| Project/Area Number |
15K04736
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Quantum beam science
|
|---|
| Research Institution | National Institutes for Quantum and Radiological Science and Technology (2016-2017)
Japan Atomic Energy Agency (2015) |
|---|
Principal Investigator |
Idesaki Akira 国立研究開発法人量子科学技術研究開発機構, 高崎量子応用研究所 先端機能材料研究部, 主幹研究員(定常) (10370355)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
SUGIMOTO Masaki 国立研究開発法人量子科学技術研究開発機構, 高崎量子応用研究所 先端機能材料研究部, 上席研究員 (90354943)
|
|---|
| Project Period (FY) |
2015-04-01 – 2018-03-31
|
| Project Status |
Completed (Fiscal Year 2017)
|
| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
|
|---|
| Keywords | 窒素含有カーボンアロイ / イオン注入 / 有機－無機転換 / 有機―無機転換 |
|---|
| Outline of Final Research Achievements |
Changes in chemical and structural properties of a phenolic resin after nitrogen-ion implantation and subsequent carbonization were investigated in order to develop synthesis process of a nitrogen-containing carbon alloy with catalytic activity. It was found that (1) nitrogen was incorporated into molecules in the phenolic resin forming C-N bonds, (2) the implanted nitrogen was remained after the carbonization to form turbostratic graphite-structure including pyridinic nitrogen, and (3) obtained carbon material showed oxygen reduction reaction (ORR) potential of 0.7 V vs RHE. According to these results, it was demonstrated that ion implantation technique is effective to synthesize a nitrogen-containing carbon alloy from a precursor polymer.
|
