| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
Many ligands carrying fused aromatics such as naphthalene anthracene, pyrene, perylene, etc. can be synthesized using condensation reaction. And, the desired complexes were successfully obtained by complexation of the ligands with 3d or 4f ions in good yields.
Structures of the complexes were determined using single crystal structure analyses. The ligand units in the complexes were oriented by bulkiness of the ligands. And it is also affected by intramolecular weak interaction such as CH-pai interaction. Further, in conc. solution only monomer emission was observed. But in crystal or solid state, eximer emission was observed due to intermolecular interaction such as pai-pai interaction.
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