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Investigation to determine the factor of long-term stability and development of Pb-free materials for application

Research Project

Project/Area Number 15K05597
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy-related chemistry
Research InstitutionKyushu Institute of Technology

Principal Investigator

MA TINGLI  九州工業大学, 大学院生命体工学研究科, 教授 (20380545)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsプロブスカイト / 耐久性 / 鉛フリー / 高効率 / カーボン電極 / 太陽電池 / ペロブスカイト / 無機ダブルペロブスカイト / 鉛フリーダブルペロブスカイト / バンドギャップ制御 / 第一原理計算 / 有機無機複合ペロブスカイト / 薄膜太陽電池 / 要因解明 / ホール輸送層不要 / カーボン電極ベースしたデバイス
Outline of Final Research Achievements

In recent years, lead-based perovskites have become the most promising photovoltaic material showing an excellent photoelectronic performance. However, the lead-based perovskite has the issues of instability and environmental problem. In this project, we carried out the studies of improvement of the stability by using carbon electrode to replace Au and sprio hole transfer material. We also designed and synthesized several new lead-free Bi-based double perovskite materials. We investigated the crystallite and electronic structure and optical properties by various testing methods. The Bi-based Pb-free perovskite solar cells were also fabricated. The performance have been evaluated by J-V curves and IPCE.
Based on the results, we published 20 papers(during them, 18 publications are collaboration with abroad). We also presented our results at international conferences as invited speaker and oral presentaion. We think that these results are very important for PSCs.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (37 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (17 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 16 results,  Acknowledgement Compliant: 4 results,  Open Access: 4 results) Presentation (14 results) (of which Int'l Joint Research: 10 results,  Invited: 5 results) Remarks (3 results)

  • [Int'l Joint Research] 大連理工大学(中国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] 大連理工大学(中国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] 大連理工大学(中国)

    • Related Report
      2015 Research-status Report
  • [Journal Article] First-principles study of electronic and optical properties of lead-free double perovskites Cs 2 Na BX 6 ( B = Sb, Bi; X = Cl, Br, I)2018

    • Author(s)
      Zhao Shuai、Yamamoto Kumiko、Iikubo Satoshi、Hayase Shuzi、Ma Tingli
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 117 Pages: 117-121

    • DOI

      10.1016/j.jpcs.2018.02.032

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Incredible PCE Enhancement Induced by Damaged Perovskite Layers: Deeply Understanding the Working Principle of Additives in Bulk Heterojunction Perovskite Solar Cells2018

    • Author(s)
      Liguo Gao、Likun Wang、Xiaogang Ding、Erling Zha、Shuzhang Yang、Yingyuan Zhao、Yanqiang Li、Shufeng Wangb、Tingli Ma
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 6 Issue: 10 Pages: 4365-4373

    • DOI

      10.1039/c7ta09740a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Low-Temperature Processed Non-TiO2 Electron Selective Layers for Perovskite Solar Cells2018

    • Author(s)
      Zhanglin Guo、Liguo Gao、Chu Zhang、Zhenhua Xua、Tingli Ma
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 6 Issue: 11 Pages: 4572-4589

    • DOI

      10.1039/c7ta10742k

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Low-temperature processed compact layer for perovskite solar cells with negligible hysteresis2017

    • Author(s)
      Wang Liang、Liu Fengjing、Liu Tianjun、Cai Xiaoyong、Wang Gongtang、Ma Tingli、Jiang Chao
    • Journal Title

      Electrochimica Acta

      Volume: 235 Pages: 640-645

    • DOI

      10.1016/j.electacta.2017.03.145

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of lead-free (CH 3 NH 3 ) 3 Bi 2 I 9 perovskite addition on spectrum absorption and enhanced photovoltaic performance of bismuth triiodide solar cells2017

    • Author(s)
      Lan Chunfeng、Luo Jingting、Zhao Shuai、Zhang Chu、Liu Weiguo、Hayase Shuzi、Ma Tingli
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 701 Pages: 834-840

    • DOI

      10.1016/j.jallcom.2017.01.169

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transparent Conductive Oxide Layer and Hole Selective Layer Free Back-Contacted Hybrid Perovskite Solar Cell2017

    • Author(s)
      Hu Zhaosheng、Kapil Gaurav、Shimazaki Hiromitsu、Pandey Shyam Sudhir、Ma Tingli、Hayase Shuzi
    • Journal Title

      American Chemical Society

      Volume: 121 Issue: 8 Pages: 4214-4219

    • DOI

      10.1021/acs.jpcc.7b00760

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Current Advancements in Material Research and Techniques Focusing on Lead-free Perovskite Solar Cells2017

    • Author(s)
      Zhang Chu、Gao Liguo、Hayase Shuzi、Ma Tingli
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 9 Pages: 1276-1284

    • DOI

      10.1246/cl.170345

    • NAID

      130006067841

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Advances and Obstacles on Perovskite Solar Cell Research from Material Properties to Photovoltaic Function2017

    • Author(s)
      Bisquert Juan、Qi Yabing、Ma Tingli、Yan Yanfa
    • Journal Title

      ACS Energy Letters

      Volume: 2 Issue: 2 Pages: 520-523

    • DOI

      10.1021/acsenergylett.7b00085

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Strategic improvement of the long-term stability of perovskite materials and perovskite solar cells2016

    • Author(s)
      Tingting Xu, Lixin Chen, Zhanhu Guo, Tingli Ma
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 18 Issue: 39 Pages: 27026-27050

    • DOI

      10.1039/c6cp04553g

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Oxygen vacancy formation and migration in double perovskite Sr2CrMoO6: a first-principles study.2016

    • Author(s)
      Shuai Zhao, Liguo Gao, Chunfeng Lan, Shyam S. Pandey, Shuzi Hayase, Tingli Ma
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 49 Pages: 43034-43040

    • DOI

      10.1039/c6ra05581h

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] First principles analysis of oxygen vacancy formation and migration in Sr2BMoO6 (B = Mg, Co, Ni)2016

    • Author(s)
      Shuai Zhao, Liguo Gao, Chunfeng Lan, Shyam S. Pandey, Shuzi Hayase, Tingli Ma
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 38 Pages: 31968-31975

    • DOI

      10.1039/c6ra02297a

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Concentration gradient controlled growth of large-grain CH3NH3PbI3 films and enhanced photovoltaic performance of solar cells in ambient conditions,2016

    • Author(s)
      Chunfeng Lan; Shuai Zhao; Chu Zhang; Weiguo Liu; Shuzi Hayase; Tingli Ma
    • Journal Title

      CrystEngComm

      Volume: 18 Issue: 48 Pages: 9243-9251

    • DOI

      10.1039/c6ce02151d

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Recent progress of silicon composites as anode materials for secondary batteries2016

    • Author(s)
      Jingjing Wang, Tingting Xu, Xiao Huang, Huan Li, Tingli Ma
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 90 Pages: 87778-87790

    • DOI

      10.1039/c6ra08971b

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Insight into Perovskite Solar Cells Based on SnO2 Compact Electron-Selective Layer.2015

    • Author(s)
      Qingshun Dong, Yantao Shi*, Kai Wang, Yu Li, Shufeng Wang, Hong Zhang, Yujin Xing, Yi Du, Xiaogong Bai, Tingli Ma*
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 119 Issue: 19 Pages: 10212-10217

    • DOI

      10.1021/acs.jpcc.5b00541

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] First principles study on the electronic and optical properties of B-site ordered double perovskite Sr2MMoO6 (M=Mg, Ca, and Zn).2015

    • Author(s)
      Shuai Zhao, Chunfeng Lan, Jie Ma, Shyam S. Pandey, Shuzi Hayase, Tingli Ma*
    • Journal Title

      Solid State Communications

      Volume: 213-214 Pages: 19-23

    • DOI

      10.1016/j.ssc.2015.04.012

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Low-Temperature and Solution-Processed Amorphous WOX as Electron-Selective Layer for Perovskite Solar Cells.2015

    • Author(s)
      Kai Wang, Yantao Shi*, Qingshun Dong, Yu Li, Shufeng Wang, Xufeng Yu, Mengyao Wu, Tingli Ma*
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 6(5) Issue: 5 Pages: 755-759

    • DOI

      10.1021/acs.jpclett.5b00010

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Amorphous Inorganic Electron-Selective Layers for Efficient Perovskite Solar Cells: Feasible Strategy Towards Room-Temperature Fabrication.2015

