• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Design of Electrophoretic Non-Ionic Polymers and the Mechanism

Research Project

Project/Area Number 15K05515
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer chemistry
Research InstitutionNagoya Institute of Technology

Principal Investigator

TAKASU AKINORI  名古屋工業大学, 工学(系)研究科(研究院), 教授 (30303697)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords電気泳動堆積 / 非イオン性 / スルホニル基 / アクリルポリマー / ポリオキサゾリン / 高分子微粒子 / 階層構造 / 構造色 / 電気泳動 / カラー電着塗装 / 微粒子 / エマルション重合 / ポリエステル
Outline of Final Research Achievements

We investigated electrophoretic behaviors of non-ionic polymers containing sulfonyl groups. The negative zeta potential of each polymer dispersion (40 to 20 mV) was also confirmed, when we used various alcohols as the poor solvent, which reveals that the electrophoretic behavior is dependent upon a partial charge separation in the protic solvent (alcohol) at the interface of the dispersion. In this study, we performed electrophoresis of non-ionic nano particles (diameter: ca. 300 nm), prepared via soap-free emulsion copolymerization of vinyl monomers containing a sulfide linkage with styrene and subsequent oxidation to a sulfonyl group. After electrodeposition (EPD), a structural color was observed, indicating that the monodisperse spheres had attached to the surface and exhibited specific light diffraction.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (49 results)

All 2018 2017 2016 2015

All Journal Article (13 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 5 results) Presentation (31 results) (of which Int'l Joint Research: 6 results,  Invited: 2 results) Book (2 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Synthesis of Non-Ionic Poly(ester-sulfone) via Low Temperature Polycondensation for Anode-Selective Electrophoretic Deposition and Subsequent Photo Cross-linking2018

    • Author(s)
      Yoshifumi Matsumoto, Akinori Takasu
    • Journal Title

      Polymer Journal

      Volume: 50 Issue: 2 Pages: 187-196

    • DOI

      10.1038/s41428-017-0001-y

    • NAID

      40021452665

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature-Responsive Electrophoretic Deposition of Sulfone-Containing Non-Ionic Poly(N-isopropylacrylamide)2018

    • Author(s)
      Ken Kimizu, Akinori Takasu
    • Journal Title

      Macromolecular Chemistry and Physics

      Volume: 219 Issue: 2 Pages: 1700468-1700468

    • DOI

      10.1002/macp.201700468

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adhesion Control of Human Umbilical Vein Endothelial Cells Using Clickable Poly(2-oxazoline)-Grafted Biosynthesized Extracellular Matrix Protein2018

    • Author(s)
      Saki Morita, Akinori Takasu
    • Journal Title

      Polymer

      Volume: 136 Pages: 194-204

    • DOI

      10.1016/j.polymer.2017.12.059

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 非イオン性高分子微粒子によるカラー電着塗装の開発2018

    • Author(s)
      高須 昭則
    • Journal Title

      ファインケミカル

      Volume: 47 Pages: 44-49

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Electrophoretic non-ionic nano-spheres (latexes) for structural coloring2017

    • Author(s)
      Daiki Mokude, Akinori Takasu, Masahiro Higuchi
    • Journal Title

      Polymer

      Volume: 117 Pages: 243-248

    • DOI

      10.1016/j.polymer.2017.04.019

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrophoretic Deposition (EPD) of Lectin in the Presence of New Glycopolymers Aiming at Facile Detection of Carbohydrate-Protein Interactions2017

    • Author(s)
      Tomomi Komura, Akinori Takasu
    • Journal Title

      Macromolecular Chemistry and Physics

      Volume: 218 Issue: 23 Pages: 1700351-1700351

    • DOI

      10.1002/macp.201700351

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] N-Heterocyclic Carbene Initiated Anionic Polymerization of (E,E)-Methyl Sorbate and Subsequent Ring-Closing to Cyclic Poly(alkyl sorbate)2017

    • Author(s)
      Yuhei Hosoi, Akinori Takasu, Shin-Ichi Matsuoka, Mikihiro Hayashi
    • Journal Title

      Journal of the American Chemical Society

      Volume: 139 Issue: 42 Pages: 15005-15012

    • DOI

      10.1021/jacs.7b06897

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 電気泳動する非イオン性高分子を用いた省エネルギー型電着塗装2017

    • Author(s)
      杢出 大樹, 高須 昭則
    • Journal Title

      塗装工学

      Volume: 52 Pages: 100-105

    • NAID

      40021168685

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 日本塗装技術協会2017

    • Author(s)
      杢出 大樹、高須 昭則
    • Journal Title

      電着塗装

      Volume: 4 Pages: 100-105

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Alcohol Dependence of Anode-selective Electrophoretic Deposition of Non-Ionic Poly(ester-sulfone)2016

