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Development of functional organic materials showing adhesive or coating ability with gelation.

Research Project

Project/Area Number 15K05480
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionKyushu Institute of Technology

Principal Investigator

Tsuge Akihiko  九州工業大学, 大学院工学研究院, 教授 (80179986)

Co-Investigator(Kenkyū-buntansha) 北村 充  九州工業大学, 大学院工学研究院, 教授 (10313199)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsゲル / 酸化還元 / 水素結合 / オルガノゲル / シクロファン / フェロセン / 分子認識 / 蛍光発光
Outline of Final Research Achievements

In this research organogelator candidates which consist of the ferrocene unit have been prepared. It has been suggested that two amino acid residues in the structure are necessary to form a stable organogel. Addition of an oxidizing agent such as NaClO induces the collapse of the gel, and reproduction of the gel was observed by addition of a reducing agent such as glutathione. It has been found out that the on-off switching of gel formation can be achieved by red-ox reaction. Two kinds of glutamaic acid-based coumarin derivatives show a quite different trend against gelation in organic solvents in terms of inter- or intramolecular hydrogen bonds involved. It has been found out that addition of the valinate structure into the coumarine derivative could improve its gelation ability.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (24 results)

All 2018 2017 2016 2015

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Open Access: 2 results) Presentation (14 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] On-off switching of gel formation by red-ox reaction.2018

    • Author(s)
      Daisuke Yakeya, Tetsuji Moriguchi, Akihiko Tsuge
    • Journal Title

      Tetrahedron Letters

      Volume: 59 Issue: 8 Pages: 712-714

    • DOI

      10.1016/j.tetlet.2018.01.013

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design and properties of glutamic acid-based coumarin derivatives as organogelators2017

    • Author(s)
      Daisuke Yakeya, Naoya Kitou, Shougo Kinugawa, Tetsuji Moriguchi, Akihiko Tsuge
    • Journal Title

      Tetrahedron

      Volume: 73 Issue: 27-28 Pages: 3973-3978

    • DOI

      10.1016/j.tet.2017.05.074

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient synthesis of novel pyrrolo[2,3-c]pyridone derivatives using Ugi four-componeny reaction followed by condensation reaction2017

    • Author(s)
      Jalli Venkataprasado Jalli, Suvratha Krishnamurthy, Tetsuji Moriguchi, Akihiko Tsuge
    • Journal Title

      New Journal of Chemistry

      Volume: 41 Issue: 1 Pages: 97-107

    • DOI

      10.1039/c6nj02569b

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Molecular Structures of Two Novel p-Conjugated Extended Dithia[3.3]metacyclophanes2017

    • Author(s)
      Tetsuji Moriguchi, Daisuke Yakeya, Venkataprasad Jalli, Akihiko Tsuge, Kenji Yoza
    • Journal Title

      Cryst Struct Theor Appl

      Volume: 6 Issue: 01 Pages: 1-10

    • DOI

      10.4236/csta.2017.61001

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] The Syntheses, Crystal Structure and Luminescence Properties of Cone-Like Octadentate Europium (III) Complexes with Four Short Alkoxy Substituents2017

    • Author(s)
      Tetsuji Moriguchi, Satoshi Hirosaki, Venkataprasad Jalli, Akihiko Tsuge, Kenji Yoza
    • Journal Title

      Crystals

      Volume: 7 Pages: 85-94

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] One-pot four component synthesis of novel 3-furyl coumarin derivatives2016

    • Author(s)
      Venkataprasad Jalli, Suvratha Krishna Murthy, Tetsuji Moriguchi, Akihiko Tsuge
    • Journal Title

      J.Chem.Sci.

