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Molecular mechanism for the resistance and degradation of organic materials to hydrogen radical

Research Project

Project/Area Number 15K05545
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Analytical chemistry
Research InstitutionYokohama City University

Principal Investigator

Takayama Mitsuo  横浜市立大学, 生命ナノシステム科学研究科(八景キャンパス), 教授 (10328635)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2017: ¥260,000 (Direct Cost: ¥200,000、Indirect Cost: ¥60,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords水素ラジカル / 質量分析 / 有機材料
Outline of Final Research Achievements

Hydrogen atoms (H) were generated from hydrogen gas (H2) by using a homemade H atom generator consisted of an ultraviolet light source incorporating a deuterium lamp and a reaction tube made of polycarbonate, under atmospheric pressure conditions. In order to confirm the generation of hydrogen atoms, resulting hydrogen atoms were irradiated onto the surface of a tip of polytetrafluoroethylene and a reaction product hydrogen fluoride (HF) were detected by an atmospheric pressure corona discharge ionization mass spectrometer. In order to examine the influence of hydrogen atoms on the resistance and degradation characteristics of an aramide synthetic polymer, Kevlar, the hydrogen atoms were irradiated to Kevler fibers. However, any degradation products were not detected, because the hydrogen-bond networks of Kevlar protect the carbonyl oxygens from the attack of hydrogen atoms.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (13 results)

All 2017 2016 2015 Other

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 4 results,  Acknowledgement Compliant: 1 results) Presentation (4 results) (of which Invited: 1 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Collision-Induced Dissociation Study of Strong Hydrogen-Bonded Cluster Ions Y<sup>−</sup>(HF)<i><sub>n</sub></i> (Y=F, O<sub>2</sub>) Using Atmospheric Pressure Corona Discharge Ionization Mass Spectrometry Combined with a HF Generator2017

    • Author(s)
      K. Sakamoto, K. Sekimoto and M. Takayama
    • Journal Title

      Mass Spectrometry

      Volume: 6 Issue: 1 Pages: A0063-A0063

    • DOI

      10.5702/massspectrometry.A0063

    • NAID

      130006091407

    • ISSN
      2186-5116, 2187-137X
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Oxidative radical driven cleavage of peptide backbone caused by matrix-assisted laser desorption/ionization in-source decay with low matrix-to-peptide molar ratios2017

    • Author(s)
      M. Yamakoshi and M. Takayama
    • Journal Title

      Int. J. Mass Spectrom.

      Volume: 422 Pages: 56-61

    • DOI

      10.1016/j.ijms.2017.08.006

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ionization Capabilities of Hydronium Ions and High Electric Fields Produced by Atmospheric Pressure Corona Discharge2017

    • Author(s)
      N. Sato, K. Sekimoto, M. Takayama
    • Journal Title

      Mass Spectrometry

      Volume: 5 Issue: 2 Pages: S0067-S0067

    • DOI

      10.5702/massspectrometry.S0067

    • NAID

      130005476003

    • ISSN
      2186-5116, 2187-137X
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] MALDI In-Source Decay of Protein2016

    • Author(s)
      Mitsuo Takayama
    • Journal Title

      Mass Spectrometry

      Volume: 5 Issue: 1 Pages: A0044-A0044

    • DOI

      10.5702/massspectrometry.A0044

    • NAID

      130005138385

    • ISSN
      2186-5116, 2187-137X
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Formation of c- and z-ions due to preferentail cleavage at the N-C bond of Xxx-Asp/Asn residues in negative-ion CID of peptides2015

    • Author(s)
      N. Sugasawa, T. Kawase, M. Oshikata, R. Iimuro, A. Motoyama, M. Takayama
    • Journal Title

      International Journal of Mass Spectrometry

      Volume: 383/384 Pages: 38-43

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 負イオンHFクラスターの水素結合解離反応とプロトン移動反応2017

    • Author(s)
      坂本賢也、高山光男
    • Organizer
      日本質量分析学会 総合討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Comprehensive Top-Down Analysis of Phosphorylated Intact Proteins using MALDI-ISD MS with 5-Amino-1-Naphthol Matrix2015

    • Author(s)
      Mitsuo Takayama
    • Organizer
      The 25th Australian and New Zealand Society for Mass Spectrometry Conference
    • Place of Presentation
      Brisbane
    • Year and Date
      2015-07-19
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] &#61538;-CaseinのMALDI-ISDフラグメント観測に対するイオン滞在時間の影響2015

    • Author(s)
      名越慶士郎・関谷禎則・岩本慎一・田中耕一・高山光男
    • Organizer
      第63回質量分析総合討論会
    • Place of Presentation
      つくば
    • Year and Date
      2015-06-17
    • Related Report
      2015 Research-status Report
  • [Presentation] ペプチド負イオンCIDにおけるcイオン生成機構-分子内プロトン引き抜き-2015

    • Author(s)
      本山晃・川瀬泰司・押方基司・菅澤奈美・高山光男
    • Organizer
      第63回質量分析総合討論会
    • Place of Presentation
      つくば
    • Year and Date
      2015-06-17
    • Related Report
      2015 Research-status Report
  • [Remarks]

    • URL

      http://masspecs.sci.yokohama-cu.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Remarks] Researchmap

    • URL

      https://researchmap.jp/read0074226/

    • Related Report
      2017 Annual Research Report
  • [Remarks] Mass Spectrometry Laboratory

    • URL

      http://masspecs.sci.yokohama-cu.ac.jp/

    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 原子状水素発生器、原子状水素の製造方法および原子状水素の発生を確認する方法2015

    • Inventor(s)
      高山光男
    • Industrial Property Rights Holder
      高山光男
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-111987
    • Filing Date
      2015-06-02
    • Related Report
      2015 Research-status Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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