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Chemical correlation analysis between different elements by extension of 2D imaging XAFS technique

Research Project

Project/Area Number 15K04739
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Quantum beam science
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

Okamoto Yoshihiro  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 物質科学研究センター, 研究主幹 (70370369)

Co-Investigator(Kenkyū-buntansha) 塩飽 秀啓  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 物質科学研究センター, 研究副主幹 (10222043)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsイメージング / 放射光 / XAFS / 化学状態 / ガラス固化 / 粘土鉱物 / 元素マッピング / ガラス固化体 / イメージングXAFS / 化学的相関 / 空間分解能
Outline of Final Research Achievements

Chemical correlation between two kinds of elements in materials were tried to evaluate by update of the imaging XAFS technique. In the analysis, imaging XAFS spectra of two different elements in soil, adsorbent and borosilicate glass were obtained and correlation between them was investigated. It can be seen that more cesium adheres to the soil containing trivalent iron rather than divalent iron. It is concluded that chemical state of rhodium in the borosilicate glass is controlled by distribution of ruthenium element. We confirmed extension of the imaging XAFS technique tried in the present work was effective for the chemical correlation analysis.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (8 results)

All 2018 2017 2016 2015

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (6 results)

  • [Journal Article] Chemical State Analysis of Rhodium in Simulated Waste Glass by Synchrotron-Radiation-based XAFS and Imaging XAFS Techniques2017

    • Author(s)
      岡本 芳浩、永井 崇之、塩飽 秀啓、猪瀬 毅彦、佐藤 誠一
    • Journal Title

      Transactions of the Atomic Energy Society of Japan

      Volume: 16 Issue: 4 Pages: 180-190

    • DOI

      10.3327/taesj.J16.024

    • NAID

      130006201787

    • ISSN
      1347-2879, 2186-2931
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 入門講座 分析化学における放射光の利用  放射光分析の応用:環境分析2015

    • Author(s)
      岡本芳浩
    • Journal Title

      ぶんせき

      Volume: 11号 Pages: 478-485

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] ガラス固化技術高度化のための放射光XAFS研究2018

    • Author(s)
      岡本芳浩、永井崇之、小林秀和、塩飽秀啓、菖蒲康夫
    • Organizer
      2017年度量子ビームサイエンスフェスタ
    • Related Report
      2017 Annual Research Report
  • [Presentation] イメージングXAFSによる異種元素間の化学的相関解析2017

    • Author(s)
      岡本芳浩
    • Organizer
      2016年度量子ビームサイエンスフェスタ 第34回PFシンポジウム
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] イメージングXAFSによる異種元素間の化学的相関解析2017

    • Author(s)
      岡本芳浩、永井崇之、小林博美、畠山清司、塩飽秀啓
    • Organizer
      2016年度量子ビームサイエンスフェスタ
    • Related Report
      2017 Annual Research Report
  • [Presentation] 流下試験ガラス固化試料のイメージングXAFS分析2017

    • Author(s)
      岡本芳浩、永井崇之、塩飽秀啓、関克巳、小林博美、本間将啓、畠山清司
    • Organizer
      第49回溶融塩化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 廃棄物含有鉄リン酸ガラスの放射光XAFSによる局所構造解析2016

    • Author(s)
      岡本芳浩
    • Organizer
      日本原子力学会 2016年秋の大会
    • Place of Presentation
      久留米シティプラザ(福岡県久留米市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
  • [Presentation] 放射光イメージングXAFS法による模擬ガラス試料中のロジウム元素の化学状態分析2016

    • Author(s)
      岡本芳浩
    • Organizer
      日本原子力学会 2016年春の大会
    • Place of Presentation
      東北大学川内キャンパス(宮城県仙台市)
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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