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Utilization of HIgh-Density Monolayer Catalyst as a Micro Device

Research Project

Project/Area Number 15K05492
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Synthetic chemistry
Research InstitutionTokyo University of Technology

Principal Investigator

HARA Kenji  東京工科大学, 工学部, 教授 (10333593)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords触媒 / 単分子層 / マイクロ流路 / 有機合成 / 金属錯体 / 金表面
Outline of Final Research Achievements

This study developed the methods to utilize unique catalytic performances found in high-density monolayers of metal complex in a form of micro fluid device for chemical transformation. The purposes of this study include having improvement in catalytic performance due to additionally gained contact efficiency,and enabling rapid screening of optimized catalyst. Several key techniques for such novel chemical transformation device based on micro fluid system incorporated with monolayer of metal complex have been established. The developments obtained in this study can be applied for efficient synthesis of important pharmaceutical or functional compounds and their precursor intermediates, and will be contributed for future clinical and medicinal technology.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (21 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (1 results) Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (12 results) (of which Int'l Joint Research: 8 results,  Invited: 9 results) Book (1 results) Remarks (3 results)

  • [Int'l Joint Research] Institute of Chemical Technology(インド)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Electrical Matching at Metal/Molecule Contacts for Efficient Heterogeneous Charge Transfer2018

    • Author(s)
      Sato Shino、Iwase Shigeru、Namba Kotaro、Ono Tomoya、Hara Kenji、Fukuoka Atsushi、Uosaki Kohei、Ikeda Katsuyoshi
    • Journal Title

      ACS Nano

      Volume: 12 Issue: 2 Pages: 1228-1235

    • DOI

      10.1021/acsnano.7b07223

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Active Palladium Colloids via Palladacycle Degradation as Efficient Catalysts for Oxidative Homocoupling and Cross-Coupling of Aryl Boronic Acids2017

    • Author(s)
      Sable, V.; Maindan, K.; Kapdi, A. R.; Shejwalkar, P. S.; Hara, K.
    • Journal Title

      ACS Omega

      Volume: 2 Issue: 1 Pages: 204-217

    • DOI

      10.1021/acsomega.6b00326

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 規整表面上における高密度金属錯体単分子層の形成と触媒としての応用2015

    • Author(s)
      原 賢二
    • Journal Title

      触媒

      Volume: 57 Pages: 240-276

    • NAID

      40020562320

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ruthenium-Immobilized Periodic Mesoporous Organosilica: Synthesis, Characterization, and Catalytic Application for Selective Oxidation of Alkanes2015

    • Author(s)
      Nobuhiro Ishito, Hirokazu Kobayashi, Kiyotaka Nakajima, Yoshifumi Maegawa, Shinji Inagaki, Kenji Hara and Atsushi Fukuoka
    • Journal Title

      Chemistry - A European Journal

      Volume: 21 Issue: 44 Pages: 15564-15569

    • DOI

      10.1002/chem.201502638

    • NAID

      120005853067

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] High-density Organic Monolayer as a Novel Type of Support Material for Sustainable and Unique Catalysis2018

    • Author(s)
      Kenji Hara
    • Organizer
      Indo-Japan Conference (ICJ-2018) on New Insights into Multifunctional Catalysis for Biomass Transformation
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 構造規整表面固定化錯体触媒の開発とXAFSによる構造解析2018

    • Author(s)
      原 賢二
    • Organizer
      X線スペクトロスコピー利用研究会 第5回会合
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Catalysis with High Density Molecular Monolayers for Organic Transformation2017

    • Author(s)
      Kenji Hara
    • Organizer
      The 2nd European Organic Chemistry Congress
    • Place of Presentation
      Hyatt Place Amsterdam Airport (オランダ アムステルダム)
    • Year and Date
      2017-03-03
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] High-Density Monolayers of Metal Complex for Catalytic Application2017

    • Author(s)
      Kenji Hara
    • Organizer
      International Conference on Catalysis and Chemical Engineering (CCE-2017)
    • Place of Presentation
      The Double Tree by Hilton Baltimore-BWI Airport (アメリカ合衆国 メリーランド州 リンシカムハイツ)
    • Year and Date
      2017-02-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] High Density Molecular Array for Catalyst Preparation2017

    • Author(s)
      Kenji Hara
    • Organizer
      2017 International Conference on Nanospace Materials (ICNM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Iron-immobilized Periodic Mesoporous Organosilica as Active and Selective Catalyst for Amino Alcohol Synthesis2017

    • Author(s)
      P. Shejwalkar, K. Hara, Y. Maegawa, Y. Teraji, S. Inagaki
    • Organizer
      International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-Density Monolayer of Metal Complex: Preparation and Catalysis2016

    • Author(s)
      Kenji Hara
    • Organizer
      Global Research Efforts on Energy and Nanomaterials (GREEN 2016)
    • Place of Presentation
      GIS Taipei Tech Convention Center(台湾 台北市)
    • Year and Date
      2016-12-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 高密度固定化錯体触媒の調製と応用2016

    • Author(s)
      原 賢二
    • Organizer
      第13回触媒相模セミナー
    • Place of Presentation
      相模中央化学研究所(神奈川県綾瀬市)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] XAFSによる金属触媒の構造解析および中性子散乱への期待2016

    • Author(s)
      原 賢二
    • Organizer
      第2回 放射光・中性子の相補利活用セミナー
    • Place of Presentation
      研究社英語センタービル(東京都・新宿区)
    • Year and Date
      2016-02-19
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] メソポーラス有機シリカ -金属錯体触媒固定化担体としての活用-2015

    • Author(s)
      原 賢二
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学(三重県・津市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Ru-Immobilized Periodic Mesoporous Organosilica as Selective Catalyst in Alkane Oxidation2015

    • Author(s)
      Kenji Hara, Nobuhiro Ishito, Yoshifumi Maegawa, Shinji Inagaki and Atsushi Fukuoka
    • Organizer
      2015 International Conference on Nanospace Materials ―from fundamental to Advanced Applications― (ICNM 2015)
    • Place of Presentation
      国立台湾大学(台湾台北市)
    • Year and Date
      2015-06-23
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Immobilization of Ru Complexes on Periodic Mesoporous Organosilica and Catalytic Application in Selective Alkane Oxidation2015

    • Author(s)
      Kenji Hara, Nobuhiro Ishito, Yoshifumi Maegawa, Shinji Inagaki and Atsushi Fukuoka
    • Organizer
      4th North American Catalysis Society Meeting
    • Place of Presentation
      David L. Lawrence Convention Center (USA、Pittsburgh)
    • Year and Date
      2015-06-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Book] ナノ空間材料ハンドブック2016

    • Author(s)
      有賀 克彦 監修、 原 賢二 他78名著
    • Total Pages
      548
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2015 Research-status Report
  • [Remarks] 触媒化学研究室(原研究室)(研究室独自のページ)

    • URL

      https://haralab2016.wixsite.com/haralab

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
  • [Remarks] 東京工科大学工学部触媒化学(原)研究室(所属研究機関が作成したページ

    • URL

      http://www.teu.ac.jp/info/lab/project/es/dep.html?id=18

    • Related Report
      2017 Annual Research Report
  • [Remarks] 東京工科大学工学部触媒化学(原)研究室(所属研究機関が作成したページ)

    • URL

      http://www.teu.ac.jp/info/lab/project/es/dep.html?id=18

    • Related Report
      2016 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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