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Creation of molecular gel materials using multi-component network

Research Project

Project/Area Number 15K05610
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic and hybrid materials
Research InstitutionAshikaga University (2018-2019)
Fukuoka Institute of Technology (2015-2017)

Principal Investigator

Ohsedo Yutaka  足利大学, 工学部, 講師 (70324811)

Project Period (FY) 2015-10-21 – 2020-03-31
Project Status Discontinued (Fiscal Year 2019)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2019: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2018: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords分子性ゲル / 低分子ゲル化剤 / ヒドロゲル / オルガノゲル / ゲル形成能 / チキソトロピー性 / 混合
Outline of Final Research Achievements

For the purpose of creating new high-performance mixed molecular gels by simply mixing gelators, homologous systems of low-molecular-weight gelators, non-gelators, or a polymer gelator have been examined. Based on the research results on the functionalization of mixed molecular gels by mixing homologues with different alkyl chain lengths, which were discovered by the principal investigator, the principal investigator has created new low-molecular-weight gelators, new polymer hydrogelator, new mixed molecular gels with better thixotropy, and new inorganic/organic and organic/organic composite polymer molecular gels with better thixotropy, respectively.

Academic Significance and Societal Importance of the Research Achievements

研究代表者が見出したアルキル鎖長の異なる同族体の混合化・多成分化による混合系ゲルの創製は、低分子ゲル化剤同士の単純な混合により達成できる。本研究では、新規混合系分子性ゲルを形成するいくつかの新規低分子化合物系を見出したのみならず、新規高分子系分子性ゲルを見出し、かつ高分子系においても混合系ゲルの物性向上や機能付与が可能であることが明らかとなった。

Report

(5 results)
  • 2019 Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Research-status Report
  • 2016 Research-status Report
  • 2015 Research-status Report
  • Research Products

    (31 results)

All 2019 2018 2017 2016 2015

All Journal Article (11 results) (of which Peer Reviewed: 10 results,  Open Access: 3 results,  Acknowledgement Compliant: 1 results) Presentation (19 results) (of which Int'l Joint Research: 6 results,  Invited: 2 results) Book (1 results)

  • [Journal Article] Fusion of inorganic nanosheets and microtubules for active anisotropic colloid driven by biochemical energy and entropic force2018

    • Author(s)
      R. Kato;A. Kakugo;K. Shikinaka;Y. Ohsedo;A. M. R. Kabir;N. Miyamoto
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 11 Pages: 14869-14874

    • DOI

      10.1021/acsomega.8b01050

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Anisotropic self-oscillating reaction in liquid crystalline nanosheets hydrogels2018

    • Author(s)
      M. Shintate, T. Inadomi, S. Yamamoto, Y. Kuboyama, Y. Ohsedo, T. Arimura, T. Nakazumi, Y. Hara, N. Miyamoto
    • Journal Title

      J. Phys. Chem. B

      Volume: 122 Issue: 11 Pages: 2957-2961

    • DOI

      10.1021/acs.jpcb.7b11631

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of an electronically conductive hydrogel from a hydrogelator and a conducting polymer2017

    • Author(s)
      Yutaka Ohsedo, Kowichiro Saruhashi, Hisayuki Watanabe, and Nobuyoshi Miyamoto
    • Journal Title

      New Journal of Chemistry

      Volume: 41 Issue: 18 Pages: 9602-9606

    • DOI

      10.1039/c7nj02412f

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thixotropic stiff hydrogels from a new class of oleoyl-D-glucamine-based low-molecular-weight gelators2017

    • Author(s)
      Yutaka Ohsedo, Masashi Oono, Kowichiro Saruhashi, Hisayuki Watanabe and Nobuyoshi Miyamoto
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 66 Pages: 41686-41692

    • DOI

      10.1039/c7ra07244a

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] New Composite Thixotropic Hydrogel Composed of a Polymer Hydrogelator and a Nanosheet2017

    • Author(s)
      Yutaka Ohsedo, Masashi Oono, Kowichiro Saruhashi, Hisayuki Watanabe and Nobuyoshi Miyamoto
    • Journal Title

      Royal Society Open Science

      Volume: 4 Issue: 12 Pages: 171117-171117

    • DOI

      10.1098/rsos.171117

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] 低分子ゲル化剤の混合によるチキソトロピー性の発現2017

    • Author(s)
      大背戸豊
    • Journal Title

      月刊ファインケミカル

      Volume: 46 Pages: 32-40

    • Related Report
      2017 Research-status Report
  • [Journal Article] Low-Molecular-Weight Organogelators as Functional Materials for Oil Spill Remediation2016

