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Development of Dye Sensitizers Containing Organoboron Complexes as Chromophores

Research Project

Project/Area Number 15K05422
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionNagoya Institute of Technology

Principal Investigator

ONO Katsuhiko  名古屋工業大学, 工学(系)研究科(研究院), 准教授 (20335079)

Project Period (FY) 2015-10-21 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsホウ素錯体色素 / 色素増感太陽電池 / 電荷移動遷移 / 電子注入効率 / 双極子モーメント / ホウ素色素 / ホウ素錯体 / 太陽電池色素 / 色素吸着 / 電子注入 / 色素吸着量
Outline of Final Research Achievements

We studied the improvement of dye sensitizers containing organoboron complexes as chromophores. In this study, we focused on the light absorption and the charge transfer properties of dyes, and synthesized new organoboron dyes for dye-sensitized solar cells. Study of these photovoltaic characteristics suggested that the process of light absorption → excitation → electron injection in solar cells occurred smoothly. Thus, we successfully observed maximum external quantum efficiencies of 80% range. As the result, the conversion efficiency reached 5.2%, which was a good value among the power conversion efficiencies of organoboron dyes. These results are significant information in the development of organoboron dyes for dye-sensitized solar cells.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (52 results)

All 2018 2017 2016 2015 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (46 results) (of which Int'l Joint Research: 8 results,  Invited: 1 results) Remarks (4 results)

  • [Journal Article] Multifunctional organic dyes: anion-sensing and light-harvesting properties of curcumin boron complexes2017

    • Author(s)
      Masahiro Tsuchikawa, Aya Takao, Takashi Funaki, Hideki Sugihara, Katsuhiko Ono
    • Journal Title

      RSC Advances

      Volume: - Issue: 58 Pages: 36612-36616

    • DOI

      10.1039/c7ra06778j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and Crystal Structure of 4,8-Di-tert-butyl-1,3,5,7(2,5)-tetraoxadiazola-2,6(2,6)-dipyridina-4,8(1,3)-dibenzenacyclooctaphane2017

    • Author(s)
      Katsuhiko Ono, Satoshi Karasuda, Masaaki Tomura
    • Journal Title

      Heterocycles

      Volume: 94 Issue: 12 Pages: 2209-2214

    • DOI

      10.3987/com-17-13815

    • NAID

      40021421516

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Molecular Structure and Electrochemical Properties of Quinacridonequinone BF2 Complex2018

    • Author(s)
      Koichiro Moriya, Ryohei Shimada, Katsuhiko Ono
    • Organizer
      2nd FRIMS International Symposium on Frontier Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Boron β-Ketoiminate Organic Dyes for Dye-Sensitized Solar Cells2018

    • Author(s)
      Fumina Yumioka, Katsuhiko Ono
    • Organizer
      2nd FRIMS International Symposium on Frontier Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Properties of BF2 Complex Dye with Improved Linearity2018

    • Author(s)
      Yuki Sakura, Keisuke Banno, Katsuhiko Ono
    • Organizer
      2nd FRIMS International Symposium on Frontier Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] キナクリドンキノンBF2 錯体の構造及び生成メカニズムの解明2018

    • Author(s)
      森谷晃一朗,島田涼介,小野克彦
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 拡張型トリフェニルアミンをもつ(1,3-ジケトナト)ボロンジフルオリド誘導体の合成研究2018

    • Author(s)
      佐倉裕規,阪野圭亮,小野克彦
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 5,6,11,12,17,18-ヘキサヒドロキシトリナフチレン誘導体の合成と性質2018

    • Author(s)
      西田圭吾,加藤真一郎,小野克彦,北村千寿
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] πスペーサーを有するホウ素キレート化合物の半導体特性2018

    • Author(s)
      杉浦壮,鈴木啓司,小野克彦
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] クルクミンホウ素錯体のクロミズム特性を用いたアニオンセンシング2017

    • Author(s)
      土川将宏,小野克彦
    • Organizer
      日本化学会第97春季年会2017
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-19
    • Related Report
      2016 Research-status Report
  • [Presentation] β-ケトイミネートホウ素錯体をもつ直線性の高い増感色素2017

    • Author(s)
      弓岡史奈,小野克彦
    • Organizer
      日本化学会第97春季年会2017
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-19
    • Related Report
      2016 Research-status Report
  • [Presentation] ビス(ジオキサボリン)誘導体の合成と光学特性2017

    • Author(s)
      石河文康,横井寛,小野克彦
    • Organizer
      日本化学会第97春季年会2017
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-19
    • Related Report
      2016 Research-status Report
  • [Presentation] 可溶性ビテトラセンの合成と性質2017

    • Author(s)
      北村千寿,本田 匡,小野克彦,西田純一,川瀬 毅
    • Organizer
      日本化学会第97春季年会2017
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-18
    • Related Report
      2016 Research-status Report
  • [Presentation] n型半導体特性を示すホウ素キレート化合物の固体電子物性2017

