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Verification of a possibility for valence fluctuation in uranium compounds probed by high-resolution x-ray spectroscopy under multiple extreme conditions

Research Project

Project/Area Number 15K05195
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionJapan Synchrotron Radiation Research Institute

Principal Investigator

Kawamura Naomi  公益財団法人高輝度光科学研究センター, 利用研究促進部門, 主幹研究員 (40393318)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsウラン化合物 / 量子臨界現象 / 価数ゆらぎ / X線発光分光 / X線吸収分光 / ウラン価数
Outline of Final Research Achievements

To understand exotic physical properties in uranium compounds derived by 5f electrons from a viewpoint of uranium valence states, high-energy resolution x-ray absorption spectroscopy was performed under low temperature, high magnetic field, and high pressure. A uranium compound, whose uranium valence states vary with temperature and pressure, was found for the first time, while there is little change in the valence states for most of uranium compounds. To clarify a factor of the valence variation, it is necessary to investigate the correlation with physical properties in near future. However, establishment of the method to precisely investigate valence states for the materials in 5f-electron system would advance understanding with interesting physics in f-electron systems.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (17 results)

All 2018 2017 2016 2015

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 2 results) Presentation (13 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Estimation of Ce 4f-5d Interaction by Analysis of Partial Fluorescence Yield at the Ce L3 Edge of CeO22017

    • Author(s)
      Tonai Hironori、Sasabe Norimasa、Uozumi Takayuki、Kawamura Naomi、Mizumaki Masaichiro
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 86 Issue: 9 Pages: 093704-093704

    • DOI

      10.7566/jpsj.86.093704

    • NAID

      210000134493

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic circular dichroism of X-ray spectroscopy for spinel-type ferrites in hard X-ray region: X-ray absorption, X-ray emission, and X-ray photoemission2017

    • Author(s)
      Kawamura N.、Ikenaga E.、Mizumaki M.、Hiraoka N.、Yanagihara H.、Maruyama H.
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 220 Pages: 81-85

    • DOI

      10.1016/j.elspec.2017.01.009

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Lifetime-Broadening-Suppressed X-ray Absorption Spectrum of β-YbAlB4 Deduced from Yb 3d→2p Resonant X-ray Emission Spectroscopy2017

    • Author(s)
      N. Kawamura, N. Kanai, H. Hayashi, Y. H. Matsuda, M. Mizumaki, K. Kuga, S. Nakatsuji and S. Watanabe
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 86 Issue: 1 Pages: 014711-014711

    • DOI

      10.7566/jpsj.86.014711

    • NAID

      210000134233

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Applications of nano-polycrystalline diamond anvils to X-ray absorption spectroscopy under high pressure2016

    • Author(s)
      N. Ishimatsu, N. Kawamura, M. Mizumaki, H. Maruyama, H. Sumiya, and T. Irifune
    • Journal Title

      High Pressure Research

      Volume: 36 Issue: 3 Pages: 381-390

    • DOI

      10.1080/08957959.2016.1205048

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] 共鳴X線発光分光によるYbCo2Zn20のYb電子状態の研究2018

    • Author(s)
      河村直己、播木敦、広瀬雄介、本多史憲、水牧仁一朗、魚住孝幸
    • Organizer
      第73回日本物理学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] BL39XUにおけるマルチアナライザー型X線発光分光測定装置の現状2018

    • Author(s)
      河村直己、水牧仁一朗、下笠諒平、三村功次郎
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] UGe2における低温・高圧条件下での共鳴X線発光分光2017

    • Author(s)
      河村直己, 本多史憲, 広瀬雄介, 鈴木佳孝, 水牧仁一朗, 中村愛, 青木大
    • Organizer
      日本物理学会第72回年次大会
    • Place of Presentation
      大阪大学 (大阪府・豊中市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] BL39XUのX線発光分光測定の現状2017

    • Author(s)
      河村直己, 水牧仁一朗, 新田清文, 朝倉博行
    • Organizer
      第30回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      神戸芸術センター (兵庫県・神戸市)
    • Year and Date
      2017-01-07
    • Related Report
      2016 Research-status Report
  • [Presentation] X線吸収・発光分光によるウラン化合物のウラン価数状態の研究2017

    • Author(s)
      河村直己、広瀬雄介、鈴木佳孝、本多史憲、水牧仁一朗、土塔寛、李德新、芳賀芳範、仲村愛、青木大、大貫惇睦
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 共鳴X線発光分光による複合極限環境下での電子状態の研究2017

    • Author(s)
      河村直己
    • Organizer
      第20回XAFS討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Uranium valence states probed by x-ray absorption and emission spectroscopy at uranium L3-edge2017

    • Author(s)
      Naomi Kawamura、Yusuke Hirose、Yoshitaka Suzuki、Fuminori Honda、Masaichiro Mizumaki、Hiroshi Doto、Dexin Li、Yoshinori Haga、Yusei Shimizu、Ai Nakamura、Dai Aoki、and Yoshichika Onuki
    • Organizer
      International Conference on Strongly Correlated Electron Systems 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] YbCo2Zn20における共鳴X線発光分光の線二色性の研究2016

    • Author(s)
      河村直己, 水牧仁一朗, 藤内博記, 魚住孝幸, 広瀬雄介, 本多史憲
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学 (石川県・金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Magnetic circular dichroism of X-ray absorption, emission, and photoemission in spinel-type ferrites2016

    • Author(s)
      N. Kawamura, M. Mizumaki, E. Ikenaga, N. Hiraoka, H. Yanagihara, and H. Maruyama
    • Organizer
      39th International Conference on Vacuum Ultraviolet and X-ray Physics
    • Place of Presentation
      チューリッヒ (スイス)
    • Year and Date
      2016-07-03
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Yb 3d-2p共鳴X線発光分光によるYbCo2Zn20およびYbCo2Ge4の電子状態の研究2016

    • Author(s)
      河村直己,水牧仁一朗,魚住孝幸,藤内博紀,松林和幸,岩谷誠,北川健太郎,広瀬雄介,本多史憲,渡辺真仁
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学 (宮城県・仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] SPring-8 BL39XUおよびBL01B1における共鳴X線発光分光の現状2016

    • Author(s)
      河村直己,水牧仁一朗,新田清文,朝倉博行
    • Organizer
      第29回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      東京大学柏の葉キャンパス駅前サテライト (千葉県・柏市)
    • Year and Date
      2016-01-09
    • Related Report
      2015 Research-status Report
  • [Presentation] X線発光分光による高エネルギー分解能XAFS分光2015

    • Author(s)
      河村直己,新田清文,朝倉博行,水牧仁一朗
    • Organizer
      第18回XAFS討論会
    • Place of Presentation
      高エネルギー加速器研究機構 (茨城県・つくば市)
    • Year and Date
      2015-07-29
    • Related Report
      2015 Research-status Report
  • [Presentation] Quantum Criticality and Valence Fluctuation Study for Ce- and Yb-based compounds Probed by 3d-2p Resonant X-ray Emission Spectroscopy2015

    • Author(s)
      Naomi Kawamura, Hironori Tonai, Masaichiro Mizumaki, Takayuki Uozumi, Shinji Watanabe
    • Organizer
      The 20th International Conference on Magnetism (ICM2015)
    • Place of Presentation
      Palau de Congressos and Hotel Rey Juan Carlos (スペイン・バルセロナ)
    • Year and Date
      2015-07-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2020-05-15  

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