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Development of Novel Functional Complexes by Chirality-assisted Preparative Strategies

Research Project

Project/Area Number 15K05479
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionKyushu University

Principal Investigator

KANEGAWA Shinji  九州大学, 先導物質化学研究所, 助教 (20516463)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords固体物性 / キラリティ / 異核錯体 / 磁気特性 / 結晶構造制御 / 外場応答性 / 機能性分子 / 電子物性 / 非対称性 / 外場感応性 / 金属錯体 / 機能性文
Outline of Final Research Achievements

We proposed a novel Chirality-assisted synthetic strategy for difficult heterometallic complex preparations and demonstrated this is an applicable useful strategy for various elements in this research. Furthermore, new stimuli-responsive polarization switch crystals based on the intramolecular electron transfer were successfully developed. Our strategy proposed here based on a general tendency of chiral molecules which prefer forming symmetric molecular structures and crystallize in racemates. Thus it has a wide coverage, and it is in particular important result that we demonstrated an effective strategy for study of molecular functional materials.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (8 results)

All 2018 2017 2016 2015

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results) Presentation (6 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Directional Electron Transfer in Crystals of [CrCo] Dinuclear Complexes Achieved by Chirality-Assisted Preparative Method2016

    • Author(s)
      Shinji Kanegawa, Yoshihito Shiota, Soonchul Kang, Kazuyuki Takahashi, Hajime Okajima, Akira Sakamoto, Tatsuya Iwata, Hideki Kandori, Kazunari Yoshizawa, and Osamu Sato
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 43 Pages: 14170-14173

    • DOI

      10.1021/jacs.6b05089

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of IntermolecularInteractions on Valence Tautomeric Behaviors in TwoPolymorphic DinuclearCobalt Complexes2016

    • Author(s)
      Guo-Ling Li, Shinji Kanegawa, Zi-Shuo Yao, Sheng-Qun Su, Shu-Qi Wu, You-Gui Huang, Soonchul Kang,and Osamu Sato
    • Journal Title

      Chem. Euro. J.

      Volume: 22 Issue: 48 Pages: 17130-17135

    • DOI

      10.1002/chem.201603817

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] キラル配位子を用いた原子価互変異性錯体の合成及び磁気特性2018

    • Author(s)
      瀬島 響・金川 慎治・中西 匠・佐藤 治
    • Organizer
      日本化学会 第98春季年会 (2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Spin Crossover in Cyanide-Bridged [FeIII 2FeII 2] Tetranuclear Clusters with Chiral Ligands2018

    • Author(s)
      LI, Junqiu; KANEGAWA, Shinji; SATO, Osamu
    • Organizer
      日本化学会 第98春季年会 (2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Deliberate Synthesis of Functional Hetrometallic Complexes by Chiral Ligands2017

    • Author(s)
      金川 慎治・佐藤 治
    • Organizer
      錯体化学会 第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 分子配向を制御した外場感応性錯体分子結晶の合成と物性2016

    • Author(s)
      金川慎治、姜 舜哲、佐藤 治
    • Organizer
      第10回 分子科学討論会
    • Place of Presentation
      神戸ファッションマート
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Polar Crystal Structures and Stimuli-responsive Magnetic Behaviors of Heterometallic Dinuclear Complexes Achieved by Chirality-assisted Synthetic Method2016

    • Author(s)
      Shinji Kanegawa, Soonchul Kang and Osamu Sato
    • Organizer
      ICMM2016 The 15th International Conference on Molecule-Based Magnets
    • Place of Presentation
      Sendai International Center
    • Year and Date
      2016-09-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Chirality-assisted Preparation of Hetero Metallic Complexes and Their Physical Properties2015

    • Author(s)
      Shinji Kanegawa, Soonchul Kang and Osamu Sato
    • Organizer
      環太平洋国際化学会議 (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2019-03-29  

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