| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
Main purpose of this research project is to gain deep understanding of properties and functions concerning σ electron acceptor (Z-type) ligands. Three important results are described here. (1) Roles of Z-type (Pt→B) interaction in B-F bond activation of BF3 were revealed. (2) E-F (E = Si, Ge, Sn) bond activation was achieved by forming Z-type interaction. (3) E-F bond cleavage reactions were expanded to catalytic reactions. These findings may provide a novel strategy for the synthesis of heavier Group 14 compounds.
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