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Structural fluctuation of supercritical solutions using anomalous small-angle X-ray scattering method

Research Project

Project/Area Number 15K05376
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionChiba University

Principal Investigator

Morita Takeshi  千葉大学, 大学院理学研究院, 准教授 (80332633)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsゆらぎ / 超臨界流体 / 異常小角X線散乱 / 濃度ゆらぎ / 異常分散 / 水溶液 / 小角X線散乱 / エネルギー変調 / 超臨界混合系
Outline of Final Research Achievements

Fluctuation is the key concept for understanding the structure of disordered systems. We can discuss the structural inhomogeneity using the fluctuations of number density and number concentration. However, we observed two peculiar behaviors of the concentration fluctuations for supercritical solutions obtained from combination of the scattering intensities and the thermodynamic quantities, which is a conventional method for evaluating the fluctuations.
Determination of the fluctuations only utilizing diffraction experiments was examined due to the issue mentioned above. We performed anomalous small-angle X-ray scattering (A-SAXS) measurements using synchrotron facility, BL-15A2 station at Photon Factory. Energy-variable SAXS experiments were carried out for xenon-krypton mixtures. Concentration fluctuation of supercritical mixture was evaluated only utilizing diffraction experiments for the first time.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (22 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (2 results) Journal Article (12 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 6 results,  Open Access: 2 results) Presentation (8 results) (of which Int'l Joint Research: 2 results)

  • [Int'l Joint Research] The University of British Columbia(カナダ)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Roskilde University(デンマーク)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Effects of ionic liquid constituent cations, tetraalkylammoniums, on water studied by means of the “1-propanol probing methodology”2018

    • Author(s)
      K. Yonenaga, T. Morita, K. Nishikawa, Y. Koga
    • Journal Title

      Journal of Molecular Liquids

      Volume: 252 Pages: 58-61

    • DOI

      10.1016/j.molliq.2017.12.130

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Band shift and bandwidth broadening in Raman spectra of CO2 induced by absorption into an imidazolium-based ionic liquid, 1-ethyl-3-methylimidazolium tetrafluoroborate, up to 15 MPa2017

    • Author(s)
      S. Suzuki, S. Okumura, K. Nishikawa, H. Nakayama, and T. Morita
    • Journal Title

      Chemical Physics Letters

      Volume: 684 Pages: 346-350

    • DOI

      10.1016/j.cplett.2017.06.060

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mixing scheme of an aqueous solution of tetrabutylphosphonium trifluoroacetate in the water-rich region2017

    • Author(s)
      A. Nitta, T. Morita, K. Nishikawa, and Y. Koga
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 19 Issue: 25 Pages: 16888-16896

    • DOI

      10.1039/c7cp02997g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Model-potential-free determination of the interaction potential between biological sensing nanoparticles2017

    • Author(s)
      T. Morita, N. Uehara, H. Imamura, and T. Sumi
    • Journal Title

      Photon Factory Highlights 2016

      Volume: - Pages: 38-39

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluctuational parameters based on the Bhatia-Thornton theory for supercritical solutions: Application to a supercritical aqueous solution of n-pentane2017

    • Author(s)
      S. Shibuta, H. Imamura, K. Nishikawa, T. Morita
    • Journal Title

      Chem. Phys.

      Volume: 487 Pages: 30-36

    • DOI

      10.1016/j.chemphys.2017.02.003

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Interaction Potential between Biological Sensing Nanoparticles Determined by Combining Small-Angle X-ray Scattering and Model-Potential-Free Liquid Theory2016

    • Author(s)
      T. Morita, N. Uehara, K. Kuwahata, H. Imamura, T. Shimada, K. Ookubo, M. Fujita, T. Sumi
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 44 Pages: 25564-25571

    • DOI

      10.1021/acs.jpcc.6b06487

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] The effect of 2,2,2-trifluoroethanol on water studied by using third derivatives of Gibbs energy, G2016

    • Author(s)
      H. Ohgi, H. Imamura, K. Yonenaga, T. Morita, K. Nishikawa, P. Westh, Y. Koga
    • Journal Title

      J. Mol. Liq.

      Volume: 224 Pages: 401-407

    • DOI

      10.1016/j.molliq.2016.09.101

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nitroxyl-Radical-Catalyzed Oxidative Coupling of Amides with Silylated Nucleophiles through N-Halogenation2016

    • Author(s)
      K. Moriyama, M. Kuramochi, K. Fujii, T. Morita, H. Togo
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 47 Pages: 14546-14551

    • DOI

      10.1002/anie.201607223

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Large-area silica aerogel for use as Cherenkov radiators with high refractive index, developed by supercritical carbon dioxide drying2016

    • Author(s)
      M. Tabata, I. Adachi, Y. Hatakeyama, H. Kawai, T. Morita, T. Sumiyoshi
    • Journal Title

      The Journal of Supercritical Fluids

      Volume: 110 Pages: 183-192

    • DOI

      10.1016/j.supflu.2015.11.022

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Density Fluctuations in Aqueous Solution of Ionic Liquid with Lower Critical Solution Temperature: Mixture of Tetrabutylphosphonium Trifluoroacetate and Water.2015

    • Author(s)
      A. Nitta, T. Morita, S. Saita, Y. Kohno, H. Ohno and K. Nishikawa
    • Journal Title

      Chem. Phys. Lett.

      Volume: 628 Pages: 108-112

    • DOI

      10.1016/j.cplett.2015.03.026

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Absorption- and Pressure-Induced Structural Transition Exhibiting V-shaped Density Change in Imidazolium-based Ionic Liquid + CO2 System.2015

    • Author(s)
      S. Okumura, M. Ushio, A. Oishi, K. Nishikawa, and T. Morita
    • Journal Title

      Chem. Lett.

      Volume: 44 Issue: 7 Pages: 937-939

    • DOI

      10.1246/cl.150187

    • NAID

      130005085155

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effects of Constituent Ions of a Phosphonium-based Ionic Liquid on Molecular Organization of H2O as Probed by 1-propanol: Tetrabutylphosphonium and Trifluoroacetate Ions.2015

    • Author(s)
      T. Morita, K. Miki, A. Nitta, H. Ohgi, and P. Westh
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 34 Pages: 22170-22178

    • DOI

      10.1039/c5cp02329g

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] 回折実験のみに基づく超臨界溶液系の濃度ゆらぎ解析の試み2017

    • Author(s)
      森田 剛, 澁田 諭, 田中 良忠, 城間 蓉子, 西川 恵子
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 超臨界状態における水と疎水性物質の全濃度領域ゆらぎ構造2016

    • Author(s)
      澁田諭, 森田剛, 西川惠子
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 超臨界アンモニアのゆらぎ構造と水素結合性の寄与2016

    • Author(s)
      後藤 サユリ, 澁田 諭, 森田 剛, 西川 惠子
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] アンモニウム系イオン液体カチオンの疎水性/親水性と 水溶液中における凝集状態の評価2016

    • Author(s)
      米永 一輝, 二田 郁子, 西川 恵子, 古賀 精方, 森田 剛
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] NMR を用いた脂環式イオン液体[Pyrr1,4][NTf2]の相挙動とイオンダイナミクス2016

    • Author(s)
      小口聡, 藤井幸造, 森田剛, 西川惠子
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Aggregation/dispersion of asphaltene in solutions at elevated temperatures using small-angle X-ray scattering2016

    • Author(s)
      Takeshi Morita
    • Organizer
      PetroPhase 2016
    • Place of Presentation
      Elsinore, Denmark
    • Year and Date
      2016-06-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 小角X 線散乱およびラマン散乱によるイオン液体中の二酸化炭素吸蔵状態2015

    • Author(s)
      森田 剛, 奥村 脩平, 西川 恵子
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学今出川キャンパス 寒梅館
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
  • [Presentation] AGGREGATION AND DISPERSION PROCESS OF POLYMER-CONJUGATED GOLD NANOPARTICLES USING MODEL-POTENTIAL-FREE METHOD2015

    • Author(s)
      T. Morita, N. Uehara and T. Sumi
    • Organizer
      16th International Conference on Small-Angle Scattering
    • Place of Presentation
      ベルリン工科大学、ドイツ
    • Year and Date
      2015-09-13
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2019-03-29  

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