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Development of environmental load lowering materials for CO2 capture and storage

Research Project

Project/Area Number 15K05583
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Green/Environmental chemistry
Research InstitutionChiba University

Principal Investigator

Kanoh Hirofumi  千葉大学, 大学院理学研究院, 教授 (60334166)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords環境負荷低減物質 / アルカリ金属炭酸塩 / 二酸化炭素貯蔵 / 再生エネルギーコスト低減 / ナノ構造形成 / ナノコンポジット / 異種原子置換 / 結晶構造不安定化 / カーボンアエロゲル
Outline of Final Research Achievements

It is an urgent issue to capture and store CO2 which is one of principal greenhouse gases. There have several problems in the CCS technologies used for a pilot plant, such as the low CO2 selectivity or high energy cost for the regeneration of materials for CCS. I studied CO2 sorptivity of alkali-metal carbonates under a moist condition to solve the problems because alkali-metal carbonates (Na2CO3 and K2CO3) can selectively capture CO2 with water vapor. However, there were problems of the slow reaction rate and high regeneration energy cost for Na2CO3 and K2CO3. To improve the problems, I prepared nanostructured alkali-metal carbonates by synthesizing a composite consisting of nanocarbons and the alkali-metal carbonates and by introducing different metal ions into crystals of the alkali-metal carbonates. The improvements were observed by forming such nanostructures in the crystals of the alkali-metal carbonates.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (35 results)

All 2017 2016 2015

All Journal Article (12 results) (of which Peer Reviewed: 12 results,  Open Access: 2 results,  Acknowledgement Compliant: 8 results) Presentation (19 results) (of which Int'l Joint Research: 7 results,  Invited: 1 results) Book (2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Fundamentals in CO2 capture of Na2CO3 under a moist condition2017

    • Author(s)
      Luo Hongchao、Kanoh Hirofumi
    • Journal Title

      J. Energy Chem.

      Volume: 26 Issue: 5 Pages: 972-983

    • DOI

      10.1016/j.jechem.2017.08.005

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanostructured silicon ferromagnet collected by a permanent neodymium magnet2017

    • Author(s)
      Okuno Takahisa、Thuermer Stephan、Kanoh Hirofumi
    • Journal Title

      Chem. Comm.

      Volume: 53 Issue: 96 Pages: 12882-12885

    • DOI

      10.1039/c7cc07372k

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cooperative CO2 adsorption promotes high CO2 adsorption density over wide optimal nanopore range2017

    • Author(s)
      Chen Lei、Watanabe Takumi、Kanoh Hirofumi、Hata Kenji、Ohba Tomonori
    • Journal Title

      Ads. Sci. Technol.

      Volume: 36 Issue: 1-2 Pages: 625-639

    • DOI

      10.1177/0263617417713573

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Significant CO2 Adsorption Ability of Nanoscale BaTiO3 Ceramics Fabricated by Carbon-Template-Solvothermal Reactions2017

    • Author(s)
      T. Watanabe, S. M. Khan, H. Kanoh, T. Ohba
    • Journal Title

      Phys. Chem. Ind. J.

      Volume: S1 Pages: 101-101

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of highly ultramicroporous carbon nanofoams by SF6 -catalyzed laser-induced chemical vapor deposition2016

    • Author(s)
      Y. Hattori, A. Shuhara, A. Kondo, S. Utsumi, H. Tanaka, T. Ohba, Hirofumi Kanoh, K. Takahashi, F. Vallejos-Burgos, K. Kaneko
    • Journal Title

      Chem. Phys. Lett.

      Volume: 652 Pages: 199-202

    • DOI

      10.1016/j.cplett.2016.04.050

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Double-Step Gate Phenomenon in CO2 Sorption of an Elastic Layer-Structured MOF2016

    • Author(s)
      M. Ichikawa, A. Kondo, H. Noguchi, N. Kojima, T. Ohba, H. Kajiro, Y. Hattori, H. Kanoh
    • Journal Title

      Langmuir

      Volume: 32 Issue: 38 Pages: 9722-9726

    • DOI

      10.1021/acs.langmuir.6b02551

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Systematic sorption studies of camptothecin on oxidized single-walled carbon nanotubes2016

    • Author(s)
      B. Permana, T. Ohba, T. Itoh, H. Kanoh
    • Journal Title

      Colloid. Surf. A: Physicochem. Eng. Aspects

      Volume: 490 Pages: 121-132

    • DOI

      10.1016/j.colsurfa.2015.11.020

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] CO2 capture by carbon aerogel-potassium carbonate nanocomposites2016

    • Author(s)
      G. Yang, H. Luo, T. Ohba, H. Kanoh
    • Journal Title

      Int. J. Chem. Eng.

