| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Outline of Final Research Achievements |
A most persistent triplet di(9-anthryl)carbene, incorporated into mesoporous silica MCM-41, was observed even after 220 hours at room temperature. Furthermore, the crystalline states of the triplet carbene survived even after 7 months under degassed conditions at room temperature.
(9-Anthryl)(phenyl)carbene derivative, connected on self-assembled monolayer (SAM) of a tripod-shaped trithiol on a gold substrate, did not dimerized and was more stable than in solution.
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