Development of high performance catalysts by surface modification using bulky ionic liquids
| Project/Area Number |
15K05606
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic and hybrid materials
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
Tomohiko Inomata 名古屋工業大学, 工学(系)研究科(研究院), 准教授 (40397493)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | イオン液体 / 触媒反応 / 修飾電極 / 金属ナノ微粒子 / ナノ細孔材料 / ナノ微粒子 / FSM / アルキル鎖長 / ナノ反応場 / 修飾基板 / 金属錯体 / 細孔材料 |
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| Outline of Final Research Achievements |
Various bulky ionic liquids were modified on substrate surfaces and "ionic liquid-reaction field" with various sized spaces were constructed. The size of ionic liquid-reactionfield affected on the surface structures of modified ionic liquids and redox behavior of trapped ferrocene molecules.
Furthermore, ionic liquid-modified Au nanoparticles and nano sized porous materials like FSM-16 were also constructed. Metal complexes were entrapped into the ionic liquid-reaction field constructed on the surface of Au nanoparticles and FSM-16. The catalytic ability of Cu complex entrapped in the ionic liquid-reaction field in FSM-16 were estimated from the oxidation reaction of thioanisole. The Cu complex-entrapped FSM modified by ionic liquids indicated good reusability in its catalytic reaction.
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Report
(4 results)
Research Products
(157 results)