    • Author(s)
      鈴木啓司,小野克彦
    • Organizer
      日本化学会第97春季年会2017
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] ジインデノテトラセン二量体の合成と性質2017

    • Author(s)
      辻航平,川瀬毅,西田純一,小野克彦,北村千寿
    • Organizer
      日本化学会第97春季年会2017
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] 酸添加によりアニオン認識を示すマクロサイクルレセプター2017

    • Author(s)
      烏田諭志,小野克彦
    • Organizer
      日本化学会第97春季年会2017
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Application of Organoboron Compounds to High Performance n-Type Semiconductors and Sustainable Dye Sensitizers2017

    • Author(s)
      So Sugiura, Masahiro Tsuchikawa, Keiji Suzuki, Katsuhiko Ono
    • Organizer
      2017 International Symposium for Advanced Materials Research (ISAMR 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organic Dyes Containing Boron β-Ketoiminate Moieties for Dye-Sensitized Solar Cells2017

    • Author(s)
      Fumina Yumioka, Katsuhiko Ono
    • Organizer
      2017 International Symposium for Advanced Materials Research (ISAMR 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アセチレンで架橋されたホウ素キレートの電子物性2017

    • Author(s)
      杉浦壮,鈴木啓司,小野克彦
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] β-ケトイミネートホウ素錯体色素の太陽電池評価2017

    • Author(s)
      弓岡史奈,舩木敬,杉原秀樹,小野克彦
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ベンゼン系溶媒中でのビス(ジオキサボリン)誘導体の発光挙動2017

    • Author(s)
      石河文康,小野克彦
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 2,3-ジニトロキニザリンの合成と溶媒依存光物性2017

    • Author(s)
      中川秀美,竹原宗範,加藤慎一郎,丸尾雅啓,小野克彦,藤本和宏,北村千寿
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Boc 基を用いた熱変換型有機半導体の開発2017

    • Author(s)
      牧野雄也,今枝優太,小野克彦
    • Organizer
      第48回中部化学関係学協会支部連合秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ナフトキノン環化三量体の誘導体の合成と反応2017

    • Author(s)
      西田圭吾,加藤真一郎,小野克彦,北村千寿
    • Organizer
      第11回有機π電子系シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 可溶性ビテトラセン誘導体の合成と性質2016

    • Author(s)
      本田匡,小野克彦,西田純一,川瀬毅,北村千寿
    • Organizer
      第10回有機π電子系シンポジウム
    • Place of Presentation
      あうる京北(京都市)
    • Year and Date
      2016-12-15
    • Related Report
      2016 Research-status Report
  • [Presentation] 水分子を包接する擬似マクロサイルの物性調査2016

    • Author(s)
      中川智裕,小野克彦
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2016-11-15
    • Related Report
      2016 Research-status Report
  • [Presentation] N-Bocピロールの分子変換反応を用いた有機半導体の開発2016

    • Author(s)
      牧野雄也,小野克彦
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2016-11-15
    • Related Report
      2016 Research-status Report
  • [Presentation] ビス(ジオキサボリン)の基礎物性と機能性色素としての展開2016

    • Author(s)
      石河文康,横井寛,小野克彦
    • Organizer
      第47回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋技術科学大学
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] 5,12-ジアルキニルテトラセン誘導体の合成と性質2016

    • Author(s)
      平松勇人,古川渉,西田純一,川瀬毅,小野克彦,北村千寿
    • Organizer
      第25回有機結晶シンポジウム
    • Place of Presentation
      京都大学
    • Year and Date
      2016-09-19
    • Related Report
      2016 Research-status Report
  • [Presentation] クルクミンホウ素錯体のクロミズム特性と太陽電池特性2016

    • Author(s)
      土川将宏,高尾綾,舩木敬,杉原秀樹,小野克彦
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場
    • Year and Date
      2016-09-02
    • Related Report
      2016 Research-status Report
  • [Presentation] 酸添加により生じるピリジニウムイオンを利用したアニオン認識2016

    • Author(s)
      烏田諭志,小野克彦
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場
    • Year and Date
      2016-09-01
    • Related Report
      2016 Research-status Report
  • [Presentation] 5,12-ジフェニルテトラセンの縮環反応を利用した多環式芳香族炭化水素の合成と性質2016

    • Author(s)
      辻航平,川瀬毅,西田純一,小野克彦,北村千寿
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場
    • Year and Date
      2016-09-01
    • Related Report
      2016 Research-status Report
  • [Presentation] O^N配位ホウ素錯体を用いたドナー-π-アクセプタ型太陽電池色素2016

    • Author(s)
      石河文康, 小野克彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] ピリジンの窒素部位を環内側に有するマクロサイクルの合成と物性2016

    • Author(s)
      烏田諭志, 小野克彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] 水分子を包接した擬似マクロサイクルの合成と物性2016

    • Author(s)
      中川智裕, 小野克彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] Boc基を用いた溶液プロセスが可能な熱変換型有機半導体の開発2016

    • Author(s)
      牧野雄也, 小野克彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] ホウ素キレート化合物のπ共役系拡張による物性への影響2016

    • Author(s)
      鈴木啓司, 小野克彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] クロミズム特性を有するクルクミンホウ素錯体の太陽電池色素への応用2016

    • Author(s)
      土川将宏, 高尾 綾, 小野克彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] アルコキシ基を有するアントラキノン / アントラセン二量体の合成と性質2016

    • Author(s)
      平松勇人,古川 渉,竹原宗範,井上吉教,北村千寿,西田純一,川瀬 毅,小野克彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] Solid-state optical properties and crystal structures of 1,4-dipropoxy-9,10-anthraquinone polymorphs2015

    • Author(s)
      Chitoshi Kitamura, Sining Li, Munenori Takehara, Yoshinori Inoue, Katsuhiko Ono, Takeshi Kawase, Kazuhiro Fujimoto
    • Organizer
      2015環太平洋国際化学会議
    • Place of Presentation
      Hawaii Convention Center (Honolulu)
    • Year and Date
      2015-12-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 光捕集能及びイオンセンシング機能を有するクルクミンホウ素錯体を用いた太陽電池色素の開発2015

    • Author(s)
      土川将宏,高尾 綾,船木 敬,杉原秀樹,小野克彦
    • Organizer
      第42回有機典型元素化学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2015-12-05
    • Related Report
      2015 Research-status Report
  • [Presentation] ホウ素錯体色素における折れ曲がり構造と物性の関係2015

    • Author(s)
      阪野圭亮, 小野克彦
    • Organizer
      第9回有機π電子系シンポジウム
    • Place of Presentation
      レイクサイド入鹿(犬山)
    • Year and Date
      2015-11-20
    • Related Report
      2015 Research-status Report
  • [Presentation] ホウ素キレート化合物の溶液安定性に対するπ共役拡張の効果2015

    • Author(s)
      鈴木啓司, 小野克彦
    • Organizer
      第9回有機π電子系シンポジウム
    • Place of Presentation
      レイクサイド入鹿(犬山)
    • Year and Date
      2015-11-20
    • Related Report
      2015 Research-status Report
  • [Presentation] クルクミンホウ素錯体を用いた太陽電池色素のクロミズム特性に関する研究2015

    • Author(s)
      土川将宏, 高尾 綾, 小野克彦
    • Organizer
      第9回有機π電子系シンポジウム
    • Place of Presentation
      レイクサイド入鹿(犬山)
    • Year and Date
      2015-11-20
    • Related Report
      2015 Research-status Report
  • [Presentation] アルコキシ基を有するアントラキノン/アントラセンの合成と性質2015

    • Author(s)
      平松勇人, 古川 渉, 北村千寿, 西田純一, 川瀬 毅, 小野克彦
    • Organizer
      第9回有機π電子系シンポジウム
    • Place of Presentation
      レイクサイド入鹿(犬山)
    • Year and Date
      2015-11-20
    • Related Report
      2015 Research-status Report
  • [Presentation] Synthesis and Properties of Boron-Chelating Bithiophene Derivatives Extended by Olefinic Accetylenic Spacers2015

    • Author(s)
      Keiji Suzuki, Yilihamu Yisilamu, Katsuhiko Ono
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      Rihga Royal Hotel Kyoto(Kyoto)
    • Year and Date
      2015-11-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Light-Harvesting and Ion-Sensing Properties of Curcumin Boron Complexes for Dye-Sensitized Solar Cells2015

    • Author(s)
      Masahiro Tsuchikawa, Aya Takao, Takashi Funaki, Hideki Sugihara, Katsuhiko Ono
    • Organizer
      The 13th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      Rihga Royal Hotel Kyoto(Kyoto)
    • Year and Date
      2015-11-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] n型半導体特性を示すビチオフェン誘導体の合成と物性2015

    • Author(s)
      鈴木啓司, Yilihamu Yisilamu, 小野克彦
    • Organizer
      第46回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      三重大学
    • Year and Date
      2015-11-07
    • Related Report
      2015 Research-status Report
  • [Remarks] 名古屋工業大学 小野克彦研究室

    • URL

      http://ono.web.nitech.ac.jp/

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
  • [Remarks] 研究者データベース:小野克彦

    • URL

      http://researcher.nitech.ac.jp/html/84_ja.html

    • Related Report
      2017 Annual Research Report 2015 Research-status Report
  • [Remarks] 研究者データベース:小野克彦

    • URL

      http://researcher.nitech.ac.jp/html/84_ja.html?l=ja&k=%E5%B0%8F%E9%87%8E%E3%80%80%E5%85%8B%E5%BD%A6&o=title-a&p=1

    • Related Report
      2016 Research-status Report
  • [Remarks] 名古屋工業大学 小野克彦研究室

    • URL

      http://www.ach.nitech.ac.jp/~physchem/ono/index.htm

    • Related Report
      2015 Research-status Report

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Published: 2015-10-21   Modified: 2019-03-29  

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