Development of Novel Functional Complexes by Chirality-assisted Preparative Strategies
| Project/Area Number |
15K05479
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
KANEGAWA Shinji 九州大学, 先導物質化学研究所, 助教 (20516463)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 固体物性 / キラリティ / 異核錯体 / 磁気特性 / 結晶構造制御 / 外場応答性 / 機能性分子 / 電子物性 / 非対称性 / 外場感応性 / 金属錯体 / 機能性文 |
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| Outline of Final Research Achievements |
We proposed a novel Chirality-assisted synthetic strategy for difficult heterometallic complex preparations and demonstrated this is an applicable useful strategy for various elements in this research. Furthermore, new stimuli-responsive polarization switch crystals based on the intramolecular electron transfer were successfully developed. Our strategy proposed here based on a general tendency of chiral molecules which prefer forming symmetric molecular structures and crystallize in racemates. Thus it has a wide coverage, and it is in particular important result that we demonstrated an effective strategy for study of molecular functional materials.
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Report
(4 results)
Research Products
(8 results)
