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Three dimensional phase microscopy for photo-excited carriers

Research Project

Project/Area Number 15K05549
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Analytical chemistry
Research InstitutionChuo University

Principal Investigator

Kayatama Kenji  中央大学, 理工学部, 教授 (00313007)

Co-Investigator(Kenkyū-buntansha) 桑原 彰太  東邦大学, 理学部, 講師 (10612658)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords色素増感太陽電池 / 位相差顕微鏡 / 屈折率 / 光励起キャリヤ / 顕微分光法 / 太陽電池 / 光触媒 / 過渡格子 / 時間分解分光法 / 増感型太陽電池
Outline of Final Research Achievements

In this research, new types of solar cells have been studied to improve their performance. The solar cells have sensitized material for light absorption, which are call "sensitized solar cell (SSC)." It is necessary to utilize the photo-excited carriers to improve the performance, but there are several loss processes for the photo-excited carriers, which is called as "recombination processes." We focus on these processes for reducing these loss processes. We have developed time-resolved microscopic techniques to study the recombination processes in terms of the time and structure relevant to the processes. We clarified the reason why the cobalt redox species have not worked for the SSCs with ruthenium dyes, and the reason why the TEMPO redox did not show a good efficiency for SSCs. Furthermore, we have developed a new phase microscope in which the refractive index image can be obtained for the photoexcited carriers in photo-devices.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (24 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (17 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 17 results,  Open Access: 4 results,  Acknowledgement Compliant: 6 results) Presentation (4 results) (of which Int'l Joint Research: 3 results,  Invited: 3 results)

  • [Int'l Joint Research] Boston College(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research]

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Boston Collage(米国)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Photoexcited charge carrier dynamics of interconnected TiO2 nanoparticles: evidence of enhancement of charge separation at anatase?rutile particle interfaces2018

    • Author(s)
      Shingai Daiki、Ide Yusuke、Sohn Woon Yong、Katayama Kenji
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 20 Issue: 5 Pages: 3484-3489

    • DOI

      10.1039/c7cp07563d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge carrier kinetics in hematite with NiFeO x coating in aqueous solutions: Dependence on bias voltage2018

    • Author(s)
      Sohn Woon Yong、Thorne James E.、Zhang Yaohong、Kuwahara Shota、Shen Qing、Wang Dunwei、Katayama Kenji
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 353 Pages: 344-348

    • DOI

      10.1016/j.jphotochem.2017.11.029

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dependences of the Optical Absorption, Ground State Energy Level, and Interfacial Electron Transfer Dynamics on the Size of CdSe Quantum Dots Adsorbed on the (001), (110), and (111) Surfaces of Single Crystal Rutile TiO22017

    • Author(s)
      Toyoda Taro、Shen Qing、Kamiyama Keita、Katayama Kenji、Hayase Shuzi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 45 Pages: 25390-25401

    • DOI

      10.1021/acs.jpcc.7b09371

    • NAID

      120006537424

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Slow hot carrier cooling in cesium lead iodide perovskites2017

    • Author(s)
      Shen Qing、Ripolles Teresa S.、Even Jacky、Ogomi Yuhei、Nishinaka Koji、Izuishi Takuya、Nakazawa Naoki、Zhang Yaohong、Ding Chao、Liu Feng、Toyoda Taro、Yoshino Kenji、Minemoto Takashi、Katayama Kenji、Hayase Shuzi
    • Journal Title

      Applied Physics Letters

      Volume: 111 Issue: 15 Pages: 153903-153903

    • DOI

      10.1063/1.4991993

    • NAID

      120006529956

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Investigation of Photoexcited Carrier Dynamics in Hematite and the Effect of Surface Modifications by an Advanced Transient Grating Technique2017

    • Author(s)
      Woon Yong Sohn, Shota Kuwahara, James E. Thorne, Dunwei Wang, Kenji Katayama
    • Journal Title

      ACS Omega

      Volume: 2 Issue: 3 Pages: 1031-1035

    • DOI

      10.1021/acsomega.7b00021

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Anomalous enhancement by alkylamine of the dye-sensitized solar cells using TEMPO redox2017

    • Author(s)
      Nishimura Taisei、Sohn Woon Yong、Shen Qing、Kuwahara Shota、Katayama Kenji
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 346 Pages: 281-286

    • DOI

      10.1016/j.jphotochem.2017.06.015

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Specific interaction between dyes and ions in dye-sensitized solar cells2017

    • Author(s)
      Ryo Hosokawa, Shota Kuwahara, Kenji Katayama
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 334 Pages: 107-112

    • DOI

      10.1016/j.jphotochem.2016.11.004

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Direct measurement of the propagation of the phase-transition region of liquid crystals2017

    • Author(s)
      Takahiro Sato, and Kenji Katayama
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 44801-44801

