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Improvement of the photoconversion efficiency of soluble-phthalocyanine-based solar cells by controlling the crystallinity of organic layer

Research Project

Project/Area Number 15K04651
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied materials
Research InstitutionShimane University

Principal Investigator

Hiromitsu Ichiro  島根大学, 総合理工学研究科, 教授 (40199138)

Co-Investigator(Kenkyū-buntansha) 半田 真  島根大学, 総合理工学研究科, 教授 (70208700)
池上 崇久  島根大学, 総合理工学研究科, 准教授 (00379033)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords有機薄膜太陽電池 / 塗布型デバイス / 可溶性フタロシアニン / 塗布型有機薄膜太陽電池 / 結晶性薄膜
Outline of Final Research Achievements

We aimed to design the device architectures and optimize the fabrication conditions of organic solar cells using soluble zinc phthalocyanine (ZnPc-TB). Inverted type solar cells fabricated with ZnO, which was inserted between indium-tin-oxide (ITO) and ZnPc-TB layers, resulted in an enhanced carrier generation activity of ZnPc-TB compared with the conventional type solar cells. Furthermore, an inverted type bulk heterojunction solar cell (ITO/ZnO/ZnPc-TB:PCBM/MoO3/Ag) showed a higher power conversion efficiency (PCE) of 4.5×10-2 %.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (21 results)

All 2018 2017 2016 2015 Other

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (15 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] Organic photovoltaic cells with onion-like carbon thin films as hole collection layers2018

    • Author(s)
      H. Mizuno, K. Nagano, S. Tomita, H. Yanagi, I. Hiromitsu
    • Journal Title

      Thin Solid Films

      Volume: 654 Pages: 69-76

    • DOI

      10.1016/j.tsf.2018.03.074

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced photoluminescence by excitation energy transfer in thin films consisting of fluorescent conjugated polymer and porphyrin2018

    • Author(s)
      H. Mizuno, S. Nasu, K. Kitamura, T. Aoki-Matsumoto, A. Fujita, Y. Fujita, I. Hiromitsu
    • Journal Title

      Thin Solid Films

      Volume: 653 Pages: 136-142

    • DOI

      10.1016/j.tsf.2018.03.008

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoconversion Characteristics of Zinc Phthalocyanine-Based Thin Film Photovoltaics2017

    • Author(s)
      H. Mizuno, T. Tsutsui, K. Nagano, I. Hiromitsu
    • Journal Title

      第14回日中国際学術セミナー論文集

      Volume: 無 Pages: 179-190

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Photoconversion Characteristics of Zinc Phthalocyanine-Based Thin Film Photovoltaics2017

    • Author(s)
      水野 斎,筒井 猛壮,長野 和基,広光 一郎
    • Journal Title

      第14回日中国際学術セミナー論文集

      Volume: 1 Pages: 179-190

    • Related Report
      2016 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] An unprecedented up-field shift in the C13 NMR spectrum of the caboxyl carbons of the lantern-type dinuclear compex TBA[Ru-2(O2CCH3)(4)Cl2]2015

    • Author(s)
      Yuya Hiraoka, Takahisa Ikeue, Hiroshi Sakiyama, Frederic Guegan, Dominique Luneau, Beatrice Gillon, Ichiro Hiromitsu, Daisuke Yoshioka, Masahiro Mikuriya, Yusuke Kataoka, Makoto Handa
    • Journal Title

      Dalton transactions

      Volume: 44 Pages: 13439-13443

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] オニオンライクカーボンをホール収集層に用いた低分子有機薄膜太陽電池の特性評価2018

    • Author(s)
      水野 斎,湯浅 泰之,冨田 知志,柳 久雄,広光 一郎
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 無機ナノシート/色素分子複合薄膜を含有するマイクロキャビティの作製とその光学特性2018

    • Author(s)
      水野 斎,藤村 卓也,笹井 亮,広光 一郎
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Influence of Onion-Like Carbon Layers on the Photovoltaic Properties in Zinc Phthalocyanine-Based Solar Cells2017

