| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
In this project, novel luminescent copper(I) and silver(I) complexes were prepared by utilization of diphosphine ligands and by the formation of mixed-crystals. The copper(I) complex having 1,5-bis(diphenylphosphino)pentane and 4,4’-bipyridine as bridging ligands was prepared as a doubly bridged luminescent coordination polymer. In the study on mixed-crystals, the mixed-bridged silver(I) coordination polymers having bipyridine and 4,4’-bipiperidine and the copper(I) coordination polymers with bis(pyridyl)ethane and bis(pyridyl)ethylene were prepared. The bipiperidine-bipyridine system revealed that the luminescent properties of bipyridine site are modified in the mixed-crystals. The bis(pyridyl)ethane-bis(pyridyl)ethylene system becomes an antenna system as the related mixed-metallic coordination polymers.
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