    • DOI

      10.1038/srep44801

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ligand-dependent exciton dynamics and photovoltaic properties of PbS quantum dot heterojunction solar cells2017

    • Author(s)
      Jin Chang, Yuhei Ogomi, Chao Ding, Yao Hong Zhang, Taro Toyoda, Shuzi Hayase, Kenji Katayama and Qing Shen*
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 9 Pages: 6358-6367

    • DOI

      10.1039/c6cp06561a

    • NAID

      120006407335

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Air Stable PbSe Colloidal Quantum Dot Heterojunction Solar Cells: Ligand-Dependent Exciton Dissociation, Recombination, Photovoltaic Property, and Stability2016

    • Author(s)
      Yaohong Zhang, Chao Ding, Guohua Wu, Naoki Nakazawa, Jin Chang, Yuhei Ogomi, Taro Toyoda, Shuzi Hayase, Kenji Katayama, and Qing Shen*
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 50 Pages: 28509-28518

    • DOI

      10.1021/acs.jpcc.6b10920

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Distinction of electron pathways at titanium oxide/liquid interfaces in photocatalytic processes and co-catalyst effects2016

    • Author(s)
      Shota Kuwahara, Kenji Katayama
    • Journal Title

      Physical Chemistry, Chemical Physics

      Volume: 18 Issue: 36 Pages: 25271-25276

    • DOI

      10.1039/c6cp04016k

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] The Electronic Structure and Photoinduced Electron Transfer Rate of CdSe Quantum Dots on Single Crystal Rutile TiO2: Dependence on the Crystal Orientation of the Substrate2016

    • Author(s)
      T. Toyoda, W. Yindeesuk, K. Kamiyama, K. Katayama, H. Kobayashi, S. Hayase, Q. Shen
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 120 Issue: 6 Pages: 2047-2057

    • DOI

      10.1016/j.jechem.2015.11.002

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Characterization of hot carrier cooling and multiple exciton generation dynamics in PbS QDs using an improved transient grating technique2015

    • Author(s)
      Q. Shen, K. Katayama, T. Toyoda
    • Journal Title

      Journal of Energy Chemistry

      Volume: 24 Issue: 4 Pages: 712-716

    • DOI

      10.1021/acs.jpcc.5b09528

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] J. Chang, T. Oshima, S. Hachiya, K. Sato, T. Toyoda, K. Katayama, S. Hayase, Q. Shen2015

    • Author(s)
      Uncovering the charge transfer and recombination mechanism in ZnS-coated PbS quantum dot sensitized solar cells
    • Journal Title

      Solar Energy

      Volume: 122 Pages: 307-313

    • DOI

      10.1016/j.solener.2015.08.035

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Blocking Effect for Carrier Transfer to Triiodide in case of Alkyl Functionalized Dyes in Dye Sensitized Solar Cell2015

    • Author(s)
      K. Omata, S. Kuwahara, R. Hosokawa, T. Nishimura, S. Qing, T. Toyoda, K. Katayama
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 88 Issue: 9 Pages: 1308-1311

    • DOI

      10.1246/bcsj.20150090

    • NAID

      130005099093

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Optical absorption, charge separation and recombination dynamics in Sn/Pb cocktail perovskite solar cells and their relationships to photovoltaic performances2015

    • Author(s)
      Q. Shen, Y. Ogomi, J. Chang, T. Toyoda, K. Fujiwara, K. Yoshino, Y. Kuga, K. Katayama, S. Hayase
    • Journal Title

      J. Mater. Chem. A.

      Volume: 3 Issue: 17 Pages: 9308-9316

    • DOI

      10.1039/c5ta01246e

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] The cause for the low efficiency of dye sensitized solar cells with the combination of Ruthenium dyes and Cobalt redox2015

    • Author(s)
      K. Omata, S. Kuwahara, K. Katayama, Q. Shen, T. Toyoda, K. M. Lee, C. G. Wu
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 15 Pages: 10170-10175

    • DOI

      10.1039/c4cp05981f

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 格子パターン励起位相差顕微鏡による液晶の相転移領域伝搬の直接計測2017

    • Author(s)
      片山建二
    • Organizer
      第7回ソフトマター研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Distinction between reactive and non-reactive trap states in photocatalytic reactions revealed by transient grating technique2017

    • Author(s)
      K. Katayama and S. Kuwahara
    • Organizer
      Photocatalysis 2 & SIEMME'23
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Time-resolved imaging of the propagation of molecular orientation change during the phase transition of liquid crystals2017

    • Author(s)
      Kenji Katayama
    • Organizer
      21st International Symposium on Advanced Display Materials & Devices (ADMD 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Time-resolved imaging of the propagation of molecular orientation change during the phase transition of liquid crystals2017

    • Author(s)
      Kenji Katayama
    • Organizer
      Optics of Liquid Crystals 2017 (OLC2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2015-04-16   Modified: 2022-06-06  

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