    • Author(s)
      Kai Wang,Yantao Shi,Bo Li,Liang Zhao,Wei Wang,Xiangyuan Wang,Xiaogong Bai,Shufeng Wang,Ce Hao, Tingli Ma*
    • Journal Title

      Advanced Materials

      Volume: 28(9) Issue: 9 Pages: 1891-1897

    • DOI

      10.1002/adma.201505241

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 鉛フリーペロブスカイト太陽電池の性能に関する研究2017

    • Author(s)
      Tingli Ma
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Development of New Materials for Highly Efficient Perovskte Solar Cells2017

    • Author(s)
      Tingli Ma
    • Organizer
      AP-HOPV2017
    • Place of Presentation
      横浜
    • Year and Date
      2017-02-03
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Recent Progress of Flexible perovskite solar cell2017

    • Author(s)
      Tingli Ma
    • Organizer
      2017 MRS SPRING MEETING & EXHIBIT
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Progress of Pb-free perovskites and their application for solar cells2017

    • Author(s)
      Tingli Ma
    • Organizer
      China Photovoltaic Technology International Conference (CPTIC) 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] In-situ Fabrication Integrated electrode of Perovskite Solar Cells2017

    • Author(s)
      Tingli Ma
    • Organizer
      11th Aseanian Conference on Nano-Hybrid Solar Cells (NHSC11)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Pb-free perovskites and their application for solar cells2017

    • Author(s)
      Tingli Ma
    • Organizer
      33rd European Photovoltaic Solar Energy Conference and Exhibition (EU PVSEC 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Feasible Strategy Towards Low Temperature Fabrication of Perovskite Solar Cells,2016

    • Author(s)
      Kai Wang, Tingli Ma
    • Organizer
      PRiMe2016
    • Place of Presentation
      アメリカ ハワイ
    • Year and Date
      2016-10-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Recent Progress of Pb-free perovskite solar cells2016

    • Author(s)
      Tingli Ma
    • Organizer
      10th Asian-Pacific Conference on Nano Hybrid Solar Cell
    • Place of Presentation
      中国 北京
    • Year and Date
      2016-09-20
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Pb-free Perovskite solar cell2016

    • Author(s)
      S.Zhao, C.Lan, Tingli Ma
    • Organizer
      2016年光化学会討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
  • [Presentation] Strategy Toward Room;Temperature Fabriciction of Flexible Perovskite Solar Cell2016

    • Author(s)
      Tingli Ma
    • Organizer
      HOPV16
    • Place of Presentation
      イギリス スワンシー
    • Year and Date
      2016-06-28
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Feasible Strategy towerds Low temperature Fabrication of Flexible Perovskite Solar Cell.2016

    • Author(s)
      Tingli Ma
    • Organizer
      EU-PVSEC2016
    • Place of Presentation
      ドイツ ミュンヘン
    • Year and Date
      2016-06-20
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] LOW TEMPERATURE AND SOLUTION PROCESSED ELECTRON SELECTIVE LAYER FOR FLEXIBLE PEROVSKITE SOLAR CELLS2015

    • Author(s)
      Tingli Ma, Wangkai,
    • Organizer
      International materials research congress
    • Place of Presentation
      Cancun Mexico
    • Year and Date
      2015-08-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] ペロブスカイト太陽電池の研究2015

    • Author(s)
      馬廷麗、王開、蘭春鋒
    • Organizer
      第2回薄膜太陽電池シンポジウム
    • Place of Presentation
      北京中国科学院物理研究所(中国)
    • Year and Date
      2015-05-24
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Low Temperature and Solution Processed WOx and SnO2 as Electron Selective Layer for Perovskite2015

    • Author(s)
      Tingli Ma, Wangkai, Shiyantao
    • Organizer
      Hybrid Organic Photovotics (HOPV)
    • Place of Presentation
      Roma,Italy
    • Year and Date
      2015-05-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Remarks] 国立大学法人 九州工業大学 大学院生命体工学研究科 馬研究室

    • URL

      http://www.life.kyutech.ac.jp/~tinglima/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 九州工業大学生命体工学研究科馬研究室

    • URL

      http://www.life.kyutech.ac.jp/~tinglima/index-e.html

    • Related Report
      2016 Research-status Report
  • [Remarks] Ma Lab

    • URL

      http://www.life.kyutech.ac.jp/~tinglima/index-e.html

    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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