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synthesis of chiral organosilane compounds for high performance CPL materials

Research Project

Project/Area Number 15K05604
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic and hybrid materials
Research InstitutionThe University of Tokyo

Principal Investigator

Yamanoi Yoshinori  東京大学, 大学院理学系研究科(理学部), 准教授 (20342636)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords円偏光発光 / 不斉ケイ素原子 / 有機ケイ素 / パラジウム触媒 / ピレン / アントラセン / 光学活性
Outline of Final Research Achievements

Compounds exhibiting circularly polarized luminescence are expected to be used as luminescent materials for three-dimensional displays. In this study, we synthesized an optically active silicon compound having both good fluorescence quantum yield and circular polarized luminescence characteristics in a monomolecular state, based on a new asymmetric silicon atom construction method. In particular, the optically active tertiary silane having a pyrene skeleton exhibited a very high value in the monomolecular state as the circular polarized luminescence characteristic glum: 0.01.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (22 results)

All 2018 2017 2016 2015 Other

All Journal Article (11 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 11 results,  Acknowledgement Compliant: 6 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results) Remarks (3 results)

  • [Journal Article] Aggregation-Induced Emission Enhancement from Disilane-Bridged Donor-Acceptor-Donor Luminogens Based on the Triarylamine Functionality2018

    • Author(s)
      Usuki Tsukasa、Shimada Masaki、Yamanoi Yoshinori、Ohto Tatsuhiko、Tada Hirokazu、Kasai Hidetaka、Nishibori Eiji、Nishihara Hiroshi
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: in press Issue: 15 Pages: 12164-12172

    • DOI

      10.1021/acsami.7b14802

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Attachment chemistry of aromatic compounds on a Silicon(100) surface2018

    • Author(s)
      Henriksson Anders、Nishiori Daiki、Maeda Hiroaki、Miyachi Mariko、Yamanoi Yoshinori、Nishihara Hiroshi
    • Journal Title

      Surface Science

      Volume: 669 Pages: 140-144

    • DOI

      10.1016/j.susc.2017.11.017

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Multifunctional Octamethyltetrasila[2.2]cyclophanes: Conformational Variations, Circularly Polarized Luminescence, and Organic Electroluminescence2017

    • Author(s)
      Shimada Masaki、Yamanoi Yoshinori、Ohto Tatsuhiko、Pham Song-Toan、Yamada Ryo、Tada Hirokazu、Omoto Kenichiro、Tashiro Shohei、Shionoya Mitsuhiko、Hattori Mineyuki、Jimura Keiko、Hayashi Shigenobu、Koike Hikaru、Iwamura Munetaka、Nozaki Koichi、Nishihara Hiroshi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 32 Pages: 11214-11221

    • DOI

      10.1021/jacs.7b05671

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocurrent generation of reconstituted photosystem II on self-assembled gold film2017

    • Author(s)
      Miyachi, M.; Ikehira, S.; Nishiori, D.; Yamanoi, Y.;* Yamada, M.; Iwai, M.; Tomo, T.; Allakhverdiev, S. I.; Nishihara, H.*
    • Journal Title

      Langmuir

      Volume: 33 Issue: 6 Pages: 1351-1358

    • DOI

      10.1021/acs.langmuir.6b03499

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Unusual reactivity of group 14 hydrides toward organic halides: synthetic studies and application to functional materials2016

    • Author(s)
      Shimada, M.; Yamanoi, Y.; Nishihara, H.
    • Journal Title

      J. Synth. Org. Chem. Jpn.

      Volume: 74 Pages: 1098-1107

    • NAID

      130005433324

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effects of Substitution on Solid-State Fluorescence in 9-Aryl-9-methyl-9H-9-silafluorenes2016

    • Author(s)
      *Yoshinori Yamanoi, Takayuki Nakashima, Masaki Shimada, Hiroaki Maeda, *Hiroshi Nishihara
    • Journal Title

      Molecules

      Volume: 21 Issue: 9 Pages: 1173-1173

    • DOI

      10.3390/molecules21091173

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effective Method for Micro-Patterning Arene-Terminated Monolayers on a Si(111) Electrode2016

    • Author(s)
      Yoshinori Yamanoi, Tetsuhiro Kobayashi, Hiroaki Maeda, Mariko Miyachi, Masato Ara, Hirokazu Tada, and Hiroshi Nishihara
    • Journal Title

      Langmuir

      Volume: 32 Issue: 27 Pages: 6825-6829

    • DOI

      10.1021/acs.langmuir.6b01370

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cross-Sectional TEM Analysis of an ITO Surface Coated with Photosystem I and Molecular Wires2016

    • Author(s)
      Miyachi, M.; Yamanoi, Y.;* Tomo, T.; Nishihara, H.*
    • Journal Title

      J. Inorg. Organomet. Polym. Mater.

      Volume: 2016 Issue: 6 Pages: 1309-1312

    • DOI

      10.1007/s10904-016-0396-5

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Bright Solid-State Emission of Disilane-Bridged Donor-Acceptor-Donor and Acceptor-Donor-Acceptor Chromophores2016