    • Author(s)
      Mizuki Yokoyama, Akinori Takasu
    • Journal Title

      Polymer

      Volume: 88 Pages: 1-8

    • DOI

      10.1016/j.polymer.2016.02.014

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A A Vinyl Polymer Having Pendent Sulfones Prepared by Atom-Transfer Radical Polymerization of a Sulfide-Containing Methacrylate and Electrophoretic Transparent Coating on a Stainless Steel AnodelTransparent Coating on a Stainless Steel Anodel2015

    • Author(s)
      Tomomi Kameyama, Akinori Takasu
    • Journal Title

      Polymer Chemistry

      Volume: 6 Issue: 23 Pages: 4336-4342

    • DOI

      10.1039/c5py00553a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Design of Electrophoretic Poly(2-oxazoline)s for Hybridization with Bioactive Glass2015

    • Author(s)
      Terunari Hayashi, Akinori Takasu
    • Journal Title

      Key Engineering Materials

      Volume: 654 Pages: 183-188

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrophoretic Vinyl Polymers Prepared via Atom Transfer Radical Polymerization and Smart Coating on Metals2015

    • Author(s)
      Tomomi Kameyama, Akinori Takasu
    • Journal Title

      Key Engineering Materials

      Volume: 654 Pages: 37-41

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 電気泳動する非イオン性高分子の設計と応用(バイオメイディカルから電着塗装まで)2017

    • Author(s)
      高須 昭則
    • Organizer
      科学技術交流財団 生きた再生医療用材料の開発研究会
    • Place of Presentation
      科学技術交流財団研究交流センター
    • Year and Date
      2017-02-17
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 非イオン性高分子微粒子の電気泳動による構造色の発現2017

    • Author(s)
      杢出 大樹, 高須 昭則, 樋口 真弘
    • Organizer
      第48回中部化学関連学協会 秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 非イオン性高分子微粒子の電気泳動による構造色塗装と評価2017

    • Author(s)
      杢出大樹、高須昭則、樋口真弘
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Electrophoretic Non-Ionic Nono-Spheres (Latexes) for Structural Coloring2017

    • Author(s)
      Daiki Mokude, Akinori Takasu, Masahiro Higuchi
    • Organizer
      254th ACS National Meeting & Exposition
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrophoretic Non-ionic Poly(N-isopropylacrylamide) Aiming for Temperature-Sensitive Cell-Cultivation Coating2017

    • Author(s)
      Ken Kimizu, Akinori Takasu
    • Organizer
      254th ACS National Meeting & Exposition
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 非イオン性高分子を用いた電着塗装2017

    • Author(s)
      杢出大樹, 高須昭則, 樋口真弘
    • Organizer
      第66回高分子年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] スルホニル基を有する非イオン性ポリウレタンの電着2017

    • Author(s)
      大野 晃典, 高須 昭則
    • Organizer
      第66回高分子年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 非イオン性高分子微粒子の電気泳動による構造色塗装2017

    • Author(s)
      杢出大樹, 高須昭則, 樋口真弘
    • Organizer
      第66回高分子年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Electrophoretic deposition of non-ionic latexes prepared by controlled radical polymerization2016

    • Author(s)
      Daiki Mokude, Masahiro Higuchi, Akinori Takasu
    • Organizer
      The 11th SPSJ International Polymer Conference (IPC2016)
    • Place of Presentation
      Fukuoka International Congress Center, Fukuoka, JAPAN
    • Year and Date
      2016-12-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of non-ionic electrophoretic unsaturated polyester and UV-curing2016

    • Author(s)
      Isamu Kawarazaki, Akinori Takasu
    • Organizer
      The 11th SPSJ International Polymer Conference (IPC2016)
    • Place of Presentation
      Fukuoka International Congress Center, Fukuoka, JAPAN
    • Year and Date
      2016-12-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Electrophoretic mechanism of non-ionic poly(ester-sulfone)2016

    • Author(s)
      Mizuki Yokoyama, Akinori Takasu
    • Organizer
      The 11th SPSJ International Polymer Conference (IPC2016)
    • Place of Presentation
      Fukuoka International Congress Center, Fukuoka, JAPAN
    • Year and Date
      2016-12-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 構造色を指向した非イオン性ラテックスの電気泳動2016

    • Author(s)
      杢出 大樹, 高須 昭則, 樋口 真弘
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] メタセシス重合による電気泳動する非イオン性不飽和ポリエステルの合成とUV硬化2016

