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AlN single crystals growth converted from Al2O3 under atomic nitrogen plasma

Research Project

Project/Area Number 15K04668
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Crystal engineering
Research InstitutionShizuoka Institute of Science and Technology

Principal Investigator

Ozawa Tetsuo  静岡理工科大学, 理工学部, 教授 (90247578)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
KeywordsAlN / プラズマ / 単結晶 / 転換層 / AlN / サファイア / 窒素プラズマ / 単結晶成長 / 面方位依存 / 窒化物半導体 / 窒化物半導体結晶 / 活性化エネルギー / 拡散過程
Outline of Final Research Achievements

Alminium nitride (AlN) is a promising material for optoelectronic device applications such as UV light-emitting diodes and UV laser diodes. The method to prevent a large mismatch with AlN/ sapphire and to avoid the high equilibrium pressure and temperature environment is required to grow high crystalline AlN. To investigate the chemical change from AlN on the surface of Al2O3 substrate, XRD peaks was monitored. Samples were included N-Al bonding for the formation of AlN. The peaks assigned to N-O and Al-O bondings were not observed. Therefore, it was indicated that AlN was formed by Al2O3 substrate nitridation.We have carried out preliminary experiments to explore sub- atmospheric pressure solution growth to grow thick single AlN crystal films for the use as substrate. Semi-transparent AlN layer was grown on the (0 0 01) sapphire substrate by using plasma mixture of nitrogen. The luminescence property without a deep level yellow emission suggested the growth of high-crystalline AlN.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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