    • Author(s)
      M. Shimada, M. Tsuchiya, R. Sakamoto, Y. Yamanoi, E. Nishibori, K. Sugimoto, H. Nishihara
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 9 Pages: 3022-3026

    • DOI

      10.1002/anie.201509380

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fluorescence and phosphorescence of a series of silicon-containing six-membered-ring molecules2016

    • Author(s)
      T. Nakashima, M. Shimada, Y. Kurihara, M. Tsuchiya, Y. Yamanoi, E. Nishibori, K. Sugimoto, H. Nishihara
    • Journal Title

      J. Organomet. Chem.

      Volume: 805 Pages: 27-33

    • DOI

      10.1016/j.jorganchem.2015.12.042

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Characterization, and Physical Properties of Oligo(1-(N,N-dimethylamino)pyrrole)s and Their Doped Forms, Precursors of Candidates for Molecular Flat-band Ferromagnets2015

    • Author(s)
      Y. Yamanoi, K. Takahashi, T. Hamada, N. Ohshima, M. Kurashina, Y. Hattori, T. Kusamoto, R. Sakamoto, M. Miyachi, and H. Nishihara
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 3 Issue: 17 Pages: 1-1

    • DOI

      10.1039/c4tc02941k

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] The development of tetrasila[2.2]cyclophane derivatives for solid-state emission,electroluminescence,and circularly polarized luminescence2017

    • Author(s)
      島田真樹,山野井慶徳,大戸達彦,山田亮,Pham Song-Toan,夛田博一,小池ひかる,岩村宗高,野崎浩一,西原寛
    • Organizer
      2017年光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis and physical properties of tetrasila[2.2]thiophenophane derivatives for the luminescent and chiroptical materials2017

    • Author(s)
      Masaki Shimada,Yoshinori Yamanoi,Kenichiro Omoto,Shohei Tashiro,Mitsuhiko Shionoya,Tatsuhiko Ohto,Song-Toan Pham,Ryo Yamada,Hirokazu Tada,Mineyuki Hattori,Keiko Jimura,Shigenobu Hayashi,Hikaru Koike,Munetaka Iwamura,Koichi Nozaki,Hiroshi Nishihara
    • Organizer
      254th ACS National Meeting & Exposition
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体発光・円偏光発光を示すオクタメチルテトラシラ[2.2]シクロファンの創製2017

    • Author(s)
      島田真樹,山野井慶徳,小池ひかる,岩村宗高,野崎浩一,西原寛
    • Organizer
      第21回ケイ素化学シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 不斉ケイ素原子をもつ化合物の効率的合成法の開発とその光物性2016

    • Author(s)
      古賀信哉・植木修平・島田真樹・山野井慶徳・湯浅順平・河合壯・打田孝明・岩村宗高・野﨑浩一・西原寛
    • Organizer
      第20回ケイ素化学協会シンポジウム
    • Place of Presentation
      安芸グランドホテル(広島県廿日市市)
    • Year and Date
      2016-10-07
    • Related Report
      2016 Research-status Report
  • [Presentation] Effective Solid-state Emission of Disilane-bridged Arenes Including Donor and Acceptor Moieties2015

    • Author(s)
      Masaki Shimada, Ryota Sakamoto, Yoshinori Yamanoi, Hiroshi Nishihara
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, HI, USA
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] シリコン電極上にSi-アリール結合で修飾したフェロセン誘導体の電子移動挙動2015

    • Author(s)
      和田慶祐、前田啓明、小林徹大、宮地麻里子、山野井慶徳、西原寛
    • Organizer
      分子アーキテクトニクス研究会 第6回研究会
    • Place of Presentation
      京都大学桂キャンパスローム記念館(京都府、京都市)
    • Year and Date
      2015-10-23
    • Related Report
      2015 Research-status Report
  • [Presentation] 固体蛍光材料・非線型光学材料に向けたドナー・アクセプター型ジアリールジシラン類の創製2015

    • Author(s)
      島田真樹, 山野井慶徳, 近藤高志, 松下智紀, 西堀英治, 畠山あかり, 杉本邦久, 西原 寛
    • Organizer
      日本化学会秋季事業 第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都、江戸川区)
    • Year and Date
      2015-10-15
    • Related Report
      2015 Research-status Report
  • [Presentation] シリコン電極上にSi-アリール結合で修飾したフェロセン誘導体の電子移動挙動2015

    • Author(s)
      和田慶祐、前田啓明、小林徹大、宮地麻里子、山野井慶徳、西原寛
    • Organizer
      2015年電気化学会秋季大会
    • Place of Presentation
      埼玉工業大学(埼玉県、深谷市)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Research-status Report
  • [Remarks] 東京大学大学院理学系研究科化学専攻無機化学研究室

    • URL

      https://www.chem.s.u-tokyo.ac.jp/users/inorg/link.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 東京大学 大学院理学系研究科 化学専攻 無機化学研究室

    • URL

      https://www.chem.s.u-tokyo.ac.jp/~inorg/

    • Related Report
      2016 Research-status Report
  • [Remarks] 東京大学大学院理学系研究科化学専攻無機化学研究室

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/inorg/index.html

    • Related Report
      2015 Research-status Report

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Published: 2015-04-16   Modified: 2019-03-29  

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