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Spectroscopic studies for amino acid and its precursors

Research Project

Project/Area Number 15K05027
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Astronomy
Research InstitutionToho University

Principal Investigator

OZEKI Hiroyuki  東邦大学, 理学部, 教授 (70260031)

Co-Investigator(Kenkyū-buntansha) 小林 かおり  富山大学, 大学院理工学研究部(理学), 教授 (80397166)
Research Collaborator BAILLEUX Stephane  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords星間アミノ酸 / ミリ波・サブミリ波分光 / 電波天文観測 / 星間分子 / アミノ酸 / 分光データベース / サブミリ波分光 / グリシン / 星間物質
Outline of Final Research Achievements

We have constructed a chemical reaction network toward synthesis of glycine, the simplest amino acid, in interstellar space by comprehensive investigation of previous researches, and have identified several key molecules for synthesizing glycine. To date, most of these species are impossible to explore by radio-astronomy due to lack of relevant spectroscopic information. In this study we tried to observe rotational spectra of Aminoacetonitrile, Hydantoin, and Aminomethanol in the millimeter-wave to sub-millimeter-wave frequency region, all of which can be regarded as direct precursors of glycine in the chemical network. Spectroscopic characterization for former two species in their vibrational ground and excited states has been successfully made, and their molecular constants are accurately determined. Line frequency catalogues for these molecules have been established for astronomical observation with whole ALMA observation bands.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (15 results)

All 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (8 results) (of which Int'l Joint Research: 4 results) Remarks (2 results)

  • [Int'l Joint Research] Università di Bologna(イタリア)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] University of Lille(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] リール第一大学 原子分子レーザー物理学研究所(フランス)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Millimeter-wave and Submillimeter-wave Spectra of Aminoacetonitrile in the Three Lowest Vibrational Excited States2017

    • Author(s)
      Esposti Claudio Degli、Dore Luca、Melosso Mattia、Kobayashi Kaori、Fujita Chiho、Ozeki Hiroyuki
    • Journal Title

      The Astrophysical Journal Supplement Series

      Volume: 230 Issue: 2 Pages: 26-26

    • DOI

      10.3847/1538-4365/aa7335

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Millimeter-wave spectroscopy of Hydantoin, -a possible precursor of glycine2017

    • Author(s)
      H. Ozeki, R. Miyahara, H. Ihara, S. Todaka, K. Kobayashi, and M. Ohishi
    • Journal Title

      Astronomy & Astrophysics

      Volume: 600 Pages: A44-A44

    • DOI

      10.1051/0004-6361/201629880

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] CHF2ラジカルのTunneling-Rotationスペクトルの解析2017

    • Author(s)
      尾関博之、稲田直美、齋藤修二
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] The Millimeter-Wave Spectroscopy of Hydantoin, A Potential Precursor of Glycine2016

    • Author(s)
      Hiroyuki Ozeki, Rio Miyahara, Hiroto Ihara, Satoshi, Todaka, Kaori, Kobayashi, and Masatoshi Ohishi
    • Organizer
      71st International Symposium on Molecular Spectroscopy
    • Place of Presentation
      Champaign-Urbama, Illinois USA
    • Year and Date
      2016-06-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] The Microwave Spectroscopy of Aminoacetonitrile in the Vibrational Excited States 22016

    • Author(s)
      Chiho Fujita, Haruka Higurashi, Hiroyuki Ozeki, and Kaori Kobayashi
    • Organizer
      71st International Symposium on Molecular Spectroscopy
    • Place of Presentation
      Champaign-Urbama, Illinois USA
    • Year and Date
      2016-06-21
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ヒダントインのミリ波分光2016

    • Author(s)
      尾関博之,宮原凛央,伊原博音,戸高智志,小林かおり,大石雅寿
    • Organizer
      第16回分子分光研究会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-05-13
    • Related Report
      2016 Research-status Report
  • [Presentation] アミノ酸前駆体分子の分光測定2015

    • Author(s)
      尾関博之
    • Organizer
      第3回キラル研究会
    • Place of Presentation
      京都大学 (京都府 京都市)
    • Year and Date
      2015-11-28
    • Related Report
      2015 Research-status Report
  • [Presentation] アミノアセトニトリル振動励起状態のミリ波・サブミリ波分光2015

    • Author(s)
      藤田智帆、尾関博之、小林かおり
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学 (東京都・目黒区)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Research-status Report
  • [Presentation] Terahertz spectroscopy of deuterated methylene bi-radical, CD22015

    • Author(s)
      Stephane Bailleux, and Hiroyuki Ozeki
    • Organizer
      70th International Symposium on Molecular Spectroscopy
    • Place of Presentation
      Champaign-Urbama, Illinois USA
    • Year and Date
      2015-06-25
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] The microwave spectroscopy of Aminoacetonitrile in the vibrational excited state2015

    • Author(s)
      Chiho Fujita, Hiroyuki Ozeki, and Kaori Kobayashi
    • Organizer
      70th International Symposium on Molecular Spectroscopy
    • Place of Presentation
      Champaign-Urbama, Illinois USA
    • Year and Date
      2015-06-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] Toyama Microwave Atlas

    • URL

      http://www.sci.u-toyama.ac.jp/phys/4ken/atlas/

    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://www.sci.u-toyama.ac.jp/phys/4ken/atlas/

    • Related Report
      2016 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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