    • Author(s)
      河原崎 勇, 高須 昭則
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 重縮合による電気泳動する非イオン性不飽和ポリ(エステル-スルホン)の合成とUV硬化2016

    • Author(s)
      松本圭史, 高須昭則
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 電気泳動する非イオン性ポリ(エステル-スルホン)の泳動機構の解明2016

    • Author(s)
      横山瑞季, 高須昭則
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 電気泳動する非イオン性ラテックスの設計2016

    • Author(s)
      杢出 大樹, 高須 昭則, 樋口 真弘
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
  • [Presentation] 水酸基を有するポリ(エステルースルホン)の合成と電着2016

    • Author(s)
      大野 晃典, 高須 昭則
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
  • [Presentation] 生合成した細胞外マトリックスタンパク質へのポリオキサゾリン側鎖のグラフト化2016

    • Author(s)
      森田 早紀, 高須 昭則
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
  • [Presentation] ADMET重合による電気泳動するスルホン含有ポリエステルの合成2016

    • Author(s)
      河原崎 勇, 高須 昭則
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
  • [Presentation] クリック反応による電気泳動するポリ(エステルースルホン)デンドリマーの合成2016

    • Author(s)
      河原崎 勇, 高須 昭則
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
  • [Presentation] Design of Electrophoretic Non-Ionic Polymers2016

    • Author(s)
      高須 昭則
    • Organizer
      The 3rd International Symposium for Green-Innovation Polymer (GRIP2016)
    • Place of Presentation
      JAPAN ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY
    • Year and Date
      2016-03-04
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of Electrophoretic Acrylic Polymer Synthesized via Atom Transfer Radical Polymerization2015

    • Author(s)
      亀山 友美
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ハワイコンベンションセンター
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
  • [Presentation] Electrophoretic Mechanism of Non-Ionic Poly(ester-sulfone)s2015

    • Author(s)
      横山 瑞季
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ハワイコンベンションセンター
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 電気泳動する非イオン性ポリメタクリレートの設計と堆積挙動2015

    • Author(s)
      亀山 友美
    • Organizer
      第46回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      三重大学
    • Year and Date
      2015-11-07
    • Related Report
      2015 Research-status Report
  • [Presentation] 非イオン性ポリエステルの電気泳動機構と極板への堆積2015

    • Author(s)
      横山 瑞季
    • Organizer
      第46回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      三重大学
    • Year and Date
      2015-11-07
    • Related Report
      2015 Research-status Report
  • [Presentation] スルフィドを含むモノマーの非環状ジエンメタセシス重合2015

    • Author(s)
      河原崎 勇
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 電気泳動する非イオン性ポリメタクリレート2015

    • Author(s)
      亀山 友美
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 電気泳動する非イオン性ポリマーの泳動メカニズム2015

    • Author(s)
      横山 瑞季
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] ポリ(エステルースルホン)分散液の電気泳動機構の解明2015

    • Author(s)
      横山 瑞季
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-05-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 重縮合による電気泳動するポリ(エステルースルホン)の合成2015

    • Author(s)
      松本 圭史
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-05-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 電気泳動するスルホン含有ポリメタクリレートの金属基盤へのクリアコーティング2015

    • Author(s)
      亀山 友美
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-05-27
    • Related Report
      2015 Research-status Report
  • [Book] 材料表面の親水・親油の評価と制御設計2016

    • Author(s)
      高須 昭則
    • Total Pages
      5
    • Publisher
      テクノシステム
    • Related Report
      2016 Research-status Report
  • [Book] 分散系の測定・評価と設計・応用2016

    • Author(s)
      高須 昭則
    • Publisher
      テクノシステム
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 透明性高分子樹脂2018

    • Inventor(s)
      林 幹大、高須 昭則、柴田桂輔
    • Industrial Property Rights Holder
      林 幹大、高須 昭則、柴田桂輔
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-080606
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 高分子微粒子からなる電着塗料組成物およびこの電着塗料組成物を用いた 複層塗膜の形成方法2016

    • Inventor(s)
      高須 昭則
    • Industrial Property Rights Holder
      高須 昭則
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-171367
    • Filing Date
      2016-09-02
    • Related Report
      2016 Research-status Report
  • [Patent(Industrial Property Rights)] スルホニル基を含む非イオン性高分子からなる電着塗料組成物2015

    • Inventor(s)
      高須 昭則
    • Industrial Property Rights Holder
      高須 昭則
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-143721
    • Filing Date
      2015-07-21
    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi