Preparation of high efficient luminescence materials using multi-coordination complex structures
| Project/Area Number |
15K05611
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic and hybrid materials
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| Research Institution | Kyushu Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 金属錯体 / 縮環芳香族 / 配位子 / 電気伝導性 / 蛍光 / 縮環芳香族配位子 / エキシマ―発光 / 単結晶Ｘ線構造解析 / 濃度消光 / 発光材料 / Eu錯体 / 高共役系配位子 / ランタノイド / ルテニウム |
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| Outline of Final Research Achievements |
Many ligands carrying fused aromatics such as naphthalene anthracene, pyrene, perylene, etc. can be synthesized using condensation reaction. And, the desired complexes were successfully obtained by complexation of the ligands with 3d or 4f ions in good yields.
Structures of the complexes were determined using single crystal structure analyses. The ligand units in the complexes were oriented by bulkiness of the ligands. And it is also affected by intramolecular weak interaction such as CH-pai interaction. Further, in conc. solution only monomer emission was observed. But in crystal or solid state, eximer emission was observed due to intermolecular interaction such as pai-pai interaction.
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Report
(4 results)
Research Products
(17 results)
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[Journal Article] Molecular structures of n-type semiconducting material 2,5-difluoro-1,4-phenylene-3,30-bis{2-[(4-trifluoromethyl)phenyl]acrylonitrile}and its photo dimerization product2016
Author(s)
Tetsuji Moriguchi, Naoya Kitou, Venkataprasad Jalli, Kenji Yoza, Shuichi Nagamatsu, Tatsuo Okauchi, Akihiko Tsuge, Wataru Takashima
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Journal Title
Journal of Molecular Structure
Volume: 1118
Pages: 372-377
DOI
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] Synthesis and Crystal Structure Determination of 4’,9’,4”,9”-Tetra-t-Butyl-1’,6’,1”,6”-Tetramethoxy-2,5-Dithia[3.3]Metabiphenylophane2016
Author(s)
Tetsuji Moriguchi, Tatsuya Egami, Daisuke Yakeya, Venkataprasad Jalli, Kenji Yoza,Akihiko Tsuge
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Journal Title
Crystal Structure Theory and Applications
Volume: 5
Issue: 03
Pages: 56-62
DOI
Related Report
Peer Reviewed / Open Access
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