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Verification of band transport mechanism in organic semiconductors by observing free carriers

Research Project

Project/Area Number 15K05129
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics I
Research InstitutionWakayama University

Principal Investigator

Akimoto Ikuko  和歌山大学, システム工学部, 准教授 (00314055)

Co-Investigator(Kenkyū-buntansha) 中 暢子  京都大学, 理学研究科, 准教授 (10292830)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords有機半導体 / 無機半導体 / 光キャリア / 伝導機構 / サイクロトロン共鳴
Outline of Final Research Achievements

We investigated transport properties of optically injected carriers in a high-mobility organic semiconductor, rubrene crystal, in comparison to those in non-organic semiconductors, with the aim of demonstrating the band transport mechanism in the organic system. First, we confirmed that optical carrier injection is established by the dissociation of excitons induced by electric field, based on an observation of anti-correlation between exciton luminescence and photocurrent. In contract, we found that all optical carrier injection pathways via (i) the band-to-band transition and (ii) exciton dissociation in pure silicon and diamond crystals. Second, we performed the time-resolved cyclotron resonance measurement for carriers generated by two-photon excitation in rubrene crystals. A spectrum observed at 2.5 K indicated a peak centered at the effective mass of 0.23 m0, but the value was still unreliable because of the puzzling dependence on temperature and crystal orientation.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (23 results)

All 2018 2017 2016 2015 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 3 results) Presentation (19 results) (of which Int'l Joint Research: 9 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] Two optical routes of cold carrier injection in silicon revealed by time-resolved excitation spectroscopy2017

    • Author(s)
      Ikuko Akimoto, Nobuko Naka
    • Journal Title

      Applied Physics Express

      Volume: in press

    • NAID

      210000135868

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Excitons and fundamental transport properties of diamond under photo-injection (Feature Article)2016

    • Author(s)
      N. Naka, H. Morimoto, and I. Akimoto
    • Journal Title

      Physica Status Solidi (a)

      Volume: 213 Issue: 10 Pages: 2551-2563

    • DOI

      10.1002/pssa.201600237

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Time-resolved cyclotron resonance on dislocation-free HPHT diamond2015

    • Author(s)
      I. Akimoto, N. Naka, N. Tokuda
    • Journal Title

      Diamond & Related Materials

      Volume: 63 Pages: 38-42

    • DOI

      10.1016/j.diamond.2015.08.013

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 高純度ダイヤモンド結晶における光キャリア生成経路の温度依存性2018

    • Author(s)
      濵端沙耶香,秋元郁子,中暢子
    • Organizer
      日本物理学会 第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Time-resolved spectroscopy on intrinsic diamond for reassessment of the exciton binding energy2018

    • Author(s)
      N. Naka, S. Hamabata, K. Konishi, J. H. Kaneko, I. Akimoto
    • Organizer
      Hasselt Diamond Workshop 2018 - SBDD XXIII 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhanced mobility of excitons under inelastic phonon scattering in intrinsic diamond2018

    • Author(s)
      K. Konishi, I. Akimoto, H. Matsuoka, Ian. Friel, J. Isberg, N. Naka
    • Organizer
      Hasselt Diamond Workshop 2018 - SBDD XXIII 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photocarrier injection by two photon excitation in rubrene single crystal2018

    • Author(s)
      Kenta Goto, Toshinobu Takayama, Keizo Ohata, and Ikuko Akimoto
    • Organizer
      EXCON2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evaluation of the exciton effective mass in intrinsic diamond2018

    • Author(s)
      S. Hamabata, I. Akimoto, N. Naka
    • Organizer
      EXCON2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optical injection of valley-polarized electrons in group-IV semiconductors2018

    • Author(s)
      Nobuko Naka and Ikuko Akimoto
    • Organizer
      EXCON2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高純度シリコン結晶におけるバレー選択的光キャリア生成2017

    • Author(s)
      秋元郁子、中暢子
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Enhanced electron mobility in intrinsic diamond at cryogenic temperatures2017

    • Author(s)
      N. Naka, I. Akimoto, T. Shimomura, Ian Friel, and J. Isberg
    • Organizer
      Hasselt Diamond Workshop 2017 - SBDD XXII
    • Place of Presentation
      Hasselt, Belgium
    • Year and Date
      2017-03-09
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ルブレン単結晶における電場印加下での光キャリア生成と試料酸化の影響2017

    • Author(s)
      後藤 建太、高山敏暢、秋元郁子
    • Organizer
      日本物理学会 秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ルブレン単結晶における電場印加下での光キャリア生成2017

    • Author(s)
      後藤建太、高山敏暢、秋元郁子
    • Organizer
      第28回光物性研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高純度ダイヤモンド結晶における光キャリア生成経路2017

    • Author(s)
      濱端沙耶香、秋元郁子、中暢子
    • Organizer
      第28回光物性研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ルブレン結晶におけるマイクロ波共振器内での光キャリア注入2016

    • Author(s)
      高山敏暢、大畠慶三、秋元郁子
    • Organizer
      第27回光物性研究会
    • Place of Presentation
      神戸大学
    • Year and Date
      2016-12-02
    • Related Report
      2016 Research-status Report
  • [Presentation] 結晶成長法の異なる高純度シリコンにおける光キャリアサイクロトロン共鳴2016

    • Author(s)
      秋元郁子,高山敏暢,大畠慶三,中暢子
    • Organizer
      日本物理学会 2016年秋季大会
    • Place of Presentation
      金沢大学
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Exciton interband relaxation observed by time-resolved cyclotron resonance in diamond2016

    • Author(s)
      I. Akimoto and N. Naka
    • Organizer
      The 19th International Conference on Dynamical Processes in Excited States of Solids (DPC16)
    • Place of Presentation
      Paris, France
    • Year and Date
      2016-07-17
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高純度シリコン結晶における光生成キャリアのダイナミクス2016

    • Author(s)
      秋元郁子、大畠慶三、中暢子
    • Organizer
      日本物理学会 第71回年次大会(2016年)
    • Place of Presentation
      東北学院大学
    • Year and Date
      2016-03-20
    • Related Report
      2015 Research-status Report
  • [Presentation] Excitons and fundamental properties of diamond2016

    • Author(s)
      N. Naka, H. Morimoto, and I. Akimoto
    • Organizer
      Hasselt Diamond Workshop 2016 - SBDD XXI
    • Place of Presentation
      Hasselt, Belgium
    • Year and Date
      2016-03-09
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 高抵抗シリコンにおける定常・パルス光生成キャリアによるサイクロトロン共鳴の比較2015

    • Author(s)
      大畠慶三,合羽一貴,半田裕之,秋元郁子,中暢子
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-09-18
    • Related Report
      2015 Research-status Report
  • [Presentation] 高抵抗シリコンにおける光キャリア生成過程の励起波長依存性2015

    • Author(s)
      秋元郁子、大畠慶三、半田裕之、中暢子
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-09-17
    • Related Report
      2015 Research-status Report
  • [Presentation] Time-Resolved Cyclotron Resonance on Dislocation-Free HPHT Diamond2015

    • Author(s)
      I. Akimoto, N. Naka and N.Tokuda
    • Organizer
      The 9th international conference on new diamond and nano carbons 2015
    • Place of Presentation
      Shizuoka, Japan
    • Year and Date
      2015-05-26
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 光機能・ナノ材料グループHP

    • URL

      http://portal.sys.wakayama-u.ac.jp/mc/photon/index-aki.html

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2020-05-15  

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