    • Author(s)
      H. Mizuno, S. Tomita, H. Yanagi, I. Hiromitsu
    • Organizer
      18th International Union of Materials Research Societies International Conference in Asia (IUMRS-ICA 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 導電性高分子:ポルフィリン混合膜を活性層に用いた光共振器の光学特性2017

    • Author(s)
      那須 俊佑,水野 斎,青木 珠緒,広光 一郎
    • Organizer
      応用物理・物理系学会中国四国支部 合同学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photovoltaic Properties of Inverted-Type Hybrid Solar Cells Using a Soluble Zinc Phthalocyanine2017

    • Author(s)
      H. Mizuno, T. Tsutsui, I. Hiromitsu
    • Organizer
      5th NANO TODAY CONFERENCE
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機薄膜太陽電池の光電変換特性に及ぼすカーボンオニオンの著しい影響2017

    • Author(s)
      水野 斎,長野 和基,三輪 涼太,冨田 知志,柳 久雄,広光 一郎
    • Organizer
      ナノ学会第15回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] P3HT/PCBMナノ粒子を用いた逆型有機薄膜太陽電池の特性評価2017

    • Author(s)
      樋口 進哉,水野 斎,広光 一郎
    • Organizer
      ナノ学会第15回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機溶媒分散PEDOTをホール輸送層に用いた逆型ペロブスカイト太陽電池の光電変換特性2017

    • Author(s)
      中村 昇太, 水野 斎, 広光 一郎
    • Organizer
      [10]ナノ学会第15回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 可溶性亜鉛フタロシアニンを用いた逆構造型バルクヘテロ接合型太陽電池2017

    • Author(s)
      筒井 猛壮,水野 斎,広光 一郎
    • Organizer
      ナノ学会第15回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photoconversion Properties of Thin Film Photovoltaics Using a Soluble Zinc Phthalocyanine2016

    • Author(s)
      水野 斎,筒井 猛壮,長野 和基,広光 一郎
    • Organizer
      Global Research Efforts on Energy and Nanomaterials (GREEN 2016)
    • Place of Presentation
      GIS Taipei Tech Convention Center, Taipei
    • Year and Date
      2016-12-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Heterojunction Photovoltaic Cells Consisting of 5,5′-Di(4-biphenylyl)-2,2′-bithiophene and 3,4,9,10-perylenetetracarboxylic bis-benzimidazole2016

    • Author(s)
      水野 斎,廣田 侑奈,広光 一郎
    • Organizer
      The 8th Asian Conference on Organic Electronics (A-COE 2016)
    • Place of Presentation
      京都大学
    • Year and Date
      2016-12-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 亜鉛フタロシアニン塗布膜太陽電池の光電変換特性2016

    • Author(s)
      水野 斎,筒井 猛壮,赤松 和也,廣光 一郎
    • Organizer
      日中国際学術セミナー
    • Place of Presentation
      島根大学
    • Year and Date
      2016-10-15
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 亜鉛フタロシアニン塗布膜を用いた薄膜太陽電池の評価2016

    • Author(s)
      水野 斎,赤松 和也,川西 有輝,廣光 一郎
    • Organizer
      ナノ学会第14回大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2016-06-14
    • Related Report
      2016 Research-status Report
  • [Presentation] CH3NH3PbI3太陽電池の評価2016

    • Author(s)
      水野 斎,大野 光紀,柳 久雄,廣光 一郎
    • Organizer
      ナノ学会第14回大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2016-06-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 可溶性亜鉛フタロシアニン塗布膜の評価2015

    • Author(s)
      赤松 和也,水野 斎,広光 一郎
    • Organizer
      島根大学―首都大学東京合同光機能材料セミナー
    • Place of Presentation
      島根大学
    • Year and Date
      2015-10-30
    • Related Report
      2015 Research-status Report
  • [Remarks] 島根大学総合理工学部物質科学科物理分野 広光・水野研究室

    • URL

      http://www.phys.shimane-u.ac.jp/hiromitsu_lab/

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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