      Volume: 128 Issue: 2 Pages: 217-226

    • DOI

      10.1007/s12039-015-1014-8

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Syntheses, Characterization and DFT Analysis of Two Novel Thiaheterohelicene Derivatives2016

    • Author(s)
      Tetsuji Moriguchi, Keiichi Mitsumoto, Yuki Nishizawa, Daisuke Yakeya, Venkataprasad Jalli, Akihiko Tsuge
    • Journal Title

      Cryst Struct Theor Appl

      Volume: 5 Issue: 04 Pages: 63-73

    • DOI

      10.4236/csta.2016.54006

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Organogelators based on metacyclophane skeleton having urea units in the bridge2015

    • Author(s)
      Akihiko Tsuge, Tsugumichi Fujiwara, Daisuke Yakeya, Hiroyoshi Kawasaki, Tetsuji Moriguchi, Koji Araki
    • Journal Title

      Tetrahedron

      Volume: 71 Issue: 50 Pages: 9429-9432

    • DOI

      10.1016/j.tet.2015.10.056

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] a-Chymotrypsin and L-acylase aided synthesis of 5-hydroxypipecolic acid via Jacobsen's hydrolytic kinetic resolution of epoxy amino acids2015

    • Author(s)
      Suvratha Krishnamurthy, Venkataprasad Jalli, Tarun Chand Vagvala, Tetsuji Moriguch, Akihiko Tsuge
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 64 Pages: 52154-52160

    • DOI

      10.1039/c5ra09207h

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] SYNTHESIS OF NOVEL SPIRO[INDOL-2,20-PYRROLES] USING ISOCYANIDE-BASED MULTICOMPONENT REACTION2015

    • Author(s)
      Venkataprasad Jalli, Suvratha Krishnamurthy, Hiroyoshi Kawasaki, Tetsuji Moriguch, Akihiko Tsuge
    • Journal Title

      Synthetic Communications

      Volume: 45 Issue: 19 Pages: 2216-2226

    • DOI

      10.1080/00397911.2015.1071396

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 新規ピンセット型有機ゲル化剤の合成とその特性2018

    • Author(s)
      濱松 千明, 森口 哲次, 荒木 孝司, 柘植 顕彦
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] シクロファン骨格を基盤とした有機ゲル化剤の合成とその特性2018

    • Author(s)
      駄場 勇貴, 森口 哲次, 荒木 孝司, 柘植 顕彦
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カテコール部位を基本骨格とするゲル化剤の合成とその特性2017

    • Author(s)
      :嘉本崚汰,森口哲次、柘植顕彦
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] スチルベン骨格を有するメタシクロファン類の合成とその渡環相互作用2017

    • Author(s)
      宮本大輔,森口哲次、柘植顕彦
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] ピンセット型ゲル化剤の合成とその特性2017

    • Author(s)
      濱松千明、森口哲次、柘植顕彦
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] カテコール部位の特性を活用した有機ゲル化剤の合成とその評価2017

    • Author(s)
      嘉本崚汰、森口哲次、柘植顕彦
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Organogelators Consisting of Some Unique Moieties2017

    • Author(s)
      Akihiko Tsuge
    • Organizer
      Symposium on Applied Engineering and Sciences (SAES2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] フェロセン部位を有するゲル化剤の合成とその特性2017

    • Author(s)
      焼谷大輔,森口哲次、柘植顕彦
    • Organizer
      日本化学会第97春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 配位子型ゲル化剤の合成とその特性評価2016

    • Author(s)
      末原俊平、森口哲次、柘植顕彦
    • Organizer
      第10回有機π電子シンポジウム
    • Place of Presentation
      京都
    • Year and Date
      2016-12-16
    • Related Report
      2016 Research-status Report
  • [Presentation] クマリン及びフェロセン部位を有するゲル化剤の合成とその特性2016

    • Author(s)
      焼谷大輔,森口哲次、柘植顕彦
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島
    • Year and Date
      2016-09-01
    • Related Report
      2016 Research-status Report
  • [Presentation] フェロセン部位を有するゲル化剤の合成とその酸化還元応答ゲル化特性2016

    • Author(s)
      焼谷大輔,森口哲次、荒木孝司、柘植顕彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] 配位Eu錯体の合成とその構造特性評価2016

    • Author(s)
      廣﨑聖,森口哲次、荒木孝司、柘植顕彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] 配位子型ゲル化剤の合成とそのゲル化特性2016

    • Author(s)
      末原俊兵,森口哲次、荒木孝司、柘植顕彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] カテコール部位を有するゲル化剤の合成とその特性2016

    • Author(s)
      嘉本崚汰,森口哲次、荒木孝司、柘植顕彦
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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