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Enhancement of Photo-absorption of Perovskite Solar Cells by Dye-sensitization

Research Project

Project/Area Number 15K05596
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy-related chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

NAKAZAKI Jotaro  東京大学, 大学院総合文化研究科, 特任准教授 (10444100)

Project Period (FY) 2015-10-21 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords太陽電池 / ペロブスカイト / 有機無機ハイブリッド / ポルフィリン
Outline of Final Research Achievements

Enhancement of photo-absorption of perovskite solar cells around 600-800 nm, where lower external quantum efficiency had been reported, was intended by the introduction of organic dyes. However, the improvement in the preparation method of the perovskite layer enhanced the photo-absorption of perovskite itself, making no room for the enhancement by organic dyes in terms of their performance. Adsorption of organic molecules over the under-layer of the perovskite layer improved solar cell performances in some cases. The improvement in solar cell performances may be derived from the improvement in interfacial contacts, indicating that those organic molecules on TiO2 layer can work as surface functionalizing molecules. The results will contribute for the enhancement of device performances of perovskite solar cells.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (20 results)

All 2018 2017 2016 2015

All Journal Article (19 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 11 results,  Open Access: 4 results) Presentation (1 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Evolution of organometal halide solar cells2018

    • Author(s)
      Jotaro Nakazaki, Hiroshi Segawa
    • Journal Title

      Journal of Photochemistry and Photobiology C: Photochemistry Reviews

      Volume: 35 Pages: 74-107

    • DOI

      10.1016/j.jphotochemrev.2018.02.002

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modulations of various alkali metal cations on organometal halide perovskites and their influence on photovoltaic performance2018

    • Author(s)
      Tang Zeguo、Uchida Satoshi、Bessho Takeru、Kinoshita Takumi、Wang Haibin、Awai Fumiyasu、Jono Ryota、Maitani Masato M.、Nakazaki Jotaro、Kubo Takaya、Segawa Hiroshi
    • Journal Title

      Nano Energy

      Volume: 45 Pages: 184-192

    • DOI

      10.1016/j.nanoen.2017.12.047

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 有機金属ハライドペロブスカイト太陽電池の高性能化に向けた最新技術2018

    • Author(s)
      瀬川浩司, 中崎城太郎
    • Journal Title

      光アライアンス

      Volume: 29(3) Pages: 6-10

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Recent progress of organometal halide perovskite solar cells2017

    • Author(s)
      Jotaro Nakazaki, Hiroshi Segawa
    • Journal Title

      AAPPS Bulletin

      Volume: 27 Pages: 9-21

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of unique power conversion efficiency of solar cell showing hysteresis in the I-V curve under various light intensities2017

    • Author(s)
      Ludmila Cojocaru, Satoshi Uchida, Koichi Tamaki, Piyankarage V. V. Jayaweera, Shoji Kaneko, Jotaro Nakazaki, Takaya Kubo, Hiroshi Segawa
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 11790-11790

    • DOI

      10.1038/s41598-017-10953-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Effect of TiO2 surface treatment on the current-voltage hysteresis of planar-structure perovskite solar cells prepared on rough and flat fluorine-doped tin oxide substrates2017

    • Author(s)
      Ludmila Cojocaru, Satoshi Uchida, Piyankarage V. V. Jayaweera, Shoji Kaneko, Haibin Wang, Jotaro Nakazaki, Takaya Kubo, Hiroshi Segawa
    • Journal Title

      Energy Technology

      Volume: 5 Issue: 10 Pages: 1762-1766

    • DOI

      10.1002/ente.201700308

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Solution-processed short-wave infrared PbS colloidal quantum dot/ZnO nanowire solar cells giving high open-circuit voltage2017

    • Author(s)
      Haibin Wang, Takaya Kubo, Jotaro Nakazaki, Hiroshi Segawa
    • Journal Title

      ACS Energy Letters

      Volume: 2 Issue: 9 Pages: 2110-2117

    • DOI

      10.1021/acsenergylett.7b00505

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 有機金属ハライド太陽電池の現状と展望2017

    • Author(s)
      中崎城太郎、瀬川浩司
    • Journal Title

      太陽エネルギー

      Volume: 43(2) Pages: 3-14

    • NAID

      130006590683

    • Related Report
      2016 Research-status Report
  • [Journal Article] 有機金属ハライド太陽電池の現状と展望2017

    • Author(s)
      中崎城太郎、瀬川浩司
    • Journal Title

      日本エネルギー学会機関誌 えねるみくす

      Volume: 96(2) Pages: 148-155

    • NAID

      130006590683

    • Related Report
      2016 Research-status Report
  • [Journal Article] 世界を席巻する有機金属ハライド太陽電池2017

