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Study of terminal structure and electronic band structure of diamond surface by angle-resolved photoelectron spectroscopy

Research Project

Project/Area Number 15K04681
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTokyo City University

Principal Investigator

Nohira Hiroshi  東京都市大学, 工学部, 教授 (30241110)

Co-Investigator(Renkei-kenkyūsha) Yamazaki Satoshi  独立行政法人産業技術総合研究所, 先進パワーエレクトロニクス研究センターダイヤモンドデバイスチーム, 招聘研究員 (80358241)
Takeuchi Daisuke  独立行政法人産業技術総合研究所, 先進パワーエレクトロニクス研究センターダイヤモンド材料チーム, チーム長 (10357402)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsダイヤモンド / 光電子分光法 / C1s光電子スペクトル / エッチングによる表面ダメージ / soft-ICP / 価電子帯
Outline of Final Research Achievements

Effects on the surface by etching process essential for diamond device fabrication (soft-ICP (ICP: Inductively Coupled Plasma) etching method which can be expected to reduce damage on the surface of diamond) and the change of valence band near the surface by boron and phosphorus doped at high concentration were investigated using a photoelectron spectrometer (AXIS Nova or ESCA - 300), and in some samples, using hard X - ray photoelectron spectroscopy (high intensity synchrotron radiation facility SPring - 8, BL47 XU). As a result, it was found that the soft-ICP etching method does not change the chemical bond state of the sample surface. The experimental results also suggested that the band near the diamond surface would bend due to high concentration doping.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (15 results)

All 2017 2016 2015

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (12 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Angle-Resolved Photoelectron Spectroscopy Studies of Initial Stage of Thermal Oxidation on 4H-SiC (0001) on-Axis and 4° Off-Axis Substrates2017

    • Author(s)
      Arai Hitoshi、Toyoda Ryoma、Ishohashi Ai、Sano Yasuhisa、Nohira Hiroshi
    • Journal Title

      ECS Transactions

      Volume: 77 Issue: 6 Pages: 51-57

    • DOI

      10.1149/07706.0051ecst

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Angle-resolved photoelectron spectroscopy study of initial stage of thermal oxidation on 4HSiC( 0001)2016

    • Author(s)
      Hitoshi Arai1 and Hiroshi Nohira
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 4S Pages: 04EB04-04EB04

    • DOI

      10.7567/jjap.55.04eb04

    • NAID

      210000146272

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of atomic-arrangement matching on La2O3/Ge heterostructures for epitaxial high-k-gate-stacks2015

    • Author(s)
      T. Kanashima, H. Nohira, M. Zenitaka, Y. Kajihara, S. Yamada, and K. Hamaya
    • Journal Title

      JOURNAL OF APPLIED PHYSICS

      Volume: 118 Issue: 22

    • DOI

      10.1063/1.4937147

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 高空間分解能HXPESによるGe 2p内殻準位の結合エネルギーに歪みが与える影響の検出2017

    • Author(s)
      佐野 良介、此島 志織、滝沢 耕平、澤野 憲太郎、野平 博司
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] エピタキシャルGe上直接ALDによるAl2O3/Ge界面特性向上2017

    • Author(s)
      池上 和彦, 佐藤 慶次郎, 澤田 浩介, Maksym Myronov, 野平 博司, 澤野 憲太郎
    • Organizer
      電子デバイス界面テクノロジー研究会
    • Place of Presentation
      東レ研修センター(静岡県三島市)
    • Year and Date
      2017-01-20
    • Related Report
      2016 Research-status Report
  • [Presentation] ARXPSによる soft-ICPエッチングプロセスがダイヤモンド半導体表面に与える影響2017

    • Author(s)
      滝沢 耕平, 加藤 有香子, 牧野 俊晴, 山崎 聡,野平 博司
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] AR-XPSによる4H-SiC (0001) on-Axis, 4° Off-Axis基板の初期酸化過程の解明2016

    • Author(s)
      荒井 仁、豊田 涼馬、礒橋 藍、佐野 泰久、野平 博司
    • Organizer
      2016年 第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] La2xA2(1-x)O3(A=Lu, Y)/La2O3/Ge(111) MIS構造におけるC-V特性の改善2016

    • Author(s)
      金島 岳、銭高 真人、山本 圭介、山城 陸、只野 純平、野平 博司、中島 寛、山田 晋也、浜屋 宏平
    • Organizer
      2016年 第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] AR-XPSによる4H-SiC (0001)の初期熱酸化過程の研究2016

    • Author(s)
      荒井 仁, 野平 博司
    • Organizer
      電子デバイス界面テクノロジー研究会(第21回)
    • Place of Presentation
      東レ研修センター(静岡県三島市)
    • Year and Date
      2016-01-22
    • Related Report
      2015 Research-status Report
  • [Presentation] Initial Stage of SiO2/SiC Interface Formation on C-face 4H-SiC2015

    • Author(s)
      Tomoya Sasago, Hitoshi Arai, Shunta Yamahori, Hiroshi Nohira
    • Organizer
      2015 International Workshop on DIELECTRIC THIN FILMS FOR FUTURE ELECTRON DEVICES – SCIENCE AND TECHNOLOGY
    • Place of Presentation
      Miraikan, National Museum of Emerging Science and Innovation(東京都江東区)
    • Year and Date
      2015-11-02
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Study of Epitaxial La2O3 High-k/Ge(111) Interface by X-ray Photoelectron Spectroscopy2015

    • Author(s)
      Takeshi Kanashima, Hiroshi Nohira, Masato Zenitaka, Taro Kobayashi, Riku Yamashiro, Shinya Yamada, Kohei Hamaya
    • Organizer
      2015 International Workshop on DIELECTRIC THIN FILMS FOR FUTURE ELECTRON DEVICES – SCIENCE AND TECHNOLOGY
    • Place of Presentation
      Miraikan, National Museum of Emerging Science and Innovation(東京都江東区)
    • Year and Date
      2015-11-02
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Angle-resolved Photoelectron Spectroscopy studies of initial stage of thermal oxidation on 4H-SiC (0001)2015

    • Author(s)
      H. Arai, H. Nohira
    • Organizer
      2015 International Conference on Solid State Devices and Materials
    • Place of Presentation
      Sapporo Convention Center(北海道札幌市)
    • Year and Date
      2015-09-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] AR-XPSによる4H-SiC (0001)の初期酸化過程の解明2015

    • Author(s)
      荒井 仁、野平 博司
    • Organizer
      2015年 第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] ドライ酸化プロセスの制御によるC関連欠陥の減少2015

    • Author(s)
      笹子 知弥、荒井 仁、喜多 浩之、室 隆桂之、野平 博司
    • Organizer
      2015年 第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 結晶性La2O3/Ge(111)高品質界面のXPS分析2015

    • Author(s)
      金島 岳、野平 博司、銭高 真人、小林 太朗、山城 陸、山田 晋也、浜屋 宏平
    • Organizer
      2015年 第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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