Utilizing carbonated water for catalytic reaction systems and the elucidation of role of proton
| Project/Area Number |
15K05579
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Green/Environmental chemistry
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| Research Institution | Iwate University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
七尾 英孝 岩手大学, 理工学部, 准教授 (50312509)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Keywords | 炭酸水 / 高温水 / 高圧二酸化炭素 / プロトン / 酸触媒 / 多相系水素化反応 / グリーンケミストリー / 多相系水素化触媒反応 |
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| Outline of Final Research Achievements |
The effect of carbonated water to homogeneous reaction systems and heterogeneous hydrogenations using supported metal catalysts were studied. We found that (1) the dehydration of erythritol to 1, 4-unhydroerythritol proceeded in high-temperature carbonated water, (2) benzyl methyl ether was produced in aqueous methanol solution under high-pressured carbon dioxide, and (3) hydrogenation of furfuryl alcohol and furfural proceeded over Pd/C in water solvent and the initial reaction rates were enhanced by the addition of carbon dioxide and the rates were increased with an increase in carbon dioxide pressure.
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Report
(4 results)
Research Products
(13 results)