      Volume: 2016 Pages: 4012976-8

    • DOI

      10.1155/2016/4012967

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Temperature-dependent Double-step CO2 Occlusion of K2CO3 under Moist Conditions2015

    • Author(s)
      H. Chioyama, H. Luo, T. Ohba, H. Kanoh
    • Journal Title

      Ads. Sci. Technol.

      Volume: 33 Issue: 3 Pages: 243-250

    • DOI

      10.1260/0263-6174.33.3.243

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Kinetics and Structural Changes in CO2 Capture of K2CO3 under a Moist Condition2015

    • Author(s)
      H. Luo, H. Chioyama, S. Thuermer, T. Ohba, H. Kanoh
    • Journal Title

      Energ. Fuel.

      Volume: 29 Issue: 7 Pages: 4472-4478

    • DOI

      10.1021/acs.energyfuels.5b00578

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Wide Carbon Nanopores as Efficient Sites for the Separation of SF6 from N22015

    • Author(s)
      A. Takase, H. Kanoh, T. Ohba
    • Journal Title

      Sci. Rep.

      Volume: 5 Issue: 1 Pages: 11994-11994

    • DOI

      10.1038/srep11994

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Recyclable Poly-Zn3(OAc)4-3,3’-Bis(aminoimino)binaphthoxide Catalyst for Asymmetric Iodolactonization2015

    • Author(s)
      T. Arai, T. Kojima, O. Watanabe, T. Itoh, H. Kanoh
    • Journal Title

      ChemCatChem

      Volume: 7 Issue: 20 Pages: 3234-3238

    • DOI

      10.1002/cctc.201500842

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 構造柔軟性MOF(ELM-11)のガス吸収特性に及ぼす合成反応場の効果2017

    • Author(s)
      5) 都甲 真利、上代 洋、加納 博文
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      横浜市慶応大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] Change in Relaxation Times of 1H-NMR accompanied by a Double-Step Gate Opening of an Elastic Layer-structured MOF (ELM-11)2017

    • Author(s)
      1) K. Ohazama, M. Ichikawa, A. Kondo, H. Kajiro, H. Masu, T. Ueda, and H. Kanoh
    • Organizer
      11h International Symposium on the Characterization of Porous Solids (COPS11)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] シリコンナノ構造磁性体の調製法の確立2017

    • Author(s)
      高松智昭、加納博文
    • Organizer
      第68回コロイドおよび界面化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 湿潤条件における炭酸ナトリウムによる二酸化炭素吸蔵反応の基礎的検討2017

    • Author(s)
      駱 紅超、加納博文
    • Organizer
      第31回日本吸着学会研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化黒鉛の二酸化炭素吸着特性2017

    • Author(s)
      福田尭夫、加納博文
    • Organizer
      第31回日本吸着学会研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ナノグラフィティックカーボンの磁性2017

    • Author(s)
      黒澤征純、加納 博文
    • Organizer
      第44回炭素材料学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] アミロイド化したコンカナバリンAに及ぼすカーボンナノ空間の効果2016

    • Author(s)
      羽根 大輔、加納 博文
    • Organizer
      第43回炭素材料学会年会
    • Place of Presentation
      千葉市千葉大学西千葉キャンパス
    • Year and Date
      2016-12-07
    • Related Report
      2016 Research-status Report
  • [Presentation] 酸化処理された単層カーボンナノチューブへのメトトレキサートの液相吸着2016

    • Author(s)
      Benny Permana、大場友則、伊藤努武、加納博文
    • Organizer
      第30回日本吸着学会研究発表会
    • Place of Presentation
      長崎市長崎大学文教キャンパス
    • Year and Date
      2016-11-10
    • Related Report
      2016 Research-status Report
  • [Presentation] XPS Analysis of Electronic Structures of an Ionic Liquid Confined in Carbon Nanospace2016