    • Author(s)
      Yutaka Ohsedo
    • Journal Title

      Polymers for Advanced Technologies

      Volume: 26 Issue: 6 Pages: 704-711

    • DOI

      10.1002/pat.3712

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Low-Molecular-Weight Organogelators as Base Materials for Ointments2016

    • Author(s)
      Yutaka Ohsedo
    • Journal Title

      Gels

      Volume: 2 Issue: 2 Pages: 13-13

    • DOI

      10.3390/gels2020013

    • Related Report
      2016 Research-status Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Improved Mechanical Properties of Polyacrylamide Hydrogels Created in the Presence of Low-Molecular-Weight Hydrogelator2015

    • Author(s)
      Yutaka Ohsedo, Makiko Taniguchi, Masashi Oono, Kowichiro Saruhashi and Hisayuki Watanabe
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 109 Pages: 90010-90013

    • DOI

      10.1039/c5ra16823f

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] New Water-Soluble Aromatic Polyamide Hydrogelator with Thixotropic Properties2015

    • Author(s)
      Yutaka Ohsedo, Masashi Oono, Kowichiro Saruhashi and Hisayuki Watanabe
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 101 Pages: 82772-82776

    • DOI

      10.1039/c5ra16824d

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Long-Chain Alkylamide-Derived Oil Gels: Mixing Induced Onset of Thixotropy and Application in Sustained Drug Release2015

    • Author(s)
      Yutaka Ohsedo, Makiko Taniguchi, Masashi Oono, Kowichiro Saruhashi and Hisayuki Watanabe
    • Journal Title

      New Journal of Chemistry

      Volume: 39 Issue: 8 Pages: 6482-6490

    • DOI

      10.1039/c5nj00999e

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Presentation] 異なる鎖長のアルキル基および水素結合性基を有する低分子ゲル化剤の混合による機能向上2019

    • Author(s)
      大背戸豊
    • Organizer
      日本化学会第99春季年会、甲南大学(神戸市、兵庫県)、2019年3月18日
    • Related Report
      2018 Annual Research Report
  • [Presentation] Squaric acid for creating low-molecular-weight gelators and functional dyes2018

    • Author(s)
      Yutaka Ohsedo
    • Organizer
      West Japan Nanosheet Society Summer Camp 2018 (WJNS-SC2018), 9-11 August, Kaneya Annex, Iki-shi, Nagasaki, Japan
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mixing Strategy to Enhance Gel Properties Composed of Low-Molecular-Weight Gelators2018

    • Author(s)
      Yutaka Ohsedo
    • Organizer
      The 5th International Conference on Nanomechanics and Nanocomposites (ICNN5) 22 to 25 August 2018, Fukuoka Institute of Technology, Fukuoka, Japan
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Nanosheet Liquid Crystal Composite Polyurethane Fiber2018

    • Author(s)
      Toki Morooka, Yutaka Ohsedo, and Nobuyoshi Miyamoto
    • Organizer
      The 5th International Conference on Nanomechanics and Nanocomposites (ICNN5) 22 to 25 August 2018, Fukuoka Institute of Technology, Fukuoka, Japan
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Nanocomposite Material Using Nanosheet/Hydrogel Composite Polymer for Template2018

    • Author(s)
      Toshiki Furukawa, Yutaka Ohsedo, Nobuyoshi Miyamoto
    • Organizer
      The 5th International Conference on Nanomechanics and Nanocomposites (ICNN5) 22 to 25 August 2018, Fukuoka Institute of Technology, Fukuoka, Japan
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子ヒドロゲル化剤をマトリクスとする複合ゲル材料の創製2018

    • Author(s)
      大背戸豊、大野正司、猿橋康一郎、渡邊久幸、宮元展義
    • Organizer
      第67回高分子討論会、北海道大学(札幌市、北海道)、2018年9月12日
    • Related Report
      2018 Annual Research Report
  • [Presentation] 液晶性無機ナノシート/ポリウレタン複合ファイバーの合成2018

    • Author(s)
      諸岡時希、大背戸豊、宮元展義
    • Organizer
      第67回高分子討論会、北海道大学(札幌市、北海道)、2018年9月12日
    • Related Report
      2018 Annual Research Report
  • [Presentation] ヒドロゲルを鋳型としたナノシート高分子ハイブリッド材料の創生2018

