Development of Catalytic Reactions using sigma Electron Acceptor Ligand
| Project/Area Number |
15K05458
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
Kameo Hajime 大阪府立大学, 理学(系)研究科(研究院), 准教授 (50597218)
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| Research Collaborator |
NAKAZAWA Hiroshi
SAKAKI Shigeyoshi
BOURISSOU Didier
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 無機化学 / 錯体化学 / 有機金属化学 / σ電子受容性配位子 / シラン / ボラン / フッ素 / 結合切断 / 結合変換 / イリジウム錯体 / Si-F 結合 |
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| Outline of Final Research Achievements |
Main purpose of this research project is to gain deep understanding of properties and functions concerning σ electron acceptor (Z-type) ligands. Three important results are described here. (1) Roles of Z-type (Pt→B) interaction in B-F bond activation of BF3 were revealed. (2) E-F (E = Si, Ge, Sn) bond activation was achieved by forming Z-type interaction. (3) E-F bond cleavage reactions were expanded to catalytic reactions. These findings may provide a novel strategy for the synthesis of heavier Group 14 compounds.
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Report
(4 results)
Research Products
(26 results)