    • Author(s)
      H. Kanoh, S. Thuermer, A. Izawa, Y. Kobayashi, T. Ohba
    • Organizer
      The 67 Divisional Meeting on Colloid and Interface Chemistry, Chemical Society of Japan
    • Place of Presentation
      旭川市、北海道教育大学旭川校
    • Year and Date
      2016-09-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Systematic sorption studies of camptothecin on oxidized single-walled carbon nanotubes2016

    • Author(s)
      H. Kanoh
    • Organizer
      12th International Conference on the Fundamentals of Adsorption (FOA12)
    • Place of Presentation
      フリーデリヒスハーフェン、ドイツ
    • Year and Date
      2016-05-29
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] アミロイド化したコンカナバリンAに及ぼすカーボンナノ空間の効果2016

    • Author(s)
      羽根大輔、加納博文
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス (京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] ELM-11が示すゲート現象のNMR法による解析2015

    • Author(s)
      大峽 和紀、大場 友則、加納 博文
    • Organizer
      第27回日本吸着学会研究発表会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島県徳島市)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
  • [Presentation] ELM-12のガス吸着におけるゲート現象の多様性2015

    • Author(s)
      都甲真利、加納博文
    • Organizer
      第27回日本吸着学会研究発表会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島県徳島市)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
  • [Presentation] Kinetics and Structural Changes in CO2 Capture of K2CO3 under a Moist Condition2015

    • Author(s)
      H. Luo, H. Chioyama, S. Thuermer, T. Ohba, H. Kanoh
    • Organizer
      Western Pacific Colloids 2015 (WPC2015)
    • Place of Presentation
      Siem Reap, Cambodia
    • Year and Date
      2015-11-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] CO2 capture by K2CO3 nanocomposites2015

    • Author(s)
      G. Yang, T. Ohba, H. Kanoh
    • Organizer
      th Pacific Basin Conference on Adsorption Science and Technology (PBAST 7)
    • Place of Presentation
      厦門、中国
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] シリコンナノ粒子の磁気的性質2015

    • Author(s)
      奥野貴久、Stephan Thuermer、大場 友則、加納 博文
    • Organizer
      第66回コロイド及び界面化学討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス(鹿児島県鹿児島市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 湿潤下における炭酸カリウムによるCO2吸蔵の速度論2015

    • Author(s)
      駱紅超・千應山英之・Stephan Thuermer・大場友則・加納博文
    • Organizer
      第66回コロイド及び界面化学討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス(鹿児島県鹿児島市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] Double-Step Swelling of an Elastic Layer-structured MOF (ELM-11) in a CO2 atmosphere2015

    • Author(s)
      H. Kanoh
    • Organizer
      2015 International Conference on Colloids and Interface Science
    • Place of Presentation
      台北、 台湾
    • Year and Date
      2015-07-22
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Systematic study of the interaction between oxidized single walled carbon nanotubes and water-insoluble anticancer drug2015

    • Author(s)
      B. Permana, T. Ohba, H. Kanoh
    • Organizer
      CARBON 2015
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2015-07-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Book] CO2削減,省エネに関する新技術,採用事例,規制対応2017

    • Author(s)
      加納博文 他
    • Total Pages
      562
    • Publisher
      技術情報協会
    • ISBN
      9784861046711
    • Related Report
      2017 Annual Research Report
  • [Book] 吸着・分離材料の設計、性能評価と新しい応用2015

    • Author(s)
      加納博文
    • Publisher
      技術情報教会
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 磁性半導体材料の製造方法及び半導体材料磁性化液2017

    • Inventor(s)
      加納博文、高松智昭
    • Industrial Property Rights Holder
      国立大学法人 千葉大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-168246
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 多孔性高分子錯体、ガス吸着材、これを用いたガス分離装置およびガス貯蔵装置2017

    • Inventor(s)
      上代洋、永井徹、加納博文、都甲真利
    • Industrial Property Rights Holder
      新日鐵住金株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-050453
    • Filing Date
      2017-03-15
    • Related Report
      2016 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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