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Utilizing carbonated water for catalytic reaction systems and the elucidation of role of proton

Research Project

Project/Area Number 15K05579
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Green/Environmental chemistry
Research InstitutionIwate University

Principal Investigator

SHIRAI Masayuki  岩手大学, 理工学部, 教授 (70250850)

Co-Investigator(Kenkyū-buntansha) 七尾 英孝  岩手大学, 理工学部, 准教授 (50312509)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords炭酸水 / 高温水 / 高圧二酸化炭素 / プロトン / 酸触媒 / 多相系水素化反応 / グリーンケミストリー / 多相系水素化触媒反応
Outline of Final Research Achievements

The effect of carbonated water to homogeneous reaction systems and heterogeneous hydrogenations using supported metal catalysts were studied. We found that (1) the dehydration of erythritol to 1, 4-unhydroerythritol proceeded in high-temperature carbonated water, (2) benzyl methyl ether was produced in aqueous methanol solution under high-pressured carbon dioxide, and (3) hydrogenation of furfuryl alcohol and furfural proceeded over Pd/C in water solvent and the initial reaction rates were enhanced by the addition of carbon dioxide and the rates were increased with an increase in carbon dioxide pressure.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (13 results)

All 2018 2017 2016 2015 Other

All Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] Benzyl methyl ether production from benzyl alcohol and methanl in carbonic water2018

    • Author(s)
      H.Nanao, H.Sasaki, O.Sato, A.Yamaguchi, and M.Shirai
    • Journal Title

      Catalysis Today

      Volume: 309 Pages: 31-34

    • DOI

      10.1016/j.cattod.2017.11.021

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Environmentally Benign Chemicals Production from Unusual Resources using water solvent2018

    • Author(s)
      M.Shirai, O.Sato, A. Yamaguchin and C.V.Rode
    • Journal Title

      Current Envrionmental Engineering

      Volume: 5 Issue: 1 Pages: 13-19

    • DOI

      10.2174/2212717805666180112163151

    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Journal Article] Furfuryl Alcohol and Furfural Hydrogenationi over Activated Carbon-supported Palladium Catalyst in Presence of Water and Carbon Dioxide2017

    • Author(s)
      Hidetaka Nanao, Yuka Murakami, Osamu Sato, Aritomo Yamaguchi, Norihito Hiyoshi, and Masayuki Shirai
    • Journal Title

      Chemistry Select

      Volume: 2 Issue: 8 Pages: 2471-2475

    • DOI

      10.1002/slct.201700382

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 竹からのソルビトール合成: 竹の粉砕及び熱水前処理効果2017

    • Author(s)
      金内良介, 松本智紘, 計良菖将, 七尾英孝, 長谷川泰久, 佐藤剛一, 佐藤修, 清住嘉道, 山口有朋, 白井誠之
    • Organizer
      第47回石油・石油化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Dehydration of erythritol in high-temperature liquid water2017

    • Author(s)
      高橋尚吾, 本郷秀一郎, 七尾英孝, 佐藤修, 山口有朋, 白井誠之
    • Organizer
      平成29年度 化学系学協会東北大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Dehydration of xylose over CHA zeolite: Effect of surface structure of CHA zeolite2017

    • Author(s)
      松本智紘, 金内良介, 七尾英孝, 佐藤修, 佐藤剛一, 長谷川泰久, 清住嘉道, 山口有朋, 白井誠之
    • Organizer
      平成29年度 化学系学協会東北大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Hydrogenation of 4-propylphenol over Pd/C in aqueous ethanol solution: role of water2017

    • Author(s)
      皆川直祐, 本郷秀一郎, 七尾英孝, 佐藤修, 山口有朋, 白井誠之
    • Organizer
      平成29年度 化学系学協会東北大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] "Hydrogenation of bamboo powder over Pt/C in water: Effect of hydrothermal and ball-milling pretreatment2017

    • Author(s)
      本郷秀一郎, 七尾英孝, 佐藤修, 山口有朋, 白井誠之
    • Organizer
      平成29年度 化学系学協会東北大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高圧二酸化炭素を用いた水―エタノール混合溶媒中でのベンジルフェニルエーテルの分解反応2016

    • Author(s)
      佐々木寛規,佐藤修,山口有朋,七尾英孝,白井誠之
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学(岩手県盛岡市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report
  • [Presentation] Valuable Chemicals Synthesis from Biomass-derived Compounds using High-temperature Liquid Water and High-pressured Carbon Dioxide2016

    • Author(s)
      M.Shirai
    • Organizer
      The International Symposium on Catalytic Conversions of Biomass (ISCCB-2016)
    • Place of Presentation
      Taipei(台湾)
    • Year and Date
      2016-06-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Green Chemicals Production with Water and Carbon Dioxide Media2016

    • Author(s)
      M.Shirai
    • Organizer
      National Workshop on Development of Nanomaterials for Energy, Environmental and Sustainability
    • Place of Presentation
      Bhubaneshswar(インド)
    • Year and Date
      2016-05-09
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Environmentally benign hydrogenation of biomass-derived compounds with supported metal catalysts and water solvent2015

    • Author(s)
      Masayuki Shirai, Yoshiyuki Nagasawa, Kurumi Yoshida, Hidetaka Nanao, Takehiko Sasaki, Osamu Sato, and Aritomo Yamaguchi
    • Organizer
      2015環太平洋国際化学会議(Pacifichem2015)
    • Place of Presentation
      ホノルル,米国
    • Year and Date
      2015-12-19
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 岩手大学理工学部化学・生命理工学科化学コース表面反応化学研究室

    • URL

      http://www.chem.iwate-u.ac.jp/labo_web/inorg_reaction/top.html

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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