• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Elucidation and application of environmental response function expression mechanism using chiral growth type aggregation reaction

Research Project

Project/Area Number 15K05587
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Green/Environmental chemistry
Research InstitutionKochi University

Principal Investigator

YONEMURA TOSHIAKI  高知大学, 教育研究部総合科学系複合領域科学部門, 教授 (90240382)

Co-Investigator(Kenkyū-buntansha) 小澤 智宏  名古屋工業大学, 工学(系)研究科(研究院), 教授 (70270999)
上田 忠治  高知大学, 教育研究部総合科学系複合領域科学部門, 教授 (50294822)
Project Period (FY) 2015-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Keywordsキラル化合物 / 環境応答 / 複合材料 / 物性・合成化学 / イオン結晶 / 環境対応 / 複合材料・物性 / ハイブリッド化合物 / 光学活性 / 合成化学
Outline of Final Research Achievements

We found that the structure of the resulting hybrid polynuclear complex can be changed by varying the bulkiness and the substituent of the used ligand.
This stereoselective synthesis could provide insights into additional factors in chiral growth-type assembly reactions.
The contents of this research will continue to be examined after the grant period, aiming to develop a chiral environment-responsive polynuclear metal complex, and we intend to expand the function expression using this system.

Academic Significance and Societal Importance of the Research Achievements

化合物の高効率的,高選択的合成反応を見出して活用することは,化学反応の本質を理解するためだけでなく,省資源・省エネルギーの観点から非常に重要であると考える。我々の研究では,環境調和型の高選択的反応の開拓に有効なキラルな環境応答性材料の開発を目指している。研究の焦点は,集積化の際におけるキラル増殖反応を,特定の部位に,いかに効率よく誘起するかについて,分子レベルで設計し,合成することに重点をおき,そのシステムを用いた機能発現を目指す。

Report

(5 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (16 results)

All 2019 2018 2017 2016 2015 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (12 results) (of which Int'l Joint Research: 2 results) Remarks (1 results)

  • [Journal Article] Stereoselective formation and spectroscopic studies of [Cr(edda or eddp)(N-N)]-type complexes (edda = ethylenediamine-N,N′-diacetate; eddp = ethylenediamine-N,N′-dipropionate)2019

    • Author(s)
      Yano Yumie、Nakayama Ryoko、Yonemura Toshiaki
    • Journal Title

      Polyhedron

      Volume: 161 Pages: 111-119

    • DOI

      10.1016/j.poly.2018.12.040

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structures, spectroscopic studies and photodenitrosylation reactions of stereoselectively formed dinitrosyl-molybdenum [Mo(bidentate-N,S)2(NO)2] complexes with 2-pyrimidinethiolate derivatives2019

    • Author(s)
      Ono Kei、Kitaoka Koji、Ikeno Suguru、Yonemura Toshiaki
    • Journal Title

      Polyhedron

      Volume: 165 Pages: 116-124

    • DOI

      10.1016/j.poly.2019.02.057

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure of Co(III) Complex with 2-Aminoethanethiol and Triethylenetetramine2019

    • Author(s)
      Kurogi Chika、Yonemura Toshiaki
    • Journal Title

      Analytical Sciences: X-ray Structure Analysis On-Line

      Volume: 印刷中

    • NAID

      130007677282

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Influence of aromatic thiolato Ligand in the formation of silver and cobalt mixed complex (8)2019

    • Author(s)
      井上廉,小澤智宏,米村俊昭
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Syntheses and Characterization of Optically Active Thiocarboxylato Cobalt(III) Complexes2018

    • Author(s)
      Matsubara, M., Yano, Y., Nakashima, M., Ozawa, T., Yonemura, T.
    • Organizer
      The 43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 銀-コバルト混合錯体の形成に及ぼす芳香族チオラト配位子の影響(7)2018

    • Author(s)
      露口優希,小澤智宏,米村俊昭
    • Organizer
      日本化学会中四国支部大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ピリミジンチオレート誘導体を含む銀(I)錯体の合成と固体発光性2018

    • Author(s)
      油布誠也,米村俊昭
    • Organizer
      日本化学会中四国支部大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光学活性なチオプロニンコバルト(III)錯体の合成と銀イオンとの多核化反応2017

    • Author(s)
      松原萌,米村俊昭
    • Organizer
      日本化学会中四国支部大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 銀(I)チオラート錯体の合成と固体発光性の発現2017

    • Author(s)
      石井亜澄,福本翔平,米村俊昭
    • Organizer
      第67回錯体化学会討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Syntheses and Polymerization Reactions of Optically Active Cobalt(III) Complexes2017

    • Author(s)
      M. Nakashima, M. Matsubara, T. Ozawa, T. Yonemura
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学(横浜)
    • Related Report
      2016 Research-status Report
  • [Presentation] 銀-コバルト混合錯体の形成に及ぼす芳香族チオラト配位子の影響(6)2016

    • Author(s)
      米村俊昭,伊藤勇輝,小澤智宏
    • Organizer
      第66回錯体化学会討論会
    • Place of Presentation
      福岡大学(福岡)
    • Related Report
      2016 Research-status Report
  • [Presentation] チオウラシル銀錯体の合成と固体発光特性2015

    • Author(s)
      石井亜澄,藤田紀子,米村俊昭
    • Organizer
      2015年日本化学会中国四国支部大会
    • Place of Presentation
      岡山大学(岡山県)
    • Year and Date
      2015-11-15
    • Related Report
      2015 Research-status Report
  • [Presentation] 硫黄架橋パラジウム-銀およびコバルト錯体の合成と性質2015

    • Author(s)
      清水大嗣,岡崎麻紗,小澤智宏,米村俊昭
    • Organizer
      2015年日本化学会中国四国支部大会
    • Place of Presentation
      岡山大学(岡山県)
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
  • [Presentation] ヘテロ環チオラト配位子を有する銀(I)錯体の合成と固体発光性2015

    • Author(s)
      福本翔平・藤田紀子・米村俊昭
    • Organizer
      第65回錯体化学会討論会
    • Place of Presentation
      奈良女子大学(奈良県)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Syntheses and polymerization reactions of optically active cobalt(III) complexes with thiocarboxylic acid2015

    • Author(s)
      Nakashima M., Ozawa T., Yonemura T.,
    • Organizer
      The 15th International Conference on Chiroptical Spectroscopy
    • Place of Presentation
      Sapporo
    • Year and Date
      2015-08-31
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 高知大学化学生命理工学科  無機化学 米村研究室

    • URL

      http://science.cc.kochi-u.ac.jp/info/dtl.php?hdnKey=736

    • Related Report
      2018 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2020-03-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi