 三浦 慎平, 菊池 護, 小金澤 智之, 廣沢 一郎, 吉本 則之,
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 2D-GIXDによる有機半導体薄膜のin situ 構造評価2017

    • Author(s)
      吉本則之、葛原大軌、菊池 護
    • Organizer
      第14回SPring-8産業利用報告会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機半導体薄膜の結晶成長に及ぼすアルキル鎖長の効果2017

    • Author(s)
      吉本則之, 三浦慎平, 葛原大軌, 菊池 護, 小金澤智之, 廣沢一郎
    • Organizer
      日本物理学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effects of alkyl-chain lengths of dialkiylated α,ω-quaterthiophenes on thin film growth, structure and transport properties2017

    • Author(s)
      D. Kuzuhara, S. Koshika, T. Koganezawa, M. Suzuki, H. Yamada, I. Hirosawa and N. Yoshimoto,
    • Organizer
      9th international conference on Molecular Electronics and Bioelectronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In situ characterization of the film coverage and charge transport in alkylated organic thin film transistor2017

    • Author(s)
      Takeshi Watanabe, Tomoyuki Koganezawa, Mamoru Kikuchi, Kosaku Nishida, Noriyuki Yoshimoto , Ichiro Hirosawa
    • Organizer
      9th international conference on Molecular Electronics and Bioelectronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 2次元X線回折法による成膜中の有機半導体薄膜の構造解析2016

    • Author(s)
      吉本則之,葛原大軌,菊池護,渡辺剛,小金澤智之,廣沢一郎
    • Organizer
      日本結晶学会平成28年度年会
    • Place of Presentation
      茨城県立県民文化センター(茨城県水戸市)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] In-situ 2次元X線回折による有機半導体薄膜成長過程の構造評価2016

    • Author(s)
      吉本 則之
    • Organizer
      2016年電子情報通信学会ソサエティ大会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2016-09-20
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] クォーターチオフェン誘導体薄膜の構造と輸送特性に及ぼすアルキル鎖長の偶奇効果2016

    • Author(s)
      廣内 大地、葛原 大軌、小金澤 智之、廣沢 一郎、吉本 則之
    • Organizer
      第77回応用物理学会秋期学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Effects of Alkyl-Chain Length of α,ω-Quaterthiophenes Derivatives on Thin-Film Structure and Transport Properties2016

    • Author(s)
      Daichi Hironai, Daiki Kuzuhara, Tomoyuki Koganezawa, Mitsuharu Suzuki, Hiroko Yamada, Ichiro Hirosawa and Noriyuki Yoshimoto
    • Organizer
      KJF International Conference of Organic Materials for Electronics and Photonics 2016
    • Place of Presentation
      Fukuoka (Japan)
    • Year and Date
      2016-09-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Molecular Alignments of σ Phase in Co-evaporated Film of PEN and PFP on SiO2 Studied by Grazing-Incidence X-ray Diffraction2016

    • Author(s)
      Ichiro Hirosawa, Takeshi Watanabe,Tomoyuki Koganesawa, Keisuke Tada, and Noriyuki Yoshimoto
    • Organizer
      KJF International Conference of Organic Materials for Electronics and Photonics 2016
    • Place of Presentation
      Fukuoka (Japan)
    • Year and Date
      2016-09-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Effects of alkyl-chain lengths on thin film growth of α,ω-quaterthiophene derivatives observed by in-situ two-dmensional X-ray diffraction2016

    • Author(s)
      D. Hironai, S. Koshika, D. Kuzuhara, T. Koganezawa , M. Suzuki, H. Yamada, I. Hirosawa, M. Hasegawawa and N. Yoshimoto
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      Nagoya (Japan)
    • Year and Date
      2016-08-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] The effect of air exposure on the crystal structure of oligothiophene thin films investigated using in situ X-ray diffraction2016

    • Author(s)
      T. Watanabe, T. Koganezawa, M. Kikuchi, N. Yoshimoto, I. Hirosawa
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      Nagoya (Japan)
    • Year and Date
      2016-08-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] In-situ Observation of Thin Film Growth of Organic Semiconductors by 2D-Xray Diffraction2016

    • Author(s)
      N.Yoshimoto, T. Watanabe, T. Koganezwa, M. Kikuchi, D. Kuzuhara, M. Suzuki, H. Yamada, I. Hirosawa,
    • Organizer
      The 2ed International Symposium on Synthetic Two―Dimensional Polymers
    • Place of Presentation
      Nara(Japan)
    • Year and Date
      2016-06-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 奇数鎖アルキル基をもつクォーターチオフェン薄膜の構造評価2016

    • Author(s)
      廣内 大地、小鹿 曹汰、小金澤 智之、廣沢 一郎、鈴木 充朗、山田 容子、吉本 則之
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Effects of alkyl-chain lengths on crystal structure and transport properties in thin films of α,ω-quaterthiophene derivatives,2015

    • Author(s)
      (68)Noriyuki Yoshimoto, Sota Koshika, Takeshi Watanabe, Tomoyuki Koganezawa, Mitsuharu Suzuki, Hiroko Yamada, Ichiro Hirosawa, Masayuki Hasegawa
    • Organizer
      15th International Conference on the Formation of Semiconductor Interfaces
    • Place of Presentation
      Hiroshima
    • Year and Date
      2015-11-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Band Gap of Epitaxial Graphene on the Ru(0001) Surface2015

    • Author(s)
      (69)K. Nishidate, N. Yoshimoto and Masayuki Hasegawa
    • Organizer
      15th International Conference on the Formation of Semiconductor Interfaces
    • Place of Presentation
      Hiroshima
    • Year and Date
      2015-11-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] α,ω-クオターチオフェン誘導体薄膜の結晶成長に及ぼす末端アルキル基の効果Ⅱ2015

    • Author(s)
      小鹿 曹汰、小金澤 智之、鈴木 充朗、山田 容子、吉本 則之
    • Organizer
      第76回応用物理学会秋期学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] バイアス印加HAXPES測定による有機トランジスタ動作中の有機半導体層内部の電位分布観察2015

    • Author(s)
      渡辺 剛、多田 圭佑、安野 聡、吉本 則之、広沢 一郎
    • Organizer
      第76回応用物理学会秋期学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 計測装置2017

    • Inventor(s)
      吉本則之、菊池護、中村雅一
    • Industrial Property Rights Holder
      岩手大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-004859
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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