    • Author(s)
      古川聡起、大背戸豊、宮元展義
    • Organizer
      第67回高分子討論会、北海道大学(札幌市、北海道)、2018年9月12日
    • Related Report
      2018 Annual Research Report
  • [Presentation] 無機ナノシート液晶を複合化したエラストマーとゲル2018

    • Author(s)
      宮元展義、諸岡時希、古川聡起、稲富巧、大背戸豊
    • Organizer
      第67回高分子討論会、北海道大学(札幌市、北海道)、2018年9月12日
    • Related Report
      2018 Annual Research Report
  • [Presentation] グルカミン系低分子ゲル化剤から成るチキソトロピー性ヒドロゲル2017

    • Author(s)
      大背戸豊、大野正司、猿橋康一郎、渡邊久幸、宮元展義
    • Organizer
      第66回高分子学会年次大会、幕張メッセ(千葉市、千葉県)
    • Related Report
      2017 Research-status Report
  • [Presentation] MIXING ENHANCEMENT EFFECT OF MOLECULAR GELS COMPOSED OF HYDORGELATOR WITH LAPONITE ON THIXOTROPIC BEHAVIOR2017

    • Author(s)
      Yutaka Ohsedo, Masashi Oono, Kowichirou Saruhashi, Hisayuki Watanabe, Nobuyoshi Miyamoto
    • Organizer
      16th INTERNATIONAL CLAY CONFERENCE, CLAYS, FROM THE OCEANS TO SPACE, Granada, Spain 17-21 July 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 新規グルカミン系低分子ゲル化剤からなる分子性ゲルとそのチキソトロピー性2017

    • Author(s)
      大背戸豊、大野正司、猿橋康一郎、渡邊久幸、宮元展義
    • Organizer
      第66回高分子討論会、愛媛大学(松山市、愛媛県)
    • Related Report
      2017 Research-status Report
  • [Presentation] 水溶性芳香族ポリアミド系高分子ゲル化剤/無機ナノシート複合分子性ゲルの創製2017

    • Author(s)
      大背戸豊、大野正司、猿橋康一郎、渡邊久幸、宮元展義
    • Organizer
      高分子基礎研究会2017、敦賀ニューサンピア(敦賀市、福井県)
    • Related Report
      2017 Research-status Report
  • [Presentation] 高分子ヒドロゲル化剤/導電性高分子複合系の創製2017

    • Author(s)
      大背戸豊、猿橋康一郎、渡邊久幸、宮元展義
    • Organizer
      西日本ナノシート研究会ウインターキャンプ、つえたて温泉ひぜんや(阿蘇郡、熊本県)
    • Related Report
      2017 Research-status Report
  • [Presentation] チキソトロピー性ヒドロゲルを形成する新規グルカミン系低分子ヒドロゲル化剤創製2016

    • Author(s)
      大背戸豊、大野正司、猿橋康一郎、渡邊久幸
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府・京田辺市)
    • Year and Date
      2016-03-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 水溶性芳香族ポリアミドの高分子ゲル化剤への応用2016

    • Author(s)
      大背戸豊
    • Organizer
      高分子基礎研究会2015
    • Place of Presentation
      FITセミナーハウス大分(大分県・由布市)
    • Year and Date
      2016-01-30
    • Related Report
      2015 Research-status Report
  • [Presentation] Mixing Enhancement Effect of Low-Molecular-Weight Hydorgelator with Laponite2016

    • Author(s)
      Yutaka Ohsedo
    • Organizer
      The 1st FIT-ME Symposium
    • Place of Presentation
      福岡工業大学(福岡県・福岡市)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] グリシン-グルカミン構造を中心とする新規低分子ゲル化剤の創製2016

    • Author(s)
      大背戸豊
    • Organizer
      西日本ナノシート研究会サマーキャンプ 2016
    • Place of Presentation
      屋久島シーサイドホテル(鹿児島県・熊毛郡屋久島町)
    • Related Report
      2016 Research-status Report
  • [Presentation] 新規グルカミン誘導体が形成するチキソトロピー性ヒドロゲル2016

    • Author(s)
      大背戸豊、大野正司、猿橋康一郎、渡邊久幸、宮元展義
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(神奈川県・横浜市)
    • Related Report
      2016 Research-status Report
  • [Book] 「低分子ゲルの開発と応用」、第11章3節、アルキルヒドラジド誘導体によるチキソトロピー性超分子ゲル(分担執筆)2016

    • Author(s)
      大背戸 豊
    • Total Pages
      249
    • Publisher
      シーエムシー出版
    • Related Report
      2016 Research-status Report

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Published: 2015-10-21   Modified: 2021-02-19  

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