Development of reverse micellar catalysis system that promotes efficient visible-light photoredox reactions
| Project/Area Number |
15K05421
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
依田 秀実 静岡大学, 工学部, 教授 (20201072)
仙石 哲也 静岡大学, 工学部, 准教授 (70451680)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 可視光増感反応 / 逆ミセル光触媒系 / 青色LED / 両親媒性ルテニウム錯体 / ラジカル二量体 / 逆ミセル / 光触媒 / 両親媒性構造 / ラジカル二量化 / 脱ハロゲン化 / 分子内環化反応 / 鎖状イミド / ２－オキシインドール / ルテニウム錯体 / ペリレンピスイミド / 脱ハロゲン化反応 |
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| Outline of Final Research Achievements |
This research work focuses on visible-light-induced photoredox reactions under catalysis by reverse micellar composites of amphiphilic catalysts and electronic mediators. Upon extensive experimentation, we discovered that the reverse micellar catalytic systems have complementary substrate specificity to allow predominantly chemoselective reactions. The results presented in this work demonstrate that the designed catalytic systems have the great potential to find many applications for developing new specific visible-light photoredox reactions.
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Report
(4 results)
Research Products
(51 results)
