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High pressure synthesis of novel ferroelectrics and characterization of structural inhomogeneities using thermal measurements

Research Project

Project/Area Number 15K05137
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics I
Research InstitutionNational Institute for Materials Science

Principal Investigator

Tachibana Makoto  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主任研究員 (40442727)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords強誘電性 / 単結晶 / フラックス法 / 熱測定 / 高圧合成 / ペロブスカイト型酸化物 / 比熱測定 / 熱膨張率測定 / 結晶成長 / 熱物性 / 強誘電体 / 物質探索 / 単結晶育成 / 比熱 / 熱伝導率
Outline of Final Research Achievements

Nanoscale inhomogeneities play fundamental roles in many functional materials. Especially, large piezoelectric effects are found in relaxor ferroelectrics, which is associated with the presence of polar nanoregions and the glasslike thermal behavior of these materials. In this study, high-quality single crystals of relaxor-like K1-xLixTaO3, KTa1-xNbxO3, Bi2WO6, SrBi2Ta2O9, and Bi4Ti3O12 were grown using the flux method, and their thermal conductivity and heat capacity were studied. The results show that these materials do not show glasslike behavior, indicating the absence of polar nanoregions.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (21 results)

All 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (10 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 10 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (4 results) (of which Int'l Joint Research: 1 results) Book (1 results) Remarks (3 results)

  • [Int'l Joint Research] McMaster University/University of Winnipeg(カナダ)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] NIST(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Paul Scherrer Institut(スイス)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Phase Competition in the Palmer-Chalker XY Pyrochlore Er2Pt2O72017

    • Author(s)
      A.M. Hallas, J. Gaudet, N.P. Butch, Guangyong Xu, M. Tachibana, C.R. Wiebe, G.M. Luke, and B.D. Gaulin
    • Journal Title

      Physical Review Letters

      Volume: 119 Issue: 18

    • DOI

      10.1103/physrevlett.119.187201

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] E-type noncollinear magnetic ordering in multiferroic o-LuMnO32017

    • Author(s)
      Saumya Mukherjee, Andreas Donni, Taro Nakajima, Setsuo Mitsuda, Makoto Tachibana, Hideaki Kitazawa, Vladimir Pomjakushin, Lukas Keller, Christof Niedermayer, Andrea Scaramucci, and Michel Kenzelmann
    • Journal Title

      Physical Review B

      Volume: 95 Issue: 10

    • DOI

      10.1103/physrevb.95.104412

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 熱容量・熱膨張測定を用いたスピン-格子強結合を有するフラストレーション磁性体の研究2017

    • Author(s)
      気谷 卓,橘 信,川路 均
    • Journal Title

      熱測定

      Volume: 44 Pages: 150-156

    • NAID

      40021375529

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] XY antiferromagnetic ground state in the effective S=1/2 pyrochlore Yb2Ge2O72016

    • Author(s)
      A. M. Hallas, J. Gaudet, M. N. Wilson, T. J. Munsie, A. A. Aczel, M. B. Stone, R. S. Freitas, A. M. Arevalo-Lopez, J. P. Attfield, M. Tachibana, C. R. Wiebe, G. M. Luke, B. D. Gaulin
    • Journal Title

      Phys. Rev. B

      Volume: 93 Issue: 10

    • DOI

      10.1103/physrevb.93.104405

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Universal dynamic magnetism in Yb pyrochlores with disparate ground states2016

    • Author(s)
      A. M. Hallas, J. Gaudet, N. P. Butch, M. Tachibana, R. S. Freitas, G. M. Luke, C. R. Wiebe, B. D. Gaulin
    • Journal Title

      Phys. Rev. B

      Volume: 93 Issue: 10

    • DOI

      10.1103/physrevb.93.100403

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Relief of frustration in the Heisenberg pyrochlore antiferromagnet Gd2Pt2O72016

    • Author(s)
      A. M. Hallas, A. Z. Sharma, Y. Cai, T. J. Munsie, M. N. Wilson, M. Tachibana, C. R. Wiebe, G. M. Luke
    • Journal Title

      10.1103/PhysRevB.94.134417

      Volume: 94 Issue: 13

    • DOI

      10.1103/physrevb.94.134417

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Low-temperature thermal expansion behavior of the geometrically frustrated pyrochlore Tb2Ti2O72016

    • Author(s)
      S. Kitani, M. Tachibana, H. Kawaji
    • Journal Title

      Solid State Commun.

      Volume: 247 Pages: 94-97

    • DOI

      10.1016/j.ssc.2016.08.020

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Broadband light-scattering spectroscopy onfractal and non-fractal relaxors2016

    • Author(s)
      Akitoshi Koreeda, Tomohiro Ogawa, Daisuke Katayama, Yasuhiro Fujii, and Makoto Tachibana
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 10S Pages: 10TC06-10TC06

    • DOI

      10.7567/jjap.55.10tc06

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Thermal conductivity of Aurivillius compounds Bi2WO6, SrBi2Ta2O9, and Bi4Ti3O122015

    • Author(s)
      Makoto Tachibana
    • Journal Title

      Solid State Communications

      Volume: 211 Pages: 1-3

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thermal conductivity of K1−xLixTaO3 and KTa1−xNbxO32015

    • Author(s)
      Makoto Tachibana
    • Journal Title

      Solid State Communications

      Volume: 221 Pages: 33-35

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] フラックス法によるルビーとサファイアの結晶育成2017

    • Author(s)
      橘信
    • Organizer
      平成29年度宝石学会(日本)総会・一般講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] フラックス法によるコランダム結晶の育成2017

    • Author(s)
      橘信
    • Organizer
      第12回日本フラックス成長研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Investigation of Crystal Growth and Magnetic Properties of Pr1-xLaxAlO32016

    • Author(s)
      C. Korosec, M. Tachibana, H. A. Dabkowska, B. D. Gaulin
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2016-08-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] (K,Li)TaO3およびK(Ta,Nb)O3の熱伝導率2015

    • Author(s)
      橘 信
    • Organizer
      日本物理学会 2015年秋季大会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Book] Beginner's Guide to Flux Crystal Growth2017

    • Author(s)
      Makoto Tachibana
    • Total Pages
      130
    • Publisher
      Springer
    • ISBN
      9784431565864
    • Related Report
      2017 Annual Research Report
  • [Remarks] SAMURAI

    • URL

      https://samurai.nims.go.jp/profiles/tachibana_makoto

    • Related Report
      2017 Annual Research Report
  • [Remarks] NIMS Researchers Database SAMURAI

    • URL

      http://samurai.nims.go.jp/TACHIBANA_Makoto-publication-j.html#Paper

    • Related Report
      2016 Research-status Report
  • [Remarks] NIMS Researcher Database Samurai

    • URL

      http://samurai.nims.go.jp/TACHIBANA_Makoto-j.html

    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2022-06-06  

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