The creation and applications of the hydrogen bonding 3 D assembly system based on the dinuclear iron(II) triple helicate
Project/Area Number |
15K05455
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Okayama University |
Principal Investigator |
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Research Collaborator |
SUZUKI Takayoshi 岡山大学, 大学院自然科学研究科, 教授
KOJIMA Masaaki 岡山大学, 名誉教授
|
Project Period (FY) |
2015-04-01 – 2018-03-31
|
Project Status |
Completed (Fiscal Year 2017)
|
Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
Keywords | 三重らせん型鉄(II)錯体 / 水素結合 / 三次元集積化構造 / 分子取り込み能 / キラル認識 / スピンクロスオーバー |
Outline of Final Research Achievements |
The preparation of 3 D assembly was attempted by the partial deprotonation of the iron(II) triple helicate aiming applications for chiral recognition and molecular sensor. Although the research objective is not reached up to date, tetranuclear tetrahedral molecules developable to cage complexes were obtained instead. In addition, it was revealed that slow conformational change of ligand substituent in solid state causes the scan-rate dependent spin-crossover behavior of a mononuclear Fe(II) complex with related bidentate ligand.
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Report
(4 results)
Research Products
(9 results)