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Research on polarization-induced resistance switching in ferroelectric polymer ultra-thin films with different electrodes

Research Project

Project/Area Number 15K04653
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied materials
Research InstitutionTokyo University of Science

Principal Investigator

Okamura Soichiro  東京理科大学, 理学部第一部応用物理学科, 教授 (60224060)

Co-Investigator(Kenkyū-buntansha) 中嶋 宇史  東京理科大学, 理学部, 助教 (60516483)
橋爪 洋一郎  東京理科大学, 理学部第一部応用物理学科, 助教 (50711610)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords分極誘起抵抗変化 / 高分子強誘電体 / 極薄膜 / トーマスフェルミ遮蔽長 / トンネル伝導 / FTJ / 強誘電体 / 抵抗変化 / 分極遮蔽電荷 / 記憶素子 / 分極反転 / 異種電極 / 自発分極
Outline of Final Research Achievements

We studied polarization-induced resistance switching in ferroelectric tunneling junction (FTJ) structure. The original point of this study is the use of ferroelectric VDF/TrFE copolymer. As a result, we revealed that the direction of spontaneous polarization induced high/low resistances and resistance ratios depended on the work functions of two electrode materials. When Au and Pt were used as electrode materials, the resistance ratio of 10,000% was achieved. This value was larger than those previously reported in the FTJ structures with ceramic ferroelectrics. We also investigated the properties of FTJ structures with Nb, Ru and high-doped silicon electrodes instead of Pt. Finally, we concluded that asymmetry potential barrier induced at electrode/ferroelectrics interface due to the differences in Thomas-Fermi screening length in electrode materials was the origin of the polarization-induced resistance switching.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (25 results)

All 2018 2017 2016 2015

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 4 results,  Acknowledgement Compliant: 2 results) Presentation (19 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results)

  • [Journal Article] Polarization Induced Resistance Switching Phenomenon in Metal Au / Ferroelectric VDF-TrFE / Semiconductor Si Junction2017

    • Author(s)
      Naoto Enomoto, Yoichiro Hashizume, Takashi Nakajima, Soichiro Okamura
    • Journal Title

      JAPANESE JOURNAL OF APPLIED PHYSICS

      Volume: 56 Issue: 10S Pages: 10PF13-10PF13

    • DOI

      10.7567/jjap.56.10pf13

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Domain switching kinetics in vinylidene fluoride/tetrafluoroethylene copolymer thin films2016

    • Author(s)
      Y. Nakagawa, Y. Hashizume, T. Nakajima, Alexei Gruverman, and Soichiro Okamura
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 55 Issue: 10S Pages: 10TA12-10TA12

    • DOI

      10.7567/jjap.55.10ta12

    • NAID

      210000147162

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Ferroelectric properties of vinylidene fluoride/tetrafluoroethylene copolymer thin films consisting of needle-like crystals2016

    • Author(s)
      Y. Nakagawa, Y. Hashizume, T. Nakajima, and Soichiro Okamura
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 50 Issue: 5 Pages: 051601-051601

    • DOI

      10.7567/jjap.55.051601

    • NAID

      210000146456

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Polarization Induced Resistance Switching in VDF/TrFE Copolymer Ultrathin Films2015

    • Author(s)
      Takashi Nakajima, Shogo Usui, Hitoshi Honmi, Yoichiro Hashizume, and Soichiro Okamura
    • Journal Title

      Extended Abstracts of the 17th US-Japan Seminar on Dielectric and Piezoelectric Ceramics

      Volume: 1 Pages: 194-196

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Theoretical analysis on polarization-induced resistance switching effects of polymer thin films including dead layers2015

    • Author(s)
      Hitoshi Honmi, Yoichiro Hashizume, Takashi Nakajima, and Soichiro Okamura
    • Journal Title

      JAPANESE JOURNAL OF APPLIED PHYSICS

      Volume: 54 Issue: 10S Pages: 10NA08-10NA08

    • DOI

      10.7567/jjap.54.10na08

    • NAID

      210000145769

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Polarization switching characteristics of vinylidene fluoride/tefrafluoroethylene copolymer thin films2015

    • Author(s)
      Yuuta Nakagawa, Yoichiro Hashizume, Takashi Nakajima, and Soichiro Okamura
    • Journal Title

      JAPANESE JOURNAL OF APPLIED PHYSICS

      Volume: 54 Issue: 10S Pages: 10NA09-10NA09

    • DOI

      10.7567/jjap.54.10na09

    • NAID

      210000145770

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 強誘電性フッ化ビニリデン/フッ化エチレン共重合体の溶融結晶化過程のその場観察2018

    • Author(s)
      宮本 将成、橋爪 洋一郎、中嶋 宇史、岡村 総一郎
    • Organizer
      第65回応用物理学会 春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] フッ化ビニリデン(54)/三フッ化エチレン(46)共重合体薄膜における強誘電性の熱処理温度依存性2017

    • Author(s)
      長畑 範之、中川 佑太、橋爪 洋一郎、中嶋 宇史、岡村 総一郎
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] フッ化ビニリデン高分子強誘電体における分子鎖内でのキンク形状2017

    • Author(s)
      山崎 勇人、橋爪 洋一郎、中嶋 宇史、岡村 総一郎
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] 強誘電性VDF/TrFE共重合体極薄膜のドメイン分極反転特性2017