    • Author(s)
      中崎城太郎、瀬川浩司
    • Journal Title

      WEB Journal

      Volume: 2017 Pages: 32-35

    • Related Report
      2016 Research-status Report
  • [Journal Article] Simulation of current-voltage curves for inverted planar structure perovskite solar cells using equivalent circuit model with inductance2017

    • Author(s)
      Ludmila Cojocaru, Satoshi Uchida, Piyankarage V. V. Jayaweera, Shoji Kaneko, Yasutake Toyoshima, Jotaro Nakazaki, Takaya Kubo, and Hiroshi Segawa
    • Journal Title

      Applied Physics Express

      Volume: 10 Issue: 2 Pages: 025701-025701

    • DOI

      10.7567/apex.10.025701

    • NAID

      210000135771

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] 有機金属ハライドペロブスカイト太陽電池の実用化最新動向2016

    • Author(s)
      中崎城太郎、瀬川浩司
    • Journal Title

      光触媒

      Volume: 49 Pages: 92-99

    • Related Report
      2016 Research-status Report
  • [Journal Article] 有機金属ハライドペロブスカイト太陽電池の現状と展望2016

    • Author(s)
      内田 聡、コジョカル ルドミラ、中崎城太郎、瀬川浩司
    • Journal Title

      応用物理

      Volume: 85 Pages: 676-683

    • NAID

      130007715371

    • Related Report
      2016 Research-status Report
  • [Journal Article] 有機金属ハライドペロブスカイト太陽電池の実用化に向けて2016

    • Author(s)
      中崎城太郎、内田 聡、瀬川浩司
    • Journal Title

      Electrochemistry

      Volume: 84 Pages: 445-448

    • Related Report
      2016 Research-status Report
  • [Journal Article] Direct confirmation of distribution for Cl- in CH3NH3PbI3-xClx layer of perovskite solar cells2016

    • Author(s)
      Ludmila Cojocaru, Satoshi Uchida, Daiki Matsubara, Hiroaki Matsumoto, Katsuji Ito, Yoshihiro Otsu, Patrick Chapon, Jotaro Nakazaki, Takaya Kubo, and Hiroshi Segawa
    • Journal Title

      Chemistry Letters

      Volume: 45 Issue: 8 Pages: 884-886

    • DOI

      10.1246/cl.160436

    • NAID

      130005254573

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Temperature effects on the photovoltaic performance of planar structure perovskite solar cells2015

    • Author(s)
      Ludmila Cojocaru, Satoshi Uchida, Yoshitaka Sanehira, Victoria Gonzalez-Pedro, Juan Bisquert, Jotaro Nakazaki, Takaya Kubo, Hiroshi Segawa
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 11 Pages: 1557-1559

    • DOI

      10.1246/cl.150781

    • NAID

      130005108106

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Origin of the hysteresis in I-V curves for planar structure perovskite solar cells rationalized with a surface boundary induced capacitance model2015

    • Author(s)
      Ludmila Cojocaru, Satoshi Uchida, Piyankarage V. V. Jayaweera, Shoji Kaneko, Jotaro Nakazaki, Takaya Kubo, Hiroshi Segawa
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 12 Pages: 1750-1752

    • DOI

      10.1246/cl.150933

    • NAID

      130005112530

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhanced carrier transport distance in colloidal PbS quantum dot-based solar cells using ZnO nanowires2015

    • Author(s)
      Haibin Wang, Victoria Gonzalez-Pedro, Takaya Kubo, Francisco Fabregat-Santiago, Juan Bisquert, Yoshitaka Sanahira, Jotaro Nakazaki, Hiroshi Segawa
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 119 Issue: 49 Pages: 27265-27274

    • DOI

      10.1021/acs.jpcc.5b09152

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] ペロブスカイト太陽電池の現状と展望2015

    • Author(s)
      中崎城太郎、木下卓巳、内田 聡、瀬川浩司
    • Journal Title

      オプトニューズ

      Volume: 10(4) Pages: 24-29

    • Related Report
      2015 Research-status Report
  • [Presentation] Recent development of perovskite solar cells2016

    • Author(s)
      Jotaro Nakazaki
    • Organizer
      5th Next PV International Workshop
    • Place of Presentation
      フランス・CNRS Meudon Bellevueキャンパス
    • Year and Date
      2016-12-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited

URL: 

Published: 2015-10-21   Modified: 2019-03-29  

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