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Spectroscopic study of CH5+ molecular ion by infrared double resonance

Research Project

Project/Area Number 15K05391
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionOkayama University

Principal Investigator

TANG JIAN  岡山大学, グローバル人材育成院, 教授 (40379706)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywordsプロトン化メタン / 赤外分光 / 二重共鳴 / CH5+分子イオン / 赤外‐赤外二重共鳴 / 振動回転スペクトル / CH5+ / CH5+
Outline of Final Research Achievements

CH5+ molecular ion has been detected by mass analysis in lab and on the satellite Titan of Saturn, and the infrared spectrum of CH5+ has also been observed in laboratory. Although the detection of the interstellar CH5+ is expected, it has been hindered by the failure of the spectral assignment for long time. In the present study, we aimed to reveal the spectral assignment for CH5+ by the infrared double resonance.
Although we can observe the infrared spectrum of CH5+ by the highly sensitive cavity ring-down spectroscopy, we failed to observe the CH5+ signal of infrared double resonance with a cw laser and a pulsed laser. Since there is no previous example for the observation of mid-infrared double resonance of molecular ions, the present work should be an importance step towards the future realization.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (20 results)

All 2018 2017 2016 2015

All Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Acknowledgement Compliant: 2 results) Presentation (13 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Observation and analysis of optical free induction decay in the CH3F v4 band2018

    • Author(s)
      Y. Okabayashi, Y. Miyamoto, J. Tang, K. Kawaguchi
    • Journal Title

      Chem. Phys. Lett.

      Volume: 692 Pages: 106-110

    • DOI

      10.1016/j.cplett.2017.12.009

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Infrared spectroscopy of the NO3 radical from 2000 to 3000 cm-12018

    • Author(s)
      K. Kawaguchi, R. Fujimori, J. Tang, T. Ishiwata
    • Journal Title

      J. Mol. Spectrosc.

      Volume: 344 Pages: 6-16

    • DOI

      10.1016/j.jms.2017.09.012

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Infrared spectroscopy of 2v4 and v3 + 2v4 bands of the NO3 radical2017

    • Author(s)
      K. Kawaguchi, T. Narahara, R. Fujimori, J. Tang, T. Ishiwata
    • Journal Title

      J. Mol. Spectrosc.

      Volume: 334 Pages: 10-21

    • DOI

      10.1016/j.jms.2017.02.008

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Detection of HF Toward PKS 1830-211, Search for Interstellar H2F+, and Laboratory Study of H2F+ and H2Cl+ Dissociative Recombination2016

    • Author(s)
      K. Kawaguchi, S. Muller, J. H. Black, T. Amano, F. Matsushima, R. Fujimori, Y. Okabayahsi, H. Nagahiro, Y. Miyamoto and J. Tang
    • Journal Title

      Astrophys. J.

      Volume: 822 Issue: 2 Pages: 115-123

    • DOI

      10.3847/0004-637x/822/2/115

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Study of infrared emission spectroscopy for the B1Δg-A1Πu and B′1Σg+-A1Πu systems of C22016

    • Author(s)
      W. Chen, K. Kawaguchi, P. F. Bernath, and J. Tang
    • Journal Title

      J. Chem. Phys.

      Volume: 144 Issue: 6 Pages: 064301-064301

    • DOI

      10.1063/1.4940907

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Simultaneous analysis of the Ballik-Ramsay and Phillips systems of C2 and observation of forbidden transitions between singlet and triplet states2015

    • Author(s)
      Wang Chen, Kentarou Kawaguchi, Peter F. Bernath, Jian Tang
    • Journal Title

      J. Chem. Phys.

      Volume: 142 Issue: 6 Pages: 064317-064317

    • DOI

      10.1063/1.4907530

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] On the vibrational assignment in the ground electronic state of NO32015

    • Author(s)
      K. Kawaguchi, R. Fujimori, J. Tang, and T. Ishiwata
    • Journal Title

      J. Mol. Spectrosc.

      Volume: 314 Pages: 73-78

    • DOI

      10.1016/j.jms.2015.06.008

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] パルス放電においてNH2ラジカルの可視光スペクトル2018

    • Author(s)
      香川洋輝,赤塚貴宏,川口建太郎,唐健
    • Organizer
      第18回分子分光研究会(つくば市文科省研究交流センター)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 近赤外cwレーザーによる気相分子のラマン振動分光2018

    • Author(s)
      長谷川大輔,唐健
    • Organizer
      第18回分子分光研究会(つくば市文科省研究交流センター)
    • Related Report
      2017 Annual Research Report
  • [Presentation] NO3ラジカルのFTIR分光と振動準位解析2018

    • Author(s)
      川口建太郎, 藤森隆彰,唐健,石渡孝
    • Organizer
      第18回分子分光研究会(つくば市文科省研究交流センター)
    • Related Report
      2017 Annual Research Report
  • [Presentation] NO3ラジカルv1+v3と2v3バンドの解析―低いv3振動数の再確認2017

    • Author(s)
      川口建太郎, 藤森隆彰,唐健,石渡孝
    • Organizer
      第17回分子分光研究会(京都大学)
    • Related Report
      2017 Annual Research Report
  • [Presentation] キャビティリングダウン分光法によるNH2可視スペクトルの研究2016

    • Author(s)
      赤塚貴宏,川口建太郎,唐健
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] NO3ラジカルv3=1,v4=2状態(1927cm-1)の摂動解析2016

    • Author(s)
      川口建太郎,楢原達朗,藤森隆彰,唐健,石渡孝
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 時間分解赤外分光を用いたKrDの観測と解析2016

    • Author(s)
      西口和宏,Deo Mukul,唐健,川口建太郎
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Study of infrared emission spectroscopy for the B1Δg-A1Πu and B′1Σg+-A1Πu system of C22016

    • Author(s)
      J. Tang, W. Chen, K. Kawaguchi, and P. F. Bernath
    • Organizer
      71st International Symposium on Molecular Spectroscopy
    • Place of Presentation
      University of Illinois at Urbana-Champaign, USA
    • Year and Date
      2016-06-20
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] NO3ラジカルの振動波数と強度のパッケージによる計算2016

    • Author(s)
      唐健, 川口建太郎
    • Organizer
      第16回分子分光研究会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2016-05-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Simultaneous analysis of the Ballik-Ramsay and Phillips systems and observation of forbidden transitions between singlet and triplet states of C22015

    • Author(s)
      Jian Tang
    • Organizer
      14th National Conference on Chemical dynamics
    • Place of Presentation
      Xi’an, China
    • Year and Date
      2015-08-21
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Simultaneous analysis of the Ballik-Ramsay and Phillips systems of C2 and observation of forbidden transitions between singlet and triplet states2015

    • Author(s)
      W. Chen, K. Kawaguchi, P. F. Bernath, and J. Tang
    • Organizer
      Symposium on Advanced Molecular Spectroscopy
    • Place of Presentation
      東京大学駒場
    • Year and Date
      2015-07-18
    • Related Report
      2015 Research-status Report
  • [Presentation] Deperturbation analysis for the a3Π and c3Σ of C22015

    • Author(s)
      J. Tang, W. Chen, K. Kawaguchi
    • Organizer
      70th International Symposium on Molecular Spectroscopy
    • Place of Presentation
      University of Illinois at Urbana-Champaign, USA
    • Year and Date
      2015-06-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] C2の多電子状態の同時摂動解析2015

    • Author(s)
      唐健, 陳望, 川口建太郎
    • Organizer
      第15回分子分光研究会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-05-22
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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