| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
This research is aimed at the construction and functionalities of ionic metal complexes consisting of both cationic and anionic complexes. Hydrogen-bonding interactions are often utilized for the aggregation of preorganized discrete molecules. In this work, the new ligand bearing a biguanide moiety as a hydrogen-bonding donor and a carboxylate group as a hydrogen-bonding acceptor was designed, and the porous hydrogen-bonding network structure was constructed. Structural conversion and chiral selectivity were demonstrated. In addition, the phenyl groups were introduced to the ligand system, which resulted in the flexible structural conversion and the molecular recognition.
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