    • Author(s)
      中川 佑太、榎本 尚人、梶山 結花、橋爪 洋一郎、中嶋 宇史、岡村 総一郎
    • Organizer
      強的秩序とその操作に関する第4 回研究会
    • Place of Presentation
      東京大学
    • Year and Date
      2017-01-04
    • Related Report
      2016 Research-status Report
  • [Presentation] 金属 Au/強誘電体 VDF-TrFE/半導体 Si 接合における分極誘起抵抗変化現象2017

    • Author(s)
      榎本尚人、橋爪洋一郎、中嶋宇史、岡村総一郎
    • Organizer
      第34回強誘電体応用会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] 低TCを持つVDF/TrFE(54/46)共重合体薄膜を用いたFTJ素子の作製2017

    • Author(s)
      長畑範之、橋爪洋一郎、中嶋宇史、岡村総一郎
    • Organizer
      第27回日本MRS年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] パルス電界を用いた強誘電体薄膜のリーク電流特性2016

    • Author(s)
      畠 希、佐々木 敏夫、橋爪 洋一郎、中嶋 宇史、岡村 総一郎
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2016-12-19
    • Related Report
      2016 Research-status Report
  • [Presentation] Ferroelectric properties of vinylidene fluoride/tetrafluoroethylene copolymer thin films2016

    • Author(s)
      uuta Nakagawa, Yoichiro Hashizume, Takashi Nakajima, Alexei Gruverman and Soichiro Okamura
    • Organizer
      The 8th Japan-China Symposium on Ferroelectric Materials and Their Applications
    • Place of Presentation
      Tsukuba (Japan)
    • Year and Date
      2016-09-30
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] VDF/TeFE共重合体薄膜の非対称なドメインスイッチング特性2016

    • Author(s)
      中川 佑太、榎本 尚人、橋爪 洋一郎、中嶋 宇史、Gruverman Alexei、岡村 総一郎
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Au/VDF-TrFE/半導体 Si 接合 における分極誘起抵抗変化現象2016

    • Author(s)
      榎本 尚人、中川 佑太、橋爪 洋一郎、中嶋 宇史、岡村 総一郎
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Limiting ferroelectric switching characteristics of VDF/TrFE copolymer ultrathin film2016

    • Author(s)
      Takashi Nakajima, Yoichiro Hashizume, and Soichiro Okamura
    • Organizer
      11th Korea-Japan Conference on Ferroelectrics
    • Place of Presentation
      Seou (Korea)
    • Year and Date
      2016-08-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 圧電応答顕微法を用いた VDF/TeFE 共重合体薄膜のドメイン反転の観察2016

    • Author(s)
      川 佑太、橋爪 洋一郎、中嶋 宇史、Alexei Gruverman、岡村 総一郎
    • Organizer
      第33回強誘電体応用会議
    • Place of Presentation
      コープイン京都
    • Year and Date
      2016-05-26
    • Related Report
      2016 Research-status Report
  • [Presentation] 極低温下におけるPZT薄膜のリーク電流特性2016

    • Author(s)
      畠 希、佐々木 敏夫、橋爪 洋一郎、中嶋 宇史、岡村 総一郎
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東工大大岡山キャンパス
    • Year and Date
      2016-03-20
    • Related Report
      2015 Research-status Report
  • [Presentation] Theoretical Analysis on Polarization-induced Resistance Switching Effects of Polymer Thin Films Including Dead Layers2016

    • Author(s)
      Yoichiro Hashizume, Takashi Nakajima, Soichiro Okamura
    • Organizer
      BIT’s 2nd Annual World Congress of Smart Materials-2016 (WCSM-2016)
    • Place of Presentation
      Grand Copthorne Waterfront Hotel, Singapol
    • Year and Date
      2016-03-06
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 極薄膜化された有機強誘電体の分極誘起抵抗変化現象2016

    • Author(s)
      中嶋宇史,橋爪洋一郎,岡村総一郎
    • Organizer
      第1回 強的秩序とその操作に関する研究会
    • Place of Presentation
      東京工業大学 キャンパスイノベーションセンター
    • Year and Date
      2016-01-04
    • Related Report
      2015 Research-status Report
  • [Presentation] PZT薄膜におけるリーク電流特性の温度依存性2015

    • Author(s)
      畠希、大塚尚之、佐々木敏夫、橋爪洋一郎、中嶋宇史、岡村総一郎
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      産業貿易センタービル
    • Year and Date
      2015-12-08
    • Related Report
      2015 Research-status Report
  • [Presentation] Polarization Induced Resistance Switching in VDF/TrFE Copolymer Ultrathin Films2015

    • Author(s)
      Takashi Nakajima, Shogo Usui, Hitoshi Honmi, Yoichiro Hashizume, and Soichiro Okamura
    • Organizer
      17th US-Japan Seminar on Dielectric and Piezoelectric Ceramics
    • Place of Presentation
      Matsumoto, Japan
    • Year and Date
      2015-11-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 分極誘起抵抗変化現象の理論的解析2015

    • Author(s)
      本美仁志,橋爪洋一郎,中嶋宇史,岡村総一郎
    • Organizer
      第32回強誘電体応用会議
    • Place of Presentation
      京都府京都市
    • Year and Date
      2015-05-20
    • Related Report
      2015 Research-status Report
  • [Presentation] 溶融状態から結晶化させた強誘電体VDF/TeFE共重合体薄膜のスイッチング特性2015

    • Author(s)
      中川佑太,橋爪洋一郎,中嶋宇史,岡村総一郎
    • Organizer
      第32回強誘電体応用会議
    • Place of Presentation
      京都府京都市
    • Year and Date
      2